Controlled copolymerization of n-butyl acrylate with semifluorinated acrylates by RAFT polymerization

2015 ◽  
Vol 6 (3) ◽  
pp. 448-458 ◽  
Author(s):  
Senbin Chen ◽  
Wolfgang H. Binder
Keyword(s):  
Butyl Acrylate ◽  
Raft Polymerization ◽  
Reactivity Ratios ◽  
New Class ◽  
Tof Ms

A new class of well-controlled semifluorinated copolymers were successfully synthesized via RAFT polymerization. We found that ESI-TOF MS was particularly useful for readily analysing our semifluorinated copolymers. The reactivity ratios of each pair of co-monomers are close to one.

scholarly journals Synthesis of amphiphilic copolymers based on acrylic acid, fluoroalkyl acrylates and n-butyl acrylate in organic, aqueous–organic, and aqueous media via RAFT polymerization

RSC Advances ◽  
2017 ◽  
Vol 7 (39) ◽  
pp. 24522-24536 ◽  
Author(s):  
N. S. Serkhacheva ◽  
O. I. Smirnov ◽  
A. V. Tolkachev ◽  
N. I. Prokopov ◽  
A. V. Plutalova ◽  
...  
Keyword(s):  
Acrylic Acid ◽  
Polyacrylic Acid ◽  
Self Assembly ◽  
Butyl Acrylate ◽  
Raft Polymerization ◽  
Aqueous Media ◽  
Amphiphilic Copolymers

Hydrophilic and amphiphilic polymeric trithiocarbonates based on polyacrylic acid are able to provide polymerization-induced self-assembly in copolymerization of butyl and fluoroalkyl acrylates.

Effect of Chain Microstructure and Subphase pH on the Surface Properties and Aggregation Behavior of Amphiphilic Copolymers Based on Fluoroacrylates

2019 ◽  
Vol 816 ◽  
pp. 312-317
Author(s):  
Alexandra O. Grigoreva ◽  
E.Y. Polozov ◽  
S.D. Zaitsev
Keyword(s):  
Acrylic Acid ◽  
Surface Properties ◽  
Butyl Acrylate ◽  
Langmuir Monolayer ◽  
Aggregation Behavior ◽  
Reactivity Ratios ◽  
Water Interface ◽  
Amphiphilic Copolymers ◽  
Air Water Interface ◽  
Raft Agent

Copolymerization of 2,2,3,3,4,4,5,5-octafluoropentyl acrylate (OFPA) and acrylic acid (AA), OFPA and tert-butyl acrylate (t-BA) in presence ofdibenzylcarbonotrithioate (BTC) and polymeric RAFT-agents was studied, reactivity ratios were calculated. It was shown that type of RAFT-agent can influence on chain microstructure of obtained polymers. Aggregation behavior of obtained amphiphilic copolymers with different microstructures at the air/water interface was characterized by the Langmuir monolayer technique. The effect of the microstructureand subphase pH on the isotherm curves were shown.

Direct two-step synthesis of n-butyl acrylate–acrylic acid block copolymer by RAFT polymerization

2015 ◽  
Vol 88 (10) ◽  
pp. 1667-1672 ◽  
Author(s):  
N. Yu. Shushunova ◽  
B. B. Troitskii ◽  
S. A. Chesnokov ◽  
T. A. Kovylina ◽  
M. V. Arsen’ev ◽  
...  
Keyword(s):  
Block Copolymer ◽  
Acrylic Acid ◽  
Butyl Acrylate ◽  
Raft Polymerization
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