Bridging from the Sequence to Architecture: Graft Copolymers Engineering via Successive Latent Monomer and Grafting‐from Strategies

2021 ◽  
Author(s):  
Yajie Zhang ◽  
Xiaohuan Cao ◽  
Yang Gao ◽  
Yujie Xie ◽  
Zhihao Huang ◽  
...  
Keyword(s):  
Graft Copolymers ◽  
Grafting From

Graft copolymers containing poly(3-hydroxyalkanoates) — A review on their synthesis, properties, and applications

2008 ◽  
Vol 86 (6) ◽  
pp. 570-578 ◽  
Author(s):  
Sophie Nguyen
Keyword(s):  
Graft Copolymer ◽  
Main Chain ◽  
Graft Copolymers ◽  
Preparation Methods ◽  
Synthesis Properties ◽  
Grafting Through ◽  
Grafting From ◽  
Grafting Onto

The use of the poly(3-hydroxyalkanoates) in copolymer synthesis has received much interest, as the microbial polyester segments can bring interesting properties, such as biodegradability and biocompatibility. The synthesis, properties, and applications of graft copolymers containing poly(3-hydroxyalkanoates) as main chain or branches are reviewed here, with emphasis on the different preparation methods, which fit into the three main synthesis strategies of graft copolymers: “grafting onto”, “grafting from”, and “grafting through” or macromonomer methods.Key words: poly(3-hydroxyalkanoates), graft copolymer, synthesis, properties, applications.

PHEA-g-PDMAEA well-defined graft copolymers: SET-LRP synthesis, self-catalyzed hydrolysis, and quaternization

2016 ◽  
Vol 7 (45) ◽  
pp. 6973-6979 ◽  
Author(s):  
Fangxu Sun ◽  
Chun Feng ◽  
Haoyu Liu ◽  
Xiaoyu Huang
Keyword(s):  
Raft Polymerization ◽  
Graft Copolymers ◽  
Side Chains ◽  
Grafting From

This article reports the synthesis of well-defined graft copolymers containing a PHEA backbone and degradable PDMAEA side chains, by the combination of RAFT polymerization, SET-LRP, and the grafting-from strategy.

Synthesis and Characterization of Thermoresponsive Graft Copolymers of NIPAAm and 2-Alkyl-2-oxazolines by the “Grafting from” Method

2005 ◽  
Vol 38 (17) ◽  
pp. 7330-7336 ◽  
Author(s):  
Juan Rueda ◽  
Stefan Zschoche ◽  
Hartmut Komber ◽  
Dirk Schmaljohann ◽  
Brigitte Voit
Keyword(s):  
Graft Copolymers ◽  
Synthesis And Characterization ◽  
Grafting From

scholarly journals First double hydrophilic graft copolymer bearing a poly(2-hydroxylethyl acrylate) backbone synthesized by sequential RAFT polymerization and SET-LRP

2016 ◽  
Vol 7 (18) ◽  
pp. 3156-3164 ◽  
Author(s):  
Yinan Cui ◽  
Xiuyu Jiang ◽  
Chun Feng ◽  
Guangxin Gu ◽  
Jie Xu ◽  
...  
Keyword(s):  
Graft Copolymer ◽  
Raft Polymerization ◽  
Graft Copolymers ◽  
Grafting From

This article reports the first synthesis of well-defined double hydrophilic graft copolymers with a PHEA backbone, by the combination of RAFT polymerization, SET-LRP, and a grafting-from strategy.

Synthesis of degradable poly(ε-caprolactone)-based graft copolymers via a “grafting-from” approach

2016 ◽  
Vol 7 (46) ◽  
pp. 7126-7134 ◽  
Author(s):  
Panagiotis Bexis ◽  
Anthony W. Thomas ◽  
Craig A. Bell ◽  
Andrew P. Dove
Keyword(s):  
Ring Opening ◽  
Graft Copolymers ◽  
Grafting From

The controlled ring-opening polymerisation (ROP) of α-bromo-ε-caprolactone (αBrCL), a derivative of ε-caprolactone (εCL), and its copolymerisation with εCL is reported.

Grafting‐from Afforded Cyclic Graft Copolymers from Cyclic Anionic Macroinitiator via Lithiation of Tolyl Groups

2019 ◽  
pp. 1900224
Author(s):  
Kaoru Adachi ◽  
Takayuki Kono ◽  
Suguru Nakano ◽  
Yusuke Hamaguchi ◽  
Yasuhisa Tsukahara
Keyword(s):  
Graft Copolymers ◽  
Grafting From

Synthesis of novel types of graft copolymers by a “grafting-from” method using ring-opening polymerization of lactones and lactides

2003 ◽  
Vol 57 (2-3) ◽  
pp. 137-146 ◽  
Author(s):  
Miroslav Janata ◽  
Bohumil Masař ◽  
Luděk Toman ◽  
Petr Vlček ◽  
Petra Látalová ◽  
...  
Keyword(s):  
Ring Opening ◽  
Graft Copolymers ◽  
Ring Opening Polymerization ◽  
Grafting From

Water soluble well-defined acidic graft copolymers based on a poly(propylene glycol) macromonomer

RSC Advances ◽  
2015 ◽  
Vol 5 (5) ◽  
pp. 3627-3635 ◽  
Author(s):  
Paulina Maksym-Bębenek ◽  
Tadeusz Biela ◽  
Dorota Neugebauer
Keyword(s):  
Propylene Glycol ◽  
Radical Polymerization ◽  
Methacrylic Acid ◽  
Graft Copolymers ◽  
Controlled Radical Polymerization ◽  
Water Soluble ◽  
Glycol Methacrylate ◽  
Grafting From ◽  
Poly Propylene

A copolymers based on poly(propylene glycol) methacrylate (PPGMA) extended with a polymethacrylate segment containing methacrylic acid units was synthesized combining controlled radical polymerization, esterification, grafting from, and acidolysis.

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