Theory of emulsion copolymerization kinetics

1981 ◽  
Vol 19 (4) ◽  
pp. 939-954 ◽  
Author(s):  
Mathew J. Ballard ◽  
Donald H. Napper ◽  
Robert G. Gilbert
Keyword(s):  
Emulsion Copolymerization ◽  
Copolymerization Kinetics

scholarly journals Synthesis Kinetics of Polymer / Copolymer Latexes via Radical Ring-Opening Emulsion Polymerization of Vinylcyclopropane

2016 ◽  
Vol 8 (3) ◽  
pp. 463-472
Author(s):  
P. Sarker ◽  
J. R. Ebdon ◽  
S. Rimmer ◽  
M. A. J. Miah ◽  
H. Ahmad
Keyword(s):  
Emulsion Polymerization ◽  
Ring Opening ◽  
Phase Transfer ◽  
Butyl Methacrylate ◽  
Reaction Conditions ◽  
Radical Ring ◽  
Emulsion Copolymerization ◽  
Emulsion Polymerizations ◽  
Kinetics Of ◽  
Copolymerization Kinetics

Radical emulsion polymerization of 1,1-bis(ethoxycarbonyl)-2-vinylcyclopropane (ECVCP) was examined in the presence of potassium persulfate (KPS) as an initiator. ECVCP underwent both emulsifier-in emulsion and emulsifier-free emulsion polymerizations to afford the ring-opened polymer in good yields. The copolymerization efficiency of this monomer was also evaluated with methyl methacrylate (MMA) and butyl methacrylate (BMA) as comonomers under the same reaction conditions. The emulsion copolymerization of ECVCP with a relatively hydrophobic monomer, lauryl methacrylate (LMA) was also investigated in presence of ?-cyclodextrin hydrate (?-CD) as a phase transfer agent. Polymerization/copolymerization kinetics, change in particle size and olefin contents were followed during the reaction.

Understanding the emulsion copolymerization kinetics of vinyl acetate and vinyl silanes

2020 ◽  
Vol 11 (13) ◽  
pp. 2390-2398
Author(s):  
Aitor Barquero ◽  
Fernando Ruipérez ◽  
María Jesús Barandiaran ◽  
Jose Ramon Leiza
Keyword(s):  
Free Radical ◽  
Vinyl Acetate ◽  
Emulsion Copolymerization ◽  
Vinyl Silanes ◽  
Kinetics Of ◽  
Copolymerization Kinetics

Radical entry affected by alkoxysilane monomers in free radical emulsion copolymerization with vinyl acetate.

Continuous Emulsion Copolymerization of Acrylonitrile and Butadiene:  Simulation Study for Reducing Transients during Changes of Grade

2007 ◽  
Vol 46 (23) ◽  
pp. 7677-7683 ◽  
Author(s):  
Roque J. Minari ◽  
Luis M. Gugliotta ◽  
Jorge R. Vega ◽  
Gregorio R. Meira
Keyword(s):  
Simulation Study ◽  
Emulsion Copolymerization
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