Differential Scanning Calorimetry Cure Studies of Tetra-N-glycidyldiaminodiphenylmethane Epoxy Resins. Part 1 - Reaction with 4,4′-Diaminodiphenylsulphone

1986 ◽  
Vol 18 (1) ◽  
pp. 37-43 ◽  
Author(s):  
John M. Barton
Keyword(s):  
Differential Scanning Calorimetry ◽  
Epoxy Resins ◽  
Scanning Calorimetry

Thermal Behavior of Epoxy Resins Cured with an Amine-Containing, Thermoplastic Poly(arylene Ether Sulphone)

1999 ◽  
Vol 19 (3) ◽  
pp. 161-174 ◽  
Author(s):  
Oriana Motta ◽  
Antonino Rocca ◽  
Valentina Siracusa ◽  
Domenico Acierno
Keyword(s):  
Differential Scanning Calorimetry ◽  
Thermal Behavior ◽  
Kinetic Parameters ◽  
Epoxy Resins ◽  
Curing Agent ◽  
Cure Process ◽  
Scanning Calorimetry ◽  
Arylene Ether ◽  
Diaminodiphenyl Methane ◽  
Residual Heat

Abstract In this paper we carried out the crosslinking of the tetraglycidyl-4,4′- diaminodiphenyl methane epoxy resin by using a reactive poly(arylene ether sulphone) as curing agent. Differential scanning calorimetry was used to derive the kinetic parameters of the reactions involved in the cure process and to evaluate the extent of the reaction as a function of time by measuring the total (ΔHr) and the residual heat(ΔHresid) of the resin at different curing times. A comparatively slower reaction was found to take place when the resin was cured with the poly(arylene ether sulphone) that when it was cured with the conventional curing agent 4,4′-diaminodiphenyl sulphone.

Study on Curing Mechanism of Azo-Containing Twin Liquid Crystalline Epoxy Resins with Anhydride

2013 ◽  
Vol 702 ◽  
pp. 119-122
Author(s):  
Teng Fei Shen ◽  
Fa Chao Wu ◽  
Ying Juan Sun
Keyword(s):  
Differential Scanning Calorimetry ◽  
Epoxy Resins ◽  
Liquid Crystalline ◽  
Curing Kinetics ◽  
Scanning Calorimetry ◽  
Curing Reaction ◽  
Azo Group ◽  
Liquid Crystalline Epoxy ◽  
Curing Mechanism ◽  
Kinetics Of

A series of novel azo-containing twin liquid crystalline (LC) epoxy monomers were cured with anhydrides without extra catalyst and the curing kinetics was investigated by non-isothermal differential scanning calorimetry (DSC) technique. The effect of Azo group on the Curing Kinetics of Epoxy/anhydride System was investigated and the result showed that Azo group served as a catalyst to accelerate the curing reaction. The curing mechanism was confirmed by the UV-Vis spectrum.

An improved simplified approach for curing kinetics of epoxy resins by nonisothermal differential scanning calorimetry

2017 ◽  
Vol 30 (3) ◽  
pp. 303-311 ◽  
Author(s):  
Chao Chen ◽  
Yanxia Li ◽  
Yizhuo Gu ◽  
Min Li ◽  
Zuoguang Zhang
Keyword(s):  
Differential Scanning Calorimetry ◽  
Epoxy Resin ◽  
Kinetic Parameters ◽  
Epoxy Resins ◽  
Curing Kinetics ◽  
Scanning Calorimetry ◽  
Simplified Approach ◽  
Curing Kinetic ◽  
Autocatalytic Curing ◽  
Kinetics Of

The curing kinetics of two different types of commercial epoxy resins were investigated by means of nonisothermal differential scanning calorimetry (DSC) in this work. The complex curve of measured heat flow of CYCOM 970 epoxy resin was simplified with the method of resolution of peak. Two typical autocatalytic curing reaction curves were gained and the kinetic parameters of the curing process were demonstrated by combination of those two reactions. The Kissinger method was adopted to obtain the values of the activation energy. The parameters of curing kinetic model were acquired according to the fitting of Kamal model. Isothermal DSC curve of CYCOM 970 epoxy resin obtained using the experimental data shows a good agreement with that theoretically calculated. Then, 603 epoxy resin was investigated by the simplified method and the kinetic parameters were received through the same procedure. The nonisothermal DSC curve tested according to the recommended cure cycle of 603 epoxy resin is also consistent with the calculated results. This improved simplified approach provides an effective method to analyze the curing kinetics of the epoxy resins with complex DSC curves as similar to this study.

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