Surface properties and thermal stability of a novel low-surface-energy polybenzoxazine/clay nanocomposites

2012 ◽  
Vol 33 (8) ◽  
pp. 1313-1320 ◽  
Author(s):  
Huijie Dong ◽  
Zhong Xin ◽  
Xin Lu ◽  
Li Qu
2013 ◽  
Vol 98 (12) ◽  
pp. 2497-2502 ◽  
Author(s):  
Stephen F. Bartolucci ◽  
Karen E. Supan ◽  
Jeffrey S. Wiggins ◽  
Lawrence LaBeaud ◽  
Jeffrey M. Warrender

2020 ◽  
Vol 20 (7) ◽  
pp. 4193-4197
Author(s):  
Seong Deok Seo ◽  
Kyung Chan Kang ◽  
Ji Won Jeong ◽  
Seung Min Lee ◽  
Ju Dong Lee ◽  
...  

The PMMA (poly methyl methacrylate)/clay nanocomposite powders were synthesized by In-Situ suspension polymerizations using microwave heating. The PMMA/clay nanocomposites were also sampled using injection moulding to make specimens for material characterization. Transmission electron microscopy (TEM) and X-ray diffraction (XRD) indicated the formation of a highly intercalated clay layer in the nanocomposites. It was found that the microstructure of PMMA/clay nanocomposites was strongly dependent of content of clay. Thermo gravimetric analysis (TGA) indicated an improvement in the thermal stability of nanocomposites compared to that of the pure PMMA. Differential scanning calorimetry (DSC) showed that the nanocomposites had a higher glass transition (Tg) temperature than the PMMA. Fourier-transform infrared (FT-IR) spectroscopy indicated an interaction between the carbonyl group of PMMA and hydroxyl group of the clay. Therefore, a possible reason in enhanced material properties of nanocomposites is that the chemical interaction and nanostructure of PMMA polymer and intercalated inorganic silicate layer has increased the thermal stability of the PMMA/clay nanocomposites.


2006 ◽  
Vol 91 (12) ◽  
pp. 3149-3155 ◽  
Author(s):  
Defeng Wu ◽  
Liang Wu ◽  
Lanfeng Wu ◽  
Ming Zhang

1992 ◽  
Vol 280 ◽  
Author(s):  
Y. W. Kim ◽  
I. K. Kim ◽  
N. I. Lee ◽  
J. W. Ko ◽  
S. T. Ahn ◽  
...  

ABSTRACTThe effect of the crystallographic orientation of underlying poly-Si film on the thermal stability of the TiSi2 film was studied. Different preferred orientations of the poly-Si film were obtained by annealing poly-Si or amorphous Si films at various temperatures. The TiSi2 film was formed by the solid-state reaction of the Ti film sputtered on the poly-Si film. The thermal stability of the TiSi2 film was evaluated by changes in the sheet resistance and microstructural evolution during furnace anneals. The TiSi2 film on poly-Si with the <110> preferred orientation shows more stable conductivity during high temperature anneals than with the <111> orientation. The surface energy of underlying poly-Si is expected to influence the thermal stability of the TiSi2/poly-Si structure significantly. Better thermal stability of the TiSi2 film can be obtained by the higher surface energy of underlying poly-Si.


2010 ◽  
Vol 20 (41) ◽  
pp. 9205 ◽  
Author(s):  
Magali Bonne ◽  
Stéphane Pronier ◽  
Yann Batonneau ◽  
Fabien Can ◽  
Xavier Courtois ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document