End group effect on the thermo-sensitive properties of well-defined water-soluble polystyrenics with short pendant oligo(ethylene glycol) groups synthesized by nitroxide-mediated radical polymerization

2007 ◽  
Vol 45 (16) ◽  
pp. 3707-3721 ◽  
Author(s):  
Xueguang Jiang ◽  
Bin Zhao
Keyword(s):  
Ethylene Glycol ◽  
Radical Polymerization ◽  
Water Soluble ◽  
Group Effect ◽  
End Group

Synthesis of binary-patterned brushes by combining atom transfer radical polymerization and ring-opening polymerization

e-Polymers ◽  
2013 ◽  
Vol 13 (1) ◽  
Author(s):  
Aurore Olivier ◽  
Franck Meyer ◽  
Jean-Marie Raquez ◽  
Philippe Dubois
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Ring Opening ◽  
Microcontact Printing ◽  
Gold Surface ◽  
Ring Opening Polymerization ◽  
Careful Study ◽  
Atom Transfer ◽  
Final Thickness ◽  
End Group

Abstract This paper report the synthesis of binary-patterned brushes, combining two distinctive surface initiated-polymerizations (SIP) on the basis of different propagating species: the SI Ring Opening Polymerization (ROP) of L-Lactide (LLA) and SI atom transfer radical polymerization (ATRP) of N,N’-dimethylaminoethyl methacrylate (DMAEMA) on gold surface. First of all, a careful study of surfaceinitiated ROP of L-Lactide from hydroxyl end-group of thiol monolayer on gold surface as catalyzed by metal-free catalyst was carried out. The PLLA brushes synthesis was evaluated using two types of thiol monolayer and revealed the influence of ROP initiator chain length on the final thickness of the PLLA film. Combining the soft lithographic technique, microcontact printing, and the liquid phase deposition, the deposition onto specific micro-domains of both initiators was performed. The growth of PDMAEMA brushes and PLLA brushes was conducted by successive ATRP and ROP.

AGET ATRP of water-soluble PEGMA: Fast living radical polymerization mediated by iron catalyst

2012 ◽  
Vol 50 (11) ◽  
pp. 2194-2200 ◽  
Author(s):  
Jie Miao ◽  
Weiwei He ◽  
Lifen Zhang ◽  
Yi Wang ◽  
Zhenping Cheng ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Iron Catalyst ◽  
Living Radical Polymerization ◽  
Water Soluble ◽  
Aget Atrp

scholarly journals End group functionalization of poly(ethylene glycol) with phenolphthalein: towards star-shaped polymers based on supramolecular interactions

2014 ◽  
Vol 10 ◽  
pp. 2263-2269 ◽  
Author(s):  
Carolin Fleischmann ◽  
Hendrik Wöhlk ◽  
Helmut Ritter
Keyword(s):  
Ethylene Glycol ◽  
Cycloaddition Reaction ◽  
Supramolecular Interactions ◽  
Poly Ethylene Glycol ◽  
Naked Eye ◽  
Vis Spectroscopy ◽  
End Group Functionalization ◽  
Interesting Approach ◽  
Poly Ethylene ◽  
End Group

The synthesis of a new phenolphthalein azide derivative, which can be easily utilized in polymer analogous reactions, is presented. The subsequent cycloaddition reaction with propargyl-functionalized methoxypoly(ethylene glycol) yielded polymers bearing phenolphthalein as the covalently attached end group. In presence of per-β-cyclodextrin-dipentaerythritol, the formation of stable inclusion complexes was observed, representing an interesting approach towards the formation of star shaped polymers. The decolorization of a basic polymer solution caused by the complexation was of great advantage since this behavior enabled following the complex formation by UV–vis spectroscopy and even the naked eye.

Preparation of thermo-responsive drug carrier consisting of biocompatible triblock copolymer and fullerene

2021 ◽  
Author(s):  
Kohei Kitano ◽  
Kazuhiko Ishihara ◽  
Shinichi Yusa
Keyword(s):  
Ethylene Glycol ◽  
Radical Polymerization ◽  
Triblock Copolymer ◽  
Drug Carrier ◽  
Controlled Radical Polymerization ◽  
Poly Ethylene Glycol ◽  
Poly Ethylene

A triblock copolymer (PEG-b-PUEM-b-PMPC; EUM) comprising poly(ethylene glycol) (PEG), thermo-responsive poly(2-ureidoethyl methacrylate) (PUEM), and poly(2-(methacryloyloxy)ethyl phosphorylcholine) (PMPC) blocks was synthesized via controlled radical polymerization. PEG and PMPC blocks exhibit hydrophilicity...

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