ChemInform Abstract: Nickel-Catalyzed Formic Acid Reductions. A Selective Method for the Reduction of Nitro Compounds.

ChemInform ◽  
2000 ◽  
Vol 31 (45) ◽  
pp. no-no
Author(s):  
D. Channe Gowda ◽  
A. S. Prakasha Gowda ◽  
A. Ramesha Baba ◽  
Shankare Gowda
Keyword(s):  
Formic Acid ◽  
Nitro Compounds ◽  
Selective Method

Nickel-Catalyzed Formic Acid Reductions. A Selective Method for the Reduction of Nitro Compounds

2000 ◽  
Vol 30 (16) ◽  
pp. 2889-2895 ◽  
Author(s):  
D. Channe Gowda ◽  
A. S. Prakasha Gowda ◽  
A. Ramesha Baba ◽  
Shankare Gowda
Keyword(s):  
Formic Acid ◽  
Nitro Compounds ◽  
Selective Method

ChemInform Abstract: Gold-Catalyzed Reductive Transformation of Nitro Compounds Using Formic Acid: Mild, Efficient, and Versatile.

ChemInform ◽  
2016 ◽  
Vol 47 (6) ◽  
pp. no-no
Author(s):  
Lei Yu ◽  
Qi Zhang ◽  
Shu-Shuang Li ◽  
Jun Huang ◽  
Yong-Mei Liu ◽  
...  
Keyword(s):  
Formic Acid ◽  
Nitro Compounds ◽  
Reductive Transformation

Design of new aliphatic azido nitro compounds as plasticizer: an initial exploration on AFCTEE (1-azido-formic acid 1,1,1-trinitro-ethyl ester)

2015 ◽  
Vol 93 (7) ◽  
pp. 690-695 ◽  
Author(s):  
Junqing Yang ◽  
Xuedong Gong ◽  
Guixiang Wang
Keyword(s):  
Thermal Stability ◽  
Formic Acid ◽  
Ethyl Ester ◽  
Chemical Stability ◽  
Density Functional ◽  
High Energy ◽  
Nitro Compounds ◽  
Functional Theory ◽  
Energetic Properties ◽  
Initial Exploration

To explore new high-energy azido nitro compounds as plasticizers for propellants, AFCTEE (1-azido-formic acid 1,1,1-trinitro-ethyl ester) was designed and studied using density functional theory. The predicted density of AFCTEE, 1.90 gcm−3, is comparable to that of HMX (1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane) and much higher than that of general organic azido compounds. AFCTEE possesses higher energetic properties and chemical stability than the promising azido nitro plasticizer DAMNP (1,3-diazido-2-methyl-2-nitropropane) and the conventional plasticizer NG (nitroglycerine), and it has a moderate thermal stability. The pyrolysis of AFCTEE starts from the rupture of C–NO2 and then the breakage of N–N2 via Curtius rearrangement. This work is the initial exploration for AFCTEE, aiming at the energetics, spectra (IR, NMR, and UV), stability, and decomposition mechanism. Compared with DAMNP, the advantages of superior energetic properties and chemical stability suggest AFCTEE is a promising energetic azido nitro compound and is worth further investigation.

Unprecedented catalytic performance in amine syntheses via Pd/g-C3N4 catalyst-assisted transfer hydrogenation

2018 ◽  
Vol 20 (9) ◽  
pp. 2038-2046 ◽  
Author(s):  
Xingliang Xu ◽  
Jiajun Luo ◽  
Liping Li ◽  
Dan Zhang ◽  
Yan Wang ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Formic Acid ◽  
Catalytic Performance ◽  
Nitro Compounds ◽  
Hydrogen Donor ◽  
Transfer Hydrogenation ◽  
Secondary Amines ◽  
Primary And Secondary Amines

A Pd/g-C3N4 catalyst exhibited a superb performance in the transfer hydrogenation of nitro compounds to generate their corresponding primary and secondary amines with formic acid as the hydrogen donor in aqueous solution.

Gold-Catalyzed Reductive Transformation of Nitro Compounds Using Formic Acid: Mild, Efficient, and Versatile

ChemSusChem ◽  
2015 ◽  
Vol 8 (18) ◽  
pp. 3029-3035 ◽  
Author(s):  
Lei Yu ◽  
Qi Zhang ◽  
Shu-Shuang Li ◽  
Jun Huang ◽  
Yong-Mei Liu ◽  
...  
Keyword(s):  
Formic Acid ◽  
Nitro Compounds ◽  
Reductive Transformation

A photoactive bimetallic framework for direct aminoformylation of nitroarenes

2016 ◽  
Vol 18 (4) ◽  
pp. 1019-1022 ◽  
Author(s):  
R. B. Nasir Baig ◽  
Sanny Verma ◽  
Mallikarjuna N. Nadagouda ◽  
Rajender S. Varma
Keyword(s):  
Formic Acid ◽  
Carbon Nitride ◽  
Bimetallic Catalyst ◽  
Nitro Compounds ◽  
Dual Role ◽  
Graphitic Carbon Nitride ◽  
Aromatic Nitro Compounds ◽  
Aromatic Nitro ◽  
Chemical Conditions

A bimetallic catalyst, AgPd@g-C3N4, on graphitic carbon nitride enables the concerted reductive formylation of aromatic nitro compounds under photo-chemical conditions; formic acid serves the dual role of a hydrogen source and a formylating agent.

Sign in / Sign up

Export Citation Format

Share Document