Cyclic Voltammetry of Th(IV) in the Room-Temperature Ionic Liquid [Me3NnBu][N(SO2CF3)2]

2006 ◽  
Vol 45 (4) ◽  
pp. 1677-1682 ◽  
Author(s):  
Anand I. Bhatt ◽  
Noel W. Duffy ◽  
David Collison ◽  
Iain May ◽  
Robert G. Lewin
Keyword(s):  
Cyclic Voltammetry ◽  
Ionic Liquid ◽  
Room Temperature ◽  
Room Temperature Ionic Liquid

scholarly journals Utilizing of 1-Hexyl-1-Methyl-Pyrrolidinium Bis (Trifluoromethyl-Sulfonyl) Imide as Medium for Electrochemical Generation of Superoxide Ion-Radical

1970 ◽  
Vol 12 (4) ◽  
Author(s):  
Maan Hayyan ◽  
Farouq S. Mjalli ◽  
Mohd Ali Hashim ◽  
And Inas M. AlNashef
Keyword(s):  
Cyclic Voltammetry ◽  
Ionic Liquid ◽  
Atmospheric Pressure ◽  
Room Temperature ◽  
Room Temperature Ionic Liquid ◽  
Superoxide Ion ◽  
Electrochemical Generation

The superoxide ion-radical was generated and analysed electrochemically using cyclic voltammetry (CV) technique from oxygen dissolved in a room-temperature ionic liquid, 1-Hexyl-1-methyl-pyrrolidinium bis (trifluoromethylsulfonyl) imide, at atmospheric pressure. It was found that the generated superoxide ion was stable which indicates its possible use for further useful applications.ABSTRAK: Ion radikal superoksida dihasil dan dianalisa secara elektrokimia menggunakan teknik voltammetri berkitar (cyclic voltammetry (CV)) daripada oksigen yang dilarutkan dalam larutan ionik pada suhu bilik, 1-Hexyl-1-methyl-pyrrolidinium bis (trifluoromethylsulfonyl) imida, pada tekanan atmosfera. Didapati bahawa ion superoksida yang terhasil adalah stabil. Ini menunjukkan ia berkemungkinan berguna dalam aplikasi lain.

scholarly journals Sequestration of tetravalent neptunium from acidic feeds using diglycolamide-functionalized dendrimers in a room temperature ionic liquid: extraction, spectroscopic and electrochemical studies

2021 ◽  
Vol 45 (38) ◽  
pp. 17951-17959
Author(s):  
Parveen K. Verma ◽  
Rajesh B. Gujar ◽  
Bholanath Mahanty ◽  
Andrea Leoncini ◽  
Jurriaan Huskens ◽  
...  
Keyword(s):  
Cyclic Voltammetry ◽  
Ionic Liquid ◽  
Room Temperature ◽  
Liquid Extraction ◽  
Room Temperature Ionic Liquid ◽  
Electrochemical Studies

Extraction of Np(iv) was studied using RTIL containing two poly(propyleneimine) based dendrimer ligands from HNO3 solutions. Studies of the extracted complexes were also carried out by Vis-NIR and cyclic voltammetry.

Electrochemical, computational and spectroscopic investigation on local environment of plutonium in ionic liquid and aqueous medium: a comparative study

2016 ◽  
Vol 104 (3) ◽  
Author(s):  
Arijit Sengupta ◽  
Mallekav S. Murali ◽  
Prasanta Kumar Mohapatra ◽  
Sk. Musharaf Ali ◽  
Kalsanka Trivikram Shenoy
Keyword(s):  
Cyclic Voltammetry ◽  
Ionic Liquid ◽  
Comparative Study ◽  
Aqueous Medium ◽  
Spectroscopic Investigation ◽  
Room Temperature ◽  
Local Environment ◽  
Room Temperature Ionic Liquid

AbstractWith an aim to understand the nature of species, cyclic voltammetry (CV) of Pu(IV) in dilute HBr and in a room temperature ionic liquid (RTIL), 1-octyl-3-methylimidazolium bromide (C

Role of H+ in Polypyrrole and Poly(3,4-ethylenedioxythiophene) Formation Using FeCl3·6H2O in the Room Temperature Ionic Liquid, C4mpyrTFSI

2012 ◽  
Vol 65 (11) ◽  
pp. 1513 ◽  
Author(s):  
Graeme A. Snook ◽  
Anand I. Bhatt ◽  
Muhammad E. Abdelhamid ◽  
Adam S. Best
Keyword(s):  
Cyclic Voltammetry ◽  
Ionic Liquid ◽  
Ir Spectroscopy ◽  
Chemical Reaction ◽  
Oxidation Reaction ◽  
Room Temperature ◽  
Trifluoromethanesulfonic Acid ◽  
Room Temperature Ionic Liquid ◽  
Iron Salt

The polymerisation reaction of pyrrole and 3,4-ethylenedioxythiophene using the chemical oxidant FeCl3·6H2O in the room temperature ionic liquid butyl-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide (C4mpyrTFSI) has been investigated using cyclic voltammetry, UV/vis and IR spectroscopy. The voltammetric data for the Fe2+/3+ reaction is complicated by the presence of H+ introduced upon dissolution of the iron salt by deprotonation of the coordinated waters. The voltammetric and chemical reaction studies show that H+ itself, introduced to solution as trifluoromethanesulfonic acid (HTFSI), can act as the chemical oxidant for the polymerisation reaction. Voltammetric data also implies that in this system the Fe2+/3+ redox couple may not actually be involved in the polymerisation reaction and that the H+ introduced upon dissolution of the FeCl3·6H2O may be the sole cause of the oxidation reaction.

The Solvent Effect on H2O2 Generation at Room Temperature Ionic Liquid|Water Interface

ChemPhysChem ◽  
2021 ◽  
Author(s):  
Marcin Wojciech Opallo ◽  
Justyna Kalisz ◽  
Wojciech Nogala ◽  
Wojciech Adamiak ◽  
Mateusz Gocyla ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Solvent Effect ◽  
Liquid Water ◽  
Room Temperature ◽  
Room Temperature Ionic Liquid ◽  
Water Interface ◽  
H2o2 Generation

Electrochemical Kinetics of Ag|Ag+and TMPD|TMPD+•in the Room-Temperature Ionic Liquid [C4mpyrr][NTf2]; toward Optimizing Reference Electrodes for Voltammetry in RTILs

2007 ◽  
Vol 111 (37) ◽  
pp. 13957-13966 ◽  
Author(s):  
Emma I. Rogers ◽  
Debbie S. Silvester ◽  
Sarah E. Ward Jones ◽  
Leigh Aldous ◽  
Christopher Hardacre ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Room Temperature ◽  
Room Temperature Ionic Liquid ◽  
Electrochemical Kinetics ◽  
Reference Electrodes ◽  
Kinetics Of
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