Gold-Catalyzed Reductive Transformation of Nitro Compounds Using Formic Acid: Mild, Efficient, and Versatile

ChemSusChem ◽  
2015 ◽  
Vol 8 (18) ◽  
pp. 3029-3035 ◽  
Author(s):  
Lei Yu ◽  
Qi Zhang ◽  
Shu-Shuang Li ◽  
Jun Huang ◽  
Yong-Mei Liu ◽  
...  
Keyword(s):  
Formic Acid ◽  
Nitro Compounds ◽  
Reductive Transformation

ChemInform Abstract: Gold-Catalyzed Reductive Transformation of Nitro Compounds Using Formic Acid: Mild, Efficient, and Versatile.

ChemInform ◽  
2016 ◽  
Vol 47 (6) ◽  
pp. no-no
Author(s):  
Lei Yu ◽  
Qi Zhang ◽  
Shu-Shuang Li ◽  
Jun Huang ◽  
Yong-Mei Liu ◽  
...  
Keyword(s):  
Formic Acid ◽  
Nitro Compounds ◽  
Reductive Transformation

ChemInform Abstract: Heterogeneous Gold-Catalyzed Selective Reductive Transformation of Quinolines with Formic Acid.

ChemInform ◽  
2015 ◽  
Vol 46 (30) ◽  
pp. no-no
Author(s):  
Lei Tao ◽  
Qi Zhang ◽  
Shu-Shuang Li ◽  
Xiang Liu ◽  
Yong-Mei Liu ◽  
...  
Keyword(s):  
Formic Acid ◽  
Reductive Transformation

ChemInform Abstract: Nickel-Catalyzed Formic Acid Reductions. A Selective Method for the Reduction of Nitro Compounds.

ChemInform ◽  
2000 ◽  
Vol 31 (45) ◽  
pp. no-no
Author(s):  
D. Channe Gowda ◽  
A. S. Prakasha Gowda ◽  
A. Ramesha Baba ◽  
Shankare Gowda
Keyword(s):  
Formic Acid ◽  
Nitro Compounds ◽  
Selective Method

Heterogeneous Gold-Catalyzed Selective Reductive Transformation of Quinolines with Formic Acid

2015 ◽  
Vol 357 (4) ◽  
pp. 753-760 ◽  
Author(s):  
Lei Tao ◽  
Qi Zhang ◽  
Shu-Shuang Li ◽  
Xiang Liu ◽  
Yong-Mei Liu ◽  
...  
Keyword(s):  
Formic Acid ◽  
Reductive Transformation

Recyclable Silica-Supported Iridium Catalysts for Selective Reductive Transformation of Quinolines with Formic Acid in Water

ChemCatChem ◽  
2017 ◽  
Vol 9 (13) ◽  
pp. 2496-2505 ◽  
Author(s):  
Jing-Fan Zhang ◽  
Rui Zhong ◽  
Quan Zhou ◽  
Xi Hong ◽  
Shuang Huang ◽  
...  
Keyword(s):  
Formic Acid ◽  
Iridium Catalysts ◽  
Reductive Transformation

Design of new aliphatic azido nitro compounds as plasticizer: an initial exploration on AFCTEE (1-azido-formic acid 1,1,1-trinitro-ethyl ester)

2015 ◽  
Vol 93 (7) ◽  
pp. 690-695 ◽  
Author(s):  
Junqing Yang ◽  
Xuedong Gong ◽  
Guixiang Wang
Keyword(s):  
Thermal Stability ◽  
Formic Acid ◽  
Ethyl Ester ◽  
Chemical Stability ◽  
Density Functional ◽  
High Energy ◽  
Nitro Compounds ◽  
Functional Theory ◽  
Energetic Properties ◽  
Initial Exploration

To explore new high-energy azido nitro compounds as plasticizers for propellants, AFCTEE (1-azido-formic acid 1,1,1-trinitro-ethyl ester) was designed and studied using density functional theory. The predicted density of AFCTEE, 1.90 gcm−3, is comparable to that of HMX (1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane) and much higher than that of general organic azido compounds. AFCTEE possesses higher energetic properties and chemical stability than the promising azido nitro plasticizer DAMNP (1,3-diazido-2-methyl-2-nitropropane) and the conventional plasticizer NG (nitroglycerine), and it has a moderate thermal stability. The pyrolysis of AFCTEE starts from the rupture of C–NO2 and then the breakage of N–N2 via Curtius rearrangement. This work is the initial exploration for AFCTEE, aiming at the energetics, spectra (IR, NMR, and UV), stability, and decomposition mechanism. Compared with DAMNP, the advantages of superior energetic properties and chemical stability suggest AFCTEE is a promising energetic azido nitro compound and is worth further investigation.

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