Tough epoxy/cyanate ester resins with improved thermal stability, lower dielectric constant and loss based on unique hyperbranched polysiloxane liquid crystalline

2015 ◽  
Vol 26 (12) ◽  
pp. 1608-1618 ◽  
Author(s):  
Zhen Liu ◽  
Li Yuan ◽  
Guozheng Liang ◽  
Aijuan Gu
2019 ◽  
Vol 9 (5) ◽  
pp. 881 ◽  
Author(s):  
Zhicong Miao ◽  
Juntao Shi ◽  
Tianjiao Liu ◽  
Peng Li ◽  
Zhiqiang Su ◽  
...  

The conjugation of graphene and polymers has attracted great attention for the fabrication of functional hybrid nanomaterials. Here, we demonstrate the modification of graphene oxide (GO) with adamantane (AMT) through the diimide-activated amidation reaction. The modification of GO with AMT improves the dispersion and decreases the interfacial polarization of GO, causing a lower dielectric constant for the fabricated GO/AMT hybrid materials. The structures of GO/AMT were studied by Fourier transform infrared spectroscopy and Raman spectroscopy. Furthermore, the mechanical properties, thermal stability, and dielectric constant of GO/AMT composites were measured at a low cured temperature using various techniques, such as differential scanning calorimetry, thermogravimetric analysis, and dynamic mechanical thermal analysis. It was found that the synthesized GO/AMT materials with different contents were blended into cyanate ester (CE) resins, resulting in a lower cure temperature, smaller dielectric constant, higher thermal stability, and stronger water resistance. It is expected that this novel GO/AMT-CE material will have potential applications for replacing traditional thermosetting resins.


2001 ◽  
Vol 682 ◽  
Author(s):  
Max D. Alexander ◽  
Thuy D. Dang ◽  
Christina E. Specker ◽  
Marlene Houtz ◽  
R.J. Spry ◽  
...  

ABSTRACTNext generation microelectronic packaging requirements are driving the need to produce increasingly lower dielectric constant materials while maintaining high thermal stability and ease of processing. Polymer candidates with exceptionally low dielectric constant (2.0-2.4), high thermal stability (degradation temperature higher than 400°C), high glass transition temperature (greater than 350°C), low water uptake (less than one percent), solubility in selected organic solvents, and low thermal expansion are all required. We have successfully synthesized and characterized several candidate polymers in an effort to address these needs.


2011 ◽  
Vol 22 (12) ◽  
pp. 2617-2625 ◽  
Author(s):  
Dongxian Zhuo ◽  
Aijuan Gu ◽  
Guozheng Liang ◽  
Jiang-tao Hu ◽  
Cheng Zhou ◽  
...  

RSC Advances ◽  
2014 ◽  
Vol 4 (101) ◽  
pp. 57759-57767 ◽  
Author(s):  
Mathivathanan Ariraman ◽  
Ramachandran Sasi kumar ◽  
Muthukaruppan Alagar

The continual development of microelectronics needs insulation materials with lower dielectric constant (low k).


2015 ◽  
Vol 120 ◽  
pp. 402-409 ◽  
Author(s):  
Kristina Gusakova ◽  
Jean-Marc Saiter ◽  
Olga Grigoryeva ◽  
Fabrice Gouanve ◽  
Alexander Fainleib ◽  
...  

2012 ◽  
Vol 19 (06) ◽  
pp. 1250063 ◽  
Author(s):  
ZHAO DU ◽  
XUEHONG ZHANG ◽  
YUNLONG YUE ◽  
HAITAO WU

The effect of MgO on structure and dielectric properties of aluminoborosilicate glasses was investigated. FTIR data indicated that glass network was mainly built by tetrahedral [ SiO4 ], [ BO4 ], [ AlO4 ] and trigonal [ BO3 ]. A small amount of AlO5 or AlO6 units also existed. The glass system was characterized with lower dielectric constant (4.17 ~ 4.6) and dielectric loss (12.3 × 10-4 ~ 14.77 × 10-4) at 1 MHz. With the increase of MgO content, the quantity of AlO5 or AlO6 units decreased. The variation of density showed a decreasing tendency. The dielectric constant and loss were all found to decrease.


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