Advanced development of dairy farm waste-based biocarbon-reinforced unsymmetrical structured biophenols polybenzoxazine composites

In the present work, an attempt has been made to develop cow manure carbon-reinforced hybrid biophenol-based benzoxazine composites for antifouling coating applications. Bio-based benzoxazine with unsymmetrical molecular structure was synthesized using the mixture of a combination of cardanol and eugenol with diaminodiphenyl methane and paraformaldehyde, and the hybrid-benzoxazine obtained was characterized using different analytical techniques, viz., Fourier transform infrared, nuclear magnetic resonance and MALDI mass. Bio-based benzoxazine was further reinforced with varying weight percentages (1, 3 and 5 wt%) of biocarbon derived from cow manure to obtain hybrid composite coatings. The hybrid benzoxazine matrix and composites were studied for their thermal behaviour, contact angle (CA), morphology, corrosion-resistant behaviour and antifouling character to utilize them as coatings materials for different industrial applications. Results obtained from different studies inferred that the biocarbon-reinforced composites possess an enhanced value of glass transition temperature (249°C), high char yield (38.4%), improved CA (105.6°), higher efficiency of corrosion protection against mild steel surface (98%) and improved antimicrobial activity.

Interpretation of the mechanism of 3,3′-dichloro-4,4′-diamino diphenylmethane synthesis over HY zeolites

Catalytic activities of zeolites HY, Hβ and HZSM-5 in the heterogeneous synthesis of 3,3′-dichloro-4,4′-diaminodiphenyl methane (MOCA) from o-chloroaniline and formaldehyde were pre-screened in an autoclave, and HY demonstrated better performance than others.