Controlling Ordered Structures of PS-b-P2VP Block Copolymer Thin Film by Tuning Solvent Evaporation Rate

2017 ◽  
Vol 371 (1) ◽  
pp. 75-83 ◽  
Author(s):  
Siti Aisyah Shamsudin ◽  
Takenaka Mikihito ◽  
Hasegawa Hirokazu
Keyword(s):  
Thin Film ◽  
Block Copolymer ◽  
Evaporation Rate ◽  
Solvent Evaporation ◽  
Ordered Structures

Morphological Evolution of Block Copolymer Particles: Effect of Solvent Evaporation Rate on Particle Shape and Morphology

ACS Nano ◽  
2017 ◽  
Vol 11 (2) ◽  
pp. 2133-2142 ◽  
Author(s):  
Jae Man Shin ◽  
YongJoo Kim ◽  
Hongseok Yun ◽  
Gi-Ra Yi ◽  
Bumjoon J. Kim
Keyword(s):  
Block Copolymer ◽  
Particle Shape ◽  
Evaporation Rate ◽  
Morphological Evolution ◽  
Solvent Evaporation ◽  
Effect Of Solvent

Electrolysis on a Chip with Tunable Thin Film Nanostructured PGM Electrocatalysts Generated from Self‐Assembled Block Copolymer Templates

Small ◽  
2021 ◽  
pp. 2100437
Author(s):  
Deepra Bhattacharya ◽  
Subarna Kole ◽  
Orhan Kizilkaya ◽  
Joseph Strzalka ◽  
Polyxeni P. Angelopoulou ◽  
...  
Keyword(s):  
Thin Film ◽  
Block Copolymer ◽  
Self Assembled

Facile synthesis of mesoporous TiO2 film templated by block copolymer for photocatalytic applications

2021 ◽  
Author(s):  
Olufemi Olatidoye ◽  
Daria Thomas ◽  
Bishnu Bastakoti
Keyword(s):  
Thin Film ◽  
Block Copolymer ◽  
Ethylene Oxide ◽  
Tio2 Thin Film ◽  
Polymeric Micelles ◽  
Polymeric Micelle ◽  
Mesoporous Tio2 ◽  
Facile Synthesis ◽  
Vinyl Pyridine ◽  
Photocatalytic Applications

A facile synthesis of a mesoporous TiO2 thin film is reported using poly(styrene-2-vinyl pyridine-ethylene oxide) polymeric micelle as a synthetic template. As the Ti precursor strongly binds with polymeric micelles...

scholarly journals Precise Synthesis and Thin Film Self-Assembly of PLLA-b-PS Bottlebrush Block Copolymers

Molecules ◽  
2021 ◽  
Vol 26 (5) ◽  
pp. 1412
Author(s):  
Eunkyung Ji ◽  
Cian Cummins ◽  
Guillaume Fleury
Keyword(s):  
Thin Film ◽  
Block Copolymers ◽  
Self Assembly ◽  
Ring Opening ◽  
Periodic Structures ◽  
One Pot ◽  
Ordered Structures ◽  
Carbonyl Chloride ◽  
Thin Film Patterning ◽  
Nanoporous Templates

The ability of bottlebrush block copolymers (BBCPs) to self-assemble into ordered large periodic structures could greatly expand the scope of photonic and membrane technologies. In this paper, we describe a two-step synthesis of poly(l-lactide)-b-polystyrene (PLLA-b-PS) BBCPs and their rapid thin-film self-assembly. PLLA chains were grown from exo-5-norbornene-2-methanol via ring-opening polymerization (ROP) of l-lactide to produce norbornene-terminated PLLA. Norbonene-terminated PS was prepared using anionic polymerization followed by a termination reaction with exo-5-norbornene-2-carbonyl chloride. PLLA-b-PS BBCPs were prepared from these two norbornenyl macromonomers by a one-pot sequential ring opening metathesis polymerization (ROMP). PLLA-b-PS BBCPs thin-films exhibited cylindrical and lamellar morphologies depending on the relative block volume fractions, with domain sizes of 46–58 nm and periodicities of 70–102 nm. Additionally, nanoporous templates were produced by the selective etching of PLLA blocks from ordered structures. The findings described in this work provide further insight into the controlled synthesis of BBCPs leading to various possible morphologies for applications requiring large periodicities. Moreover, the rapid thin film patterning strategy demonstrated (>5 min) highlights the advantages of using PLLA-b-PS BBCP materials beyond their linear BCP analogues in terms of both dimensions achievable and reduced processing time.

Transfer of Pre-Assembled Block Copolymer Thin Film to Nanopattern Unconventional Substrates

2014 ◽  
Vol 6 (12) ◽  
pp. 9442-9448 ◽  
Author(s):  
Jonathan W. Choi ◽  
Myungwoong Kim ◽  
Nathaniel S. Safron ◽  
Michael S. Arnold ◽  
Padma Gopalan
Keyword(s):  
Thin Film ◽  
Block Copolymer

scholarly journals Effect of annealing and UV-radiation time over micropore architecture of self-assembled block copolymer thin film

2015 ◽  
Vol 9 (6) ◽  
pp. 525-535 ◽  
Author(s):  
G. del C. Pizarro ◽  
O. G. Marambio ◽  
M. Jeria-Orell ◽  
C. M. Gonzalez-Henriquez ◽  
M. Sarabia-Vallejos ◽  
...  
Keyword(s):  
Thin Film ◽  
Block Copolymer ◽  
Uv Radiation ◽  
Self Assembled ◽  
Radiation Time

scholarly journals Publisher’s Note: “Origin of thermally stable ferroelectricity in a porous barium titanate thin film synthesized through block copolymer templating” [APL Mater. 5, 076111 (2017)]

APL Materials ◽  
2017 ◽  
Vol 5 (9) ◽  
pp. 099901
Author(s):  
Norihiro Suzuki ◽  
Minoru Osada ◽  
Motasim Billah ◽  
Zeid Abdullah Alothman ◽  
Yoshio Bando ◽  
...  
Keyword(s):  
Thin Film ◽  
Block Copolymer ◽  
Barium Titanate ◽  
Thermally Stable ◽  
Barium Titanate Thin Film ◽  
Titanate Thin Film

Large scale alignment of a lamellar block copolymer thin film via electric fields: a time-resolved SFM study

Soft Matter ◽  
2006 ◽  
Vol 2 (12) ◽  
pp. 1089-1094 ◽  
Author(s):  
Violetta Olszowka ◽  
Markus Hund ◽  
Volker Kuntermann ◽  
Sabine Scherdel ◽  
Larisa Tsarkova ◽  
...  
Keyword(s):  
Thin Film ◽  
Block Copolymer ◽  
Electric Fields ◽  
Large Scale ◽  
Time Resolved ◽  
Large Scale Alignment
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