Increasing the Tackiness of Statistical Poly(Butyl Acrylate) and Poly(Ethyl Acrylate) Network Materials via RAFT Polymerization

2015 ◽  
Vol 300 (5) ◽  
pp. 551-561
Author(s):  
Rouven Henkel ◽  
Philipp Vana
Keyword(s):  
Butyl Acrylate ◽  
Raft Polymerization ◽  
Ethyl Acrylate

Dermal oncogenicity bioassays of acrylic acid, ethyl acrylate, and butyl acrylate

1984 ◽  
Vol 14 (2-3) ◽  
pp. 115-120 ◽  
Author(s):  
Linval R. DePass ◽  
Edward H. Fowler ◽  
Daniel R. Meckley ◽  
Carrol S. Weil
Keyword(s):  
Acrylic Acid ◽  
Butyl Acrylate ◽  
Ethyl Acrylate

scholarly journals Design, Preparation, and Evaluation of a Novel Elastomer with Bio-Based Diethyl Itaconate Aiming at High-Temperature Oil Resistance

Polymers ◽  
2019 ◽  
Vol 11 (11) ◽  
pp. 1897
Author(s):  
Hui Yang ◽  
Haijun Ji ◽  
Xinxin Zhou ◽  
Weiwei Lei ◽  
Liqun Zhang ◽  
...  
Keyword(s):  
High Temperature ◽  
Butyl Acrylate ◽  
Glycidyl Methacrylate ◽  
Average Molecular Weight ◽  
Ethyl Acrylate ◽  
Number Average Molecular Weight ◽  
Elongation At Break ◽  
Oil Resistance ◽  
Monomer Ratio ◽  
Preparation And Evaluation

A novel elastomer poly(diethyl itaconate-co-butyl acrylate-co-ethyl acrylate-co-glycidyl methacrylate) (PDEBEG) was designed and synthesized by redox emulsion polymerization based on bio-based diethyl itaconate, butyl acrylate, ethyl acrylate, and glycidyl methacrylate. The PDEBEG has a number average molecular weight of more than 200,000 and the yield is up to 96%. It is easy to control the glass transition temperature of the PDEBEG, which is ranged from −25.2 to −0.8 °C, by adjusting the monomer ratio. We prepared PDEBEG/CB composites by mixing PDEBEG with carbon black N330 and studied the oil resistance of the composites. The results show that the tensile strength and the elongation at break of the composites with 10 wt% diethyl itaconate can reach up to 14.5 MPa and 305%, respectively. The mechanical properties and high-temperature oil resistance of the composites are superior to that of the commercially available acrylate rubber AR72LS.

Controlled copolymerization of n-butyl acrylate with semifluorinated acrylates by RAFT polymerization

2015 ◽  
Vol 6 (3) ◽  
pp. 448-458 ◽  
Author(s):  
Senbin Chen ◽  
Wolfgang H. Binder
Keyword(s):  
Butyl Acrylate ◽  
Raft Polymerization ◽  
Reactivity Ratios ◽  
New Class ◽  
Tof Ms

A new class of well-controlled semifluorinated copolymers were successfully synthesized via RAFT polymerization. We found that ESI-TOF MS was particularly useful for readily analysing our semifluorinated copolymers. The reactivity ratios of each pair of co-monomers are close to one.

scholarly journals Synthesis of amphiphilic copolymers based on acrylic acid, fluoroalkyl acrylates and n-butyl acrylate in organic, aqueous–organic, and aqueous media via RAFT polymerization

RSC Advances ◽  
2017 ◽  
Vol 7 (39) ◽  
pp. 24522-24536 ◽  
Author(s):  
N. S. Serkhacheva ◽  
O. I. Smirnov ◽  
A. V. Tolkachev ◽  
N. I. Prokopov ◽  
A. V. Plutalova ◽  
...  
Keyword(s):  
Acrylic Acid ◽  
Polyacrylic Acid ◽  
Self Assembly ◽  
Butyl Acrylate ◽  
Raft Polymerization ◽  
Aqueous Media ◽  
Amphiphilic Copolymers

Hydrophilic and amphiphilic polymeric trithiocarbonates based on polyacrylic acid are able to provide polymerization-induced self-assembly in copolymerization of butyl and fluoroalkyl acrylates.

Controlling the morphology of glyco-nanoparticles in water using block copolymer mixtures: the effect on cellular uptake

2015 ◽  
Vol 6 (45) ◽  
pp. 7812-7820 ◽  
Author(s):  
Aydan Dag ◽  
Hongxu Lu ◽  
Martina Stenzel
Keyword(s):  
Block Copolymer ◽  
Ethylene Glycol ◽  
Cellular Uptake ◽  
Methyl Ether ◽  
Butyl Acrylate ◽  
Diblock Copolymers ◽  
Ethyl Acrylate ◽  
Poly Ethylene Glycol ◽  
Poly Ethylene ◽  
Glycol Methyl Ether

Poly[(2-(α-d-mannosyloxy)ethyl acrylate)-block-(n-butyl acrylate)], P(ManA-b-BA), and poly[poly(ethylene glycol) methyl ether acrylate]-block-(n-butyl acrylate)], P(OEGMEA-b-BA) diblock copolymers were mixed at various ratios to generate self-assembled structures of different morphologies.

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