Studies of Allyl Alcohol Radical Polymerization by PFG-HMQC and HMBC NMR at 750 MHz

2002 ◽  
Vol 35 (7) ◽  
pp. 2602-2607 ◽  
Author(s):  
Sung Joon Oh ◽  
David R. Kinney ◽  
Wei Wang ◽  
Peter L. Rinaldi
Keyword(s):  
Radical Polymerization ◽  
Allyl Alcohol ◽  
Alcohol Radical

Synthesis and Radical Polymerizations of N-Substituted Maleimide Bearing Two Olefinic Groups

2014 ◽  
Vol 1033-1034 ◽  
pp. 619-622
Author(s):  
Hua Jing Gao ◽  
Zhao Hui Jin
Keyword(s):  
Maleic Anhydride ◽  
Radical Polymerization ◽  
Allyl Alcohol ◽  
Optically Active ◽  
Optically Active Polymers ◽  
Allyl Ester ◽  
Radical Polymerizations ◽  
Alcohol Radical

A kind of N-substituted maleimide - having two olefinic bonds with different reactivities, (S)-N-Maleoyl-L-leucine allyl ester ((S)-ALMI), was synthesized from maleic anhydride, L-leucine and allyl alcohol. Radical polymerizations were carried out to obtain optically active polymers using 2,2′-azobisisobutyronitrile. Structures of the monomer and polymers obtained were investigated by NMR measurements. In radical polymerizations, the solvents strongly affect the radical polymerization behaviors of (S)-ALMI.

Radical polymerization of allyl alcohol and allyl acetate

2007 ◽  
Vol 18 (12) ◽  
pp. 953-958 ◽  
Author(s):  
Kokoro Iio ◽  
Kentaro Kobayashi ◽  
Mutsuo Matsunaga
Keyword(s):  
Radical Polymerization ◽  
Allyl Alcohol ◽  
Allyl Acetate

A Route to Modify Polymeric Pigment Dispersants with Polysiloxanes by Atom Transfer Radical Polymerization

2012 ◽  
Vol 441 ◽  
pp. 478-483 ◽  
Author(s):  
Chuan Xia Huang ◽  
Ling Min Yi ◽  
Hao Yu Yuan ◽  
Chang Qin Chen
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Butyl Acrylate ◽  
Allyl Alcohol ◽  
Graft Copolymers ◽  
Catalyst System ◽  
Side Chains ◽  
Atom Transfer ◽  
Novel Approach ◽  
Dispersing Agents

A novel approach to modify polymeric pigment dispersants with polysiloxanes was developed based on the sequential atom transfer radical polymerization (ATRP) of styrene (St) and tert-butyl acrylate (tBA), using multifunctional α-bromoisobutyryl-containing poly (dimethylsiloxane) (PDMS-Brm) as the macroinitiators and CuBr/N,N,N,N,N- pentamethyldiethylenetriamine (PMDETA) as the catalyst system. The PDMS-Brm macroinitiators were obtained from the sequential hydrosilylation of commercially available methyl polysiloxanes containing SiH groups with allyl alcohol and then α-bromoisobutyryl bromide. And then, a series of well-defined comb-like graft copolymers with a PDMS backbone and several polystyrene-block-poly (tert-butyl acrylate) (PS-b-PtBA) side-chains were synthesized via ATRP. After hydrolyzing the tert-butyl groups, the comb-like copolymers may serve as multifunctional dispersing agents in the pigment printing.

Reactions of alcohols adsorbed on MgO. Part I. Heterogeneous reactions with hydrogen atoms and trapped electrons at room temperature: a new technique in surface chemistry

1969 ◽  
Vol 47 (8) ◽  
pp. 1381-1389 ◽  
Author(s):  
D. R. Smith ◽  
A. J. Tench
Keyword(s):  
Allyl Alcohol ◽  
Room Temperature ◽  
Heterogeneous Reactions ◽  
Hydrogen Atoms ◽  
Hydrogen Elimination ◽  
Oxygen Ion ◽  
Spin Resonance ◽  
A New Technique ◽  
Mgo Surface ◽  
Alcohol Radical

A series of alcohols, adsorbed on MgO powder, have been bombarded by a stream of hydrogen atoms at room temperature and the radicals thus formed are detected by electron spin resonance. Methanol, ethanol, n-propanol, iso-propanol, n-butanol, sec-butanol, and allyl alcohol have been studied. The radical species produced have been identified and radical lifetimes varying from minutes to hours at 300 °K have been observed. For methanol, the first monolayer appears to be chemisorbed as methoxy groups whereas the ethanol data indicate that some of the molecules in the first monolayer are physically adsorbed. The higher alcohols form secondary radicals via hydrogen elimination from the primary radical; the isopropyl alcohol radical appears to isomerize before losing hydrogen. Allyl alcohol undergoes hydrogen atom abstraction in preference to addition to the double bond and yields the α-hydroxy-allyl radical. Methanol and ethanol have also been reacted with electrons trapped on a MgO surface to form stable alkoxide ion radicals trapped at oxygen ion vacancies on the surface of the lattice.

Non-isothermal Kinetics of Free Radical Polymerization of 2-Phenylethyl (Meth)acrylate

2018 ◽  
Vol 8 (3) ◽  
pp. 585-594
Author(s):  
Khdbudin Mulani ◽  
Ravindra Ghorpade ◽  
Surendra Ponrathnam ◽  
Nayaku Chavan ◽  
Kamini Donde
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Isothermal Kinetics ◽  
Kinetics Of
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