Synthesis and characterization of radiopaque poly(ether urethane) with iodine-Containing diol as chain extender

2011 ◽  
Vol 49 (10) ◽  
pp. 2191-2198 ◽  
Author(s):  
Weiqiang Qu ◽  
Weijuan Xia ◽  
Chao Feng ◽  
Xinlin Tuo ◽  
Teng Qiu
Keyword(s):  
Chain Extender ◽  
Synthesis And Characterization

Synthesis and Characterization of Luminescence Eu3+/Polyurethane Composite Material

2014 ◽  
Vol 884-885 ◽  
pp. 247-250 ◽  
Author(s):  
Kai Sheng ◽  
Jie Lin Wang ◽  
Ying Li ◽  
Yi Han Wang ◽  
Meng Xue Xu ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Composite Material ◽  
Rare Earth ◽  
Hybrid Materials ◽  
Chain Extender ◽  
Synthesis And Characterization ◽  
Rare Earth Ion ◽  
Polyurethane Composite ◽  
Small Molecule Ligands

Selecting lactam 2,6-pyridinedicarboxamide (PDCA) as the ligand and 1,4-butanediol as chain extender, we prepare polyurea polyurethane PDCA-PU; then, introduction of rare earth ion Eu3+ and small molecule ligands 1,10-phenanthroline (phen), synthesized binary and ternary polyurethane composite containing Eu3+, and comparing the fluorescence properties of the material. We investigated the thermal stability and luminescence properties of hybrids and found that the ternary hybrid materials exhibit better thermal stability and stronger emission intensity.

Synthesis and Characterization of Temperature-Sensitive TSPU/PNIPAAm Semi-IPN Polymer

2011 ◽  
Vol 399-401 ◽  
pp. 359-362 ◽  
Author(s):  
Yi Chun Wang ◽  
Zheng Wei Dai ◽  
Yuan Xue
Keyword(s):  
Chemical Structure ◽  
In Situ Polymerization ◽  
Phenyl Isocyanate ◽  
Chain Extender ◽  
Synthesis And Characterization ◽  
Temperature Sensitive ◽  
Sensitive Material ◽  
Ft Ir

Thermo-sensitive polyurethane (TSPU) was synthesized from poly(ε-caprolactone) and 4,4’-methylenebis (phenyl isocyanate) by a two-step process with 1,4-butanediol as the chain extender. Following that, a novel temperature-sensitive material was created by the strategy of IPN from TSPU and PNIPAAm in the method of in situ polymerization. The chemical structure and thermo properties of the semi-IPN were characterized with FT-IR and DSC. The results prove that intensive inter-molecular interactions exist between TSPU and PNIPAAm chains, which have significant influence on the phase transition behaviors of the material. According to these results, the transition temperature of the semi-IPN can be adjusted in the range of 30~40 °C by controlling the composition of TSPU and the semi-IPNs.

Synthesis and Characterization of Silk Fibre Reinforced Cepu Composites

2010 ◽  
Vol 123-125 ◽  
pp. 391-394 ◽  
Author(s):  
T.M. Mruthyunjaya Swamy ◽  
Manjula Koregala Sidde Gowda ◽  
Siddaramaiah ◽  
Joong Hee Lee
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Castor Oil ◽  
Glutaric Acid ◽  
Biological Fluids ◽  
Chain Extender ◽  
Synthesis And Characterization ◽  
Silk Fibre ◽  
Fibre Composites

Composites of silk fibre reinforced chain extended polyurethane (CEPU) was synthesized by the reaction of castor oil with different diisocyanates and glutaric acid as chain extender. The effect of incorporation of silk fibre into neat CEPU on the physico- mechanical properties and thermal behaviours (TGA and DMA) has been investigated. The incorporation of silk fibre into CEPUs resulted in an enhancement of tensile strength and Tg. The effects of biological fluids and salt solution on swelling behavior of CEPU biocomposites were reported. Key words: Castor oil, silk fibre, composites, polyurethane, DMA, TGA.

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