PHEA-g-PDMAEA well-defined graft copolymers: SET-LRP synthesis, self-catalyzed hydrolysis, and quaternization

2016 ◽  
Vol 7 (45) ◽  
pp. 6973-6979 ◽  
Author(s):  
Fangxu Sun ◽  
Chun Feng ◽  
Haoyu Liu ◽  
Xiaoyu Huang
Keyword(s):  
Raft Polymerization ◽  
Graft Copolymers ◽  
Side Chains ◽  
Grafting From

This article reports the synthesis of well-defined graft copolymers containing a PHEA backbone and degradable PDMAEA side chains, by the combination of RAFT polymerization, SET-LRP, and the grafting-from strategy.

The first amphiphilic graft copolymer bearing a hydrophilic poly(2-hydroxylethyl acrylate) backbone synthesized by successive RAFT and ATRP

2014 ◽  
Vol 5 (17) ◽  
pp. 4915-4925 ◽  
Author(s):  
Xiuyu Jiang ◽  
Xue Jiang ◽  
Guolin Lu ◽  
Chun Feng ◽  
Xiaoyu Huang
Keyword(s):  
Graft Copolymer ◽  
Raft Polymerization ◽  
Graft Copolymers ◽  
Side Chains ◽  
Amphiphilic Graft Copolymer ◽  
Amphiphilic Graft Copolymers ◽  
Grafting From

This paper reports the first synthesis of well-defined amphiphilic graft copolymers, consisting of a hydrophilic poly(2-hydroxyethyl acrylate) (PHEA) backbone and hydrophobic polystyrene side chains, by the combination of RAFT polymerization, ATRP, and the grafting-from strategy.

scholarly journals First double hydrophilic graft copolymer bearing a poly(2-hydroxylethyl acrylate) backbone synthesized by sequential RAFT polymerization and SET-LRP

2016 ◽  
Vol 7 (18) ◽  
pp. 3156-3164 ◽  
Author(s):  
Yinan Cui ◽  
Xiuyu Jiang ◽  
Chun Feng ◽  
Guangxin Gu ◽  
Jie Xu ◽  
...  
Keyword(s):  
Graft Copolymer ◽  
Raft Polymerization ◽  
Graft Copolymers ◽  
Grafting From

This article reports the first synthesis of well-defined double hydrophilic graft copolymers with a PHEA backbone, by the combination of RAFT polymerization, SET-LRP, and a grafting-from strategy.

Synthesis and characterization of amphiphilic graft copolymers with hydrophobic poly(α-methylstyrene) backbone and hydrophilic poly(n-vinylpyrrolidone) side chains

e-Polymers ◽  
2012 ◽  
Vol 12 (1) ◽  
Author(s):  
Fatima Zohra Sebba ◽  
Seghier Ould Kada ◽  
Mohamed Benaicha ◽  
Nerjesse Nemiche
Keyword(s):  
Graft Copolymer ◽  
Graft Copolymers ◽  
Radical Copolymerization ◽  
Side Chains ◽  
Free Radical Copolymerization ◽  
Good Efficiency ◽  
Molecular Weights ◽  
Grafting Reaction ◽  
Viscosity Variation ◽  
End Capping

AbstractIn this study, 2-oxopropylmethacrylate-terminated poly(N-vinyl-2- pyrrolidone) is produced by cationic polymerization using HClO4 as an initiator. Termination (end capping) step is accomplished using 2- hydroxypropylmethacrylate (2HPMA) and the polymer product has different chain lengths of molecular weight averages ranging from 672 to 3049 g/mol. The study also synthesised amphipathic graft copolymers having hydrophobic poly(α- methylstyrene) as a backbone chain and hydrophilic poly(N-vinyl-2-pyrrolidone) (PVP) as side chains of various lengths. The copolymer synthesis was accomplished by free radical copolymerization of ω-oxopropylmethacrylate PVP in the presence of α-methyl styrene initiated with benzoyl peroxide. Measurements of the dynamic viscosity of the polymer solution (20% weight of macromonomers in ethanol) show that the viscosity is proportional to the average molecular weights M̅n . However, a reverse behaviour of the viscosity variation with regard to M̅n is observed for graft copolymer samples. The viscosity variation with respect to the graft copolymer mass must be due to steric effects, which are strongly pronounced in grafted copolymer chains. Appearance of the number of side chains attached to poly(α-methylstyrene) backbone reveals that the grafting reaction has occurred with good efficiency.

Preparation of cellulose graft copolymers having polypeptide side chains and their blood compatibility

1986 ◽  
Vol 31 (7) ◽  
pp. 2303-2314 ◽  
Author(s):  
Takeaki Miyamoto ◽  
Shin-Ichi Takahashi ◽  
Sin-Ichi Tsuji ◽  
Hiraku Ito ◽  
Hiroshi Inagaki ◽  
...  
Keyword(s):  
Blood Compatibility ◽  
Graft Copolymers ◽  
Side Chains

Thermoresponsive behavior of graft copolymers based on poly(N,N-dimethylacrylamide-co-diacetoneacrylamide) side chains

2018 ◽  
Vol 136 (6) ◽  
pp. 47051 ◽  
Author(s):  
Yongjun Guo ◽  
Rutong Song ◽  
Rusen Feng ◽  
Gang Dai ◽  
Yan Liang ◽  
...  
Keyword(s):  
Graft Copolymers ◽  
Side Chains
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