Synthetic Potassium Vanadium Oxide K2V6O16·1.5H2O Superlong Nanobelts: A 1D Room-Temperature Ferromagnetic Semiconductor

2013 ◽  
Vol 2013 (20) ◽  
pp. 3497-3505 ◽  
Author(s):  
Liangfei Bai ◽  
Yan Xue ◽  
Jiajia Zhang ◽  
Bicai Pan ◽  
Changzheng Wu
ChemInform ◽  
2013 ◽  
Vol 44 (49) ◽  
pp. no-no
Author(s):  
Liangfei Bai ◽  
Yan Xue ◽  
Jiajia Zhang ◽  
Bicai Pan ◽  
Changzheng Wu

2012 ◽  
Vol 22 (6) ◽  
pp. 2560-2565 ◽  
Author(s):  
Yan Xue ◽  
Xiaodong Zhang ◽  
Jiajia Zhang ◽  
Jian Wu ◽  
Yongfu Sun ◽  
...  

2004 ◽  
Vol 262 (1-4) ◽  
pp. 287-289 ◽  
Author(s):  
Fuqiang Zhang ◽  
NuoFu Chen ◽  
Xianglin Liu ◽  
Zhikai Liu ◽  
Shaoyan Yang ◽  
...  

Nanomaterials ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 317 ◽  
Author(s):  
Haihong Yin ◽  
Changqing Song ◽  
Zhiliang Wang ◽  
Haibao Shao ◽  
Yi Li ◽  
...  

VO2(B), VO2(M), and V2O5 are the most famous compounds in the vanadium oxide family. Here, their gas-sensing properties were investigated and compared. VO2(B) nanoflakes were first self-assembled via a hydrothermal method, and then VO2(M) and V2O5 nanoflakes were obtained after a heat-phase transformation in nitrogen and air, respectively. Their microstructures were evaluated using X-ray diffraction and scanning and transmission electron microscopies, respectively. Gas sensing measurements indicated that VO2(M) nanoflakes were gas-insensitive, while both VO2(B) and V2O5 nanoflakes were highly selective to ammonia at room temperature. As ammonia sensors, both VO2(B) and V2O5 nanoflakes showed abnormal p-type sensing characteristics, although vanadium oxides are generally considered as n-type semiconductors. Moreover, V2O5 nanoflakes exhibited superior ammonia sensing performance compared to VO2(B) nanoflakes, with one order of magnitude higher sensitivity, a shorter response time of 14–22 s, and a shorter recovery time of 14–20 s. These characteristics showed the excellent potential of V2O5 nanostructures as ammonia sensors.


2014 ◽  
Vol 1053 ◽  
pp. 332-336 ◽  
Author(s):  
Ya Qiao ◽  
Yuan Lu ◽  
Hua Yang ◽  
Yong Shun Ling

Low valence vanadium oxide thin film was deposited on ordinary glass substrates by direct current (DC) magnetron sputtering from a vanadium metal target. And then it was annealed in an atmosphere of oxygen/argon mixture at the temperature of 450°C for 2hours to obtain VO2thin film possessing the ability of phase transition. The XRD patterns and resistance-temperature (R-T) curves of the film before and after the annealing were given. The results show that: the as-deposited film, whose main component is V2O3, presents no phase transition and its resistance changes from 1.26 kΩ~1.01kΩ while its temperature rising from room temperature to 80°C; the annealed film, whose main component is VO2, presents a phase transition when its temperature rising from room temperature to 80°C and its resistance changes from 10kΩ to 60Ω, more than two orders. And the phase transition temperature of the film deposited is only 30°C.


2004 ◽  
Vol 848 ◽  
Author(s):  
Olivier Durupthy ◽  
Saïd Es-salhi ◽  
Nathalie Steunou ◽  
Thibaud Coradin ◽  
Jacques Livage

ABSTRACTVarious cations (Li+, Na+, K+, NH4+, Cs+, Mg2+, Ca2+, Ba2+) were introduced during the formation of a V2O5. nH2O gel. Cation intercalated Xy V2O5. nH2O (y = 0.3 for X = Li+, Na+, K+, NH4+ or y = 0.15 for Mg2+, Ca2+, Ba2+) were first obtained at room temperature but some of them evolve upon ageing into a new phase: XV3O8. nH2O for X = Na+, K+, NH4+ and Cs+ or XV6O16. nH2O for X = Mg2+, Ca2+, Ba2+. All the vanadium oxide phases were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and infrared spectroscopy (IR); the supernatant solutions were analysed by 51V NMR spectroscopy. These vanadium oxide phases exhibit a layered structure with cations and water molecules intercalated within the interlayer space. The formation of the different phases depends mainly on the pH of the supernatant solution and on the nature of the cation.


2019 ◽  
Vol 294 ◽  
pp. 17-24 ◽  
Author(s):  
Shrouk E. Zaki ◽  
Mohamed A. Basyooni ◽  
Mohamed Shaban ◽  
Mohamed Rabia ◽  
Yasin Ramazan Eker ◽  
...  

1999 ◽  
Vol 38 (25) ◽  
pp. 5709-5715 ◽  
Author(s):  
R. C. Bell ◽  
A. W. Castleman ◽  
D. L. Thorn

2016 ◽  
Vol 22 (4) ◽  
pp. 901-904 ◽  
Author(s):  
A. A Akande ◽  
K. E Rammutla ◽  
B. P Dhonge ◽  
A. G. J Machatine ◽  
B. W Mwakikunga

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