Electrochemical Behaviour of Iron in a Third-Generation Ionic Liquid: Cyclic Voltammetry and Micromachining Investigations

ChemPhysChem ◽  
2009 ◽  
Vol 10 (17) ◽  
pp. 3090-3096 ◽  
Author(s):  
Essam M. Moustafa ◽  
Olivier Mann ◽  
Wolfram Fürbeth ◽  
Rolf Schuster
Keyword(s):  
Cyclic Voltammetry ◽  
Ionic Liquid ◽  
Electrochemical Behaviour ◽  
Third Generation

Unusual electrochemical behaviour of AuBr4− in ionic liquids. Towards a simple recovery of gold(iii) after extraction into an ionic liquid

RSC Advances ◽  
2014 ◽  
Vol 4 (103) ◽  
pp. 58910-58915 ◽  
Author(s):  
Nicolas Papaiconomou ◽  
Nicolas Glandut ◽  
Isabelle Billard ◽  
Eric Chainet
Keyword(s):  
Cyclic Voltammetry ◽  
Ionic Liquid ◽  
Ionic Liquids ◽  
Glassy Carbon ◽  
Electrochemical Behaviour ◽  
Linear Voltammetry

The electrochemistry of AuBr4− complexes extracted into ionic liquids [C8PYR][NTf2] or [C8MIM][NTf2] saturated with water and gas has been studied by cyclic voltammetry on a glassy carbon macro electrode and by linear voltammetry on a platinum microelectrode.

On the electroreduction mechanism of halobenzenes: Detection of intermediates in reduction of monohalobenzenes

1989 ◽  
Vol 54 (4) ◽  
pp. 900-910 ◽  
Author(s):  
Juan Casado ◽  
Iluminada Gallardo
Keyword(s):  
Cyclic Voltammetry ◽  
Electrochemical Behaviour ◽  
Experimental Results ◽  
Disk Electrode ◽  
Rotating Ring Disk Electrode ◽  
Mercury Cathode

Experimental results from electrochemical behaviour of halobenzenes in DMF at a mercury cathode are used to discuss alternative mechanisms of reduction. Intermediates of these mechanisms, such as phenyl anion, phenylmercury radical and phenylmercury cation have been detected at the electrode by using cyclic voltammetry and a rotating ring-disk electrode.

Cyclic Voltammetry of Th(IV) in the Room-Temperature Ionic Liquid [Me3NnBu][N(SO2CF3)2]

2006 ◽  
Vol 45 (4) ◽  
pp. 1677-1682 ◽  
Author(s):  
Anand I. Bhatt ◽  
Noel W. Duffy ◽  
David Collison ◽  
Iain May ◽  
Robert G. Lewin
Keyword(s):  
Cyclic Voltammetry ◽  
Ionic Liquid ◽  
Room Temperature ◽  
Room Temperature Ionic Liquid

scholarly journals Utilizing of 1-Hexyl-1-Methyl-Pyrrolidinium Bis (Trifluoromethyl-Sulfonyl) Imide as Medium for Electrochemical Generation of Superoxide Ion-Radical

1970 ◽  
Vol 12 (4) ◽  
Author(s):  
Maan Hayyan ◽  
Farouq S. Mjalli ◽  
Mohd Ali Hashim ◽  
And Inas M. AlNashef
Keyword(s):  
Cyclic Voltammetry ◽  
Ionic Liquid ◽  
Atmospheric Pressure ◽  
Room Temperature ◽  
Room Temperature Ionic Liquid ◽  
Superoxide Ion ◽  
Electrochemical Generation

The superoxide ion-radical was generated and analysed electrochemically using cyclic voltammetry (CV) technique from oxygen dissolved in a room-temperature ionic liquid, 1-Hexyl-1-methyl-pyrrolidinium bis (trifluoromethylsulfonyl) imide, at atmospheric pressure. It was found that the generated superoxide ion was stable which indicates its possible use for further useful applications.ABSTRAK: Ion radikal superoksida dihasil dan dianalisa secara elektrokimia menggunakan teknik voltammetri berkitar (cyclic voltammetry (CV)) daripada oksigen yang dilarutkan dalam larutan ionik pada suhu bilik, 1-Hexyl-1-methyl-pyrrolidinium bis (trifluoromethylsulfonyl) imida, pada tekanan atmosfera. Didapati bahawa ion superoksida yang terhasil adalah stabil. Ini menunjukkan ia berkemungkinan berguna dalam aplikasi lain.

