Butyl acrylate RAFT polymerization in miniemulsion

2007 ◽  
Vol 45 (11) ◽  
pp. 2304-2315 ◽  
Author(s):  
Yingwu Luo ◽  
Bei Liu ◽  
Zuohe Wang ◽  
Jin Gao ◽  
Bogeng Li
Keyword(s):  
Butyl Acrylate ◽  
Raft Polymerization

Controlled copolymerization of n-butyl acrylate with semifluorinated acrylates by RAFT polymerization

2015 ◽  
Vol 6 (3) ◽  
pp. 448-458 ◽  
Author(s):  
Senbin Chen ◽  
Wolfgang H. Binder
Keyword(s):  
Butyl Acrylate ◽  
Raft Polymerization ◽  
Reactivity Ratios ◽  
New Class ◽  
Tof Ms

A new class of well-controlled semifluorinated copolymers were successfully synthesized via RAFT polymerization. We found that ESI-TOF MS was particularly useful for readily analysing our semifluorinated copolymers. The reactivity ratios of each pair of co-monomers are close to one.

scholarly journals Synthesis of amphiphilic copolymers based on acrylic acid, fluoroalkyl acrylates and n-butyl acrylate in organic, aqueous–organic, and aqueous media via RAFT polymerization

RSC Advances ◽  
2017 ◽  
Vol 7 (39) ◽  
pp. 24522-24536 ◽  
Author(s):  
N. S. Serkhacheva ◽  
O. I. Smirnov ◽  
A. V. Tolkachev ◽  
N. I. Prokopov ◽  
A. V. Plutalova ◽  
...  
Keyword(s):  
Acrylic Acid ◽  
Polyacrylic Acid ◽  
Self Assembly ◽  
Butyl Acrylate ◽  
Raft Polymerization ◽  
Aqueous Media ◽  
Amphiphilic Copolymers

Hydrophilic and amphiphilic polymeric trithiocarbonates based on polyacrylic acid are able to provide polymerization-induced self-assembly in copolymerization of butyl and fluoroalkyl acrylates.

Direct two-step synthesis of n-butyl acrylate–acrylic acid block copolymer by RAFT polymerization

2015 ◽  
Vol 88 (10) ◽  
pp. 1667-1672 ◽  
Author(s):  
N. Yu. Shushunova ◽  
B. B. Troitskii ◽  
S. A. Chesnokov ◽  
T. A. Kovylina ◽  
M. V. Arsen’ev ◽  
...  
Keyword(s):  
Block Copolymer ◽  
Acrylic Acid ◽  
Butyl Acrylate ◽  
Raft Polymerization

Super impact strength of blends prepared from regular HIPS and poly(butyl acrylate)-block -poly(styrene) obtained by RAFT polymerization

2011 ◽  
Vol 23 (3) ◽  
pp. 375-381 ◽  
Author(s):  
Francisco J. Enríquez-Medrano ◽  
Martín Hernández-Valdez ◽  
Hortensia Maldonado-Textle ◽  
Patrick Lacroix-Desmazes ◽  
Ramiro Guerrero-Santos
Keyword(s):  
Impact Strength ◽  
Butyl Acrylate ◽  
Raft Polymerization

Grafting of n-Butyl Acrylate and N,N'-Dimethyl Acrylamide from Poly(divinylbenzene) Microspheres by RAFT Polymerization

2005 ◽  
Vol 58 (6) ◽  
pp. 468 ◽  
Author(s):  
Raymond Joso ◽  
Martina H. Stenzel ◽  
Thomas P. Davis ◽  
Christopher Barner-Kowollik ◽  
Leonie Barner
Keyword(s):  
Butyl Acrylate ◽  
Chain Transfer ◽  
Raft Polymerization ◽  
Total Reflection ◽  
Attenuated Total Reflection ◽  
Weight Increase ◽  
Reversible Addition ◽  
Raft Agent ◽  
Grafting From ◽  
Particle Weight

N,N´-Dimethyl acrylamide and n-butyl acrylate have been grafted from crosslinked poly(divinylbenzene) core microspheres by both reversible addition–fragmentation chain transfer (RAFT) polymerization and conventional free radical polymerization. The microspheres were prepared by precipitation polymerization utilizing 55 and 80 wt. % divinylbenzene (DVB), respectively. The RAFT agent cumyl dithiobenzoate (CDB) was utilized and grafting was performed in toluene at 80°C with 2,2´-azoisobutyronitrile (AIBN) as thermal initiator. Particle weights increased up to 6% for poly(n-butyl acrylate) and up to 15% for poly(N,N´-dimethyl acrylamide). Grafting from poly(DVB-55) microspheres results in a higher particle weight increase than grafting from poly(DVB-80) microspheres while using the same RAFT agent concentrations. The particle weight increase is approximately higher by a factor of two. The grafted microspheres were characterized by attenuated total reflection (ATR) IR spectroscopy and scanning electron microscopy.

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