Electrochemistry of Neodymium in Phosphonium Ionic Liquids: The Influence of Cation, Water Content, and Mixed Anions

2020 ◽  
Vol 73 (11) ◽  
pp. 1080
Author(s):  
Laura Sanchez-Cupido ◽  
Jennifer M. Pringle ◽  
Amal Siriwardana ◽  
Cristina Pozo-Gonzalo ◽  
Maria Forsyth
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Electrochemical Behaviour ◽  
Critical Metals ◽  
Deposition Mechanism ◽  
Reduction Processes ◽  
Constant Potential ◽  
Current Densities ◽  
Environmentally Friendly Approach ◽  
Phosphonium Ionic Liquids

Electrodeposition using ionic liquids has emerged as an environmentally friendly approach to recover critical metals, such a neodymium. The investigation of ionic liquid chemistries and compositions is an important part of the move towards efficient neodymium recovery from end-of-life products that needs further research. Thus, in this paper we have investigated a series of phosphonium ionic liquids as potential electrolytic media. Anions such as bis(trifluoromethylsulfonyl)imide (TFSI), dicyanamide (DCA), and triflate (TfO) have been investigated, in combination with short- and long-alkyl-chain phosphonium cations. The work here suggests that [TFSI]– is one of the most promising anions for successful deposition of Nd and that water plays an important role. In contrast, electrochemical behaviour was significantly hindered in the case of DCA ionic liquid, most likely owing to strong coordination between [DCA]– and Nd3+. Mixtures of anions, [TfO]– and [TFSI]–, have also been investigated in this work, resulting in two reduction processes that could be related to a different deposition mechanism involving two steps, as observed in the case of dysprosium or, alternatively, different coordination environments that have distinct deposition potentials. Additionally, we investigated the influence of electrode substrates – glassy carbon and copper. Cu electrodes resulted in the largest current densities and thus were used for subsequent electrodeposition at constant potential. These findings are valuable for optimising the deposition of Nd in order to develop more efficient and inexpensive recycling technologies for rare earth metals.

Electrochemical behaviour of zinc acetate complexes: a cyclic voltammetry study

2005 ◽  
Vol 83 (6) ◽  
pp. 300-302 ◽  
Author(s):  
R. Sekar ◽  
S. Jayakrishnan ◽  
V. S. Muralidharan
Keyword(s):  
Cyclic Voltammetry ◽  
Zinc Acetate ◽  
Electrochemical Behaviour

Electrochemical study of Alamar Blue (resazurin) in aqueous solutions and room-temperature ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate at a glassy carbon electrode

RSC Advances ◽  
2014 ◽  
Vol 4 (17) ◽  
pp. 8431-8438 ◽  
Author(s):  
Sadegh Khazalpour ◽  
Davood Nematollahi
Keyword(s):  
Ionic Liquid ◽  
Aqueous Solutions ◽  
Glassy Carbon Electrode ◽  
Glassy Carbon ◽  
Room Temperature ◽  
Electrochemical Behaviour ◽  
Carbon Surface ◽  
Carbon Electrode ◽  
Alamar Blue ◽  
Glassy Carbon Surface

Electrochemical behaviour of resazurin in aqueous buffered solutions and ionic liquid was studied. The orientation of adsorbed resazurin was estimated. It is found that, the orientation of the adsorbed resazurin at glassy carbon surface is edgewise.

Studies on electrochemical behaviour of PVdF-HFP based ionic liquid gel polymer electrolyte

2019 ◽  
Author(s):  
M. Z. Dzulkipli ◽  
A. Ahmad ◽  
M. S. Su’ait ◽  
S. A. M. Noor ◽  
N. A. Dzulkurnain ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Polymer Electrolyte ◽  
Electrochemical Behaviour ◽  
Gel Polymer Electrolyte
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