ChemInform Abstract: Water Opens the Door to Organolithiums and Grignard Reagents: Exploring and Comparing the Reactivity of Highly Polar Organometallic Compounds in Unconventional Reaction Media Towards the Synthesis of Tetrahydrofurans.

Luciana Cicco; Stefania Sblendorio; Rosmara Mansueto; Filippo M. Perna; Antonio Salomone; Saverio Florio; Vito Capriati

doi:10.1002/chin.201623120

ChemInform Abstract: Water Opens the Door to Organolithiums and Grignard Reagents: Exploring and Comparing the Reactivity of Highly Polar Organometallic Compounds in Unconventional Reaction Media Towards the Synthesis of Tetrahydrofurans.

ChemInform ◽

10.1002/chin.201623120 ◽

2016 ◽

Vol 47 (23) ◽

Author(s):

Luciana Cicco ◽

Stefania Sblendorio ◽

Rosmara Mansueto ◽

Filippo M. Perna ◽

Antonio Salomone ◽

...

Keyword(s):

Organometallic Compounds ◽

Grignard Reagents ◽

Reaction Media

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Water opens the door to organolithiums and Grignard reagents: exploring and comparing the reactivity of highly polar organometallic compounds in unconventional reaction media towards the synthesis of tetrahydrofurans

Chemical Science ◽

10.1039/c5sc03436a ◽

2016 ◽

Vol 7 (2) ◽

pp. 1192-1199 ◽

Cited By ~ 74

Author(s):

Luciana Cicco ◽

Stefania Sblendorio ◽

Rosmara Mansueto ◽

Filippo M. Perna ◽

Antonio Salomone ◽

...

Keyword(s):

Organometallic Compounds ◽

Grignard Reagents ◽

Nucleophilic Additions ◽

Organolithium Reagents ◽

Reaction Media

Grignard and organolithium reagents undergo smooth nucleophilic additions to γ-chloroketones “on water”.

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Relative reactivities of organometallic compounds. XI Grignard reagents

Recueil des Travaux Chimiques des Pays-Bas ◽

10.1002/recl.19360550708 ◽

2010 ◽

Vol 55 (7) ◽

pp. 577-585 ◽

Cited By ~ 6

Author(s):

Henry Gilman ◽

Edith L. St. John ◽

Nina B. St. John ◽

Myrl Lichtenwalter

Keyword(s):

Organometallic Compounds ◽

Grignard Reagents

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ChemInform Abstract: SYNTHESIS AND REACTIVITY OF PERFLUORINATED ORGANOMETALLIC COMPOUNDS. VIII. IMPROVED SYNTHESES OF NEW FLUORINATED ACETYLENIC COMPOUNDS RFCCRH AND OF THEIR FLUOROOLEFINIC ANALOGS RFCF:CFRH VIA PERFLUORINATED GRIGNARD REAGENTS

Chemischer Informationsdienst ◽

10.1002/chin.198319123 ◽

1983 ◽

Vol 14 (19) ◽

Author(s):

R. ALBADRI ◽

P. MOREAU ◽

A. COMMEYRAS

Keyword(s):

Organometallic Compounds ◽

Grignard Reagents ◽

Acetylenic Compounds

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Reaction of 1-Alkynes with Organometallic Compounds. VIII.1Rate of Reaction of Grignard Reagents with Hexyne-1 in the Presence of Tertiary Amines and Magnesium Bromide2

The Journal of Organic Chemistry ◽

10.1021/jo01091a009 ◽

1959 ◽

Vol 24 (9) ◽

pp. 1202-1205 ◽

Cited By ~ 8

Author(s):

JOHN H. WOTIZ ◽

C. A. HOLLINGSWORTH ◽

ALBERT W. SIMON

Keyword(s):

Organometallic Compounds ◽

Grignard Reagents ◽

Tertiary Amines

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Reactivity of Polar Organometallic Compounds in Unconventional Reaction Media: Challenges and Opportunities

European Journal of Organic Chemistry ◽

10.1002/ejoc.201500757 ◽

2015 ◽

Vol 2015 (31) ◽

pp. 6779-6799 ◽

Cited By ~ 72

Author(s):

Joaquin García-Álvarez ◽

Eva Hevia ◽

Vito Capriati

Keyword(s):

Organometallic Compounds ◽

Challenges And Opportunities ◽

Reaction Media

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The Reaction of 1-Alkynes with Organometallic Compounds. II. The Relationship between Decomposition Potentials of Grignard Reagents and Their Relative Reactivity Towards Terminal Acetylens

Journal of the American Chemical Society ◽

10.1021/ja01621a068 ◽

1955 ◽

Vol 77 (16) ◽

pp. 4410-4410 ◽

Cited By ~ 3

Author(s):

Raymond E. Dessy ◽

C.A. Hollingsworth ◽

John H. Wotiz

Keyword(s):

Organometallic Compounds ◽

Relative Reactivity ◽

Grignard Reagents ◽

The Relationship

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Reaction of Troponoids and Organometallic Compounds. VI. Reaction of Tropone with Grignard Reagents

Bulletin of the Chemical Society of Japan ◽

10.1246/bcsj.34.619 ◽

1961 ◽

Vol 34 (5) ◽

pp. 619-622 ◽

Cited By ~ 21

Author(s):

Tetsuo Nozoe ◽

Toshio Mukai ◽

Takahiro Tezuka

Keyword(s):

Organometallic Compounds ◽

Grignard Reagents

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ChemInform Abstract: Reactivity of Polar Organometallic Compounds in Unconventional Reaction Media: Challenges and Opportunities

ChemInform ◽

10.1002/chin.201550215 ◽

2015 ◽

Vol 46 (50) ◽

pp. no-no

Author(s):

Joaquin Garcia-Alvarez ◽

Eva Hevia ◽

Vito Capriati

Keyword(s):

Organometallic Compounds ◽

Challenges And Opportunities ◽

Reaction Media

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Reaction of 1-Alkynes with Organometallic Compounds. IX.1aThe Reactivity of Mixed Grignard Reagents toward 1-Hexyne1b

The Journal of Organic Chemistry ◽

10.1021/jo01050a016 ◽

1962 ◽

Vol 27 (3) ◽

pp. 760-762 ◽

Cited By ~ 2

Author(s):

EDMUND W. SMALLEY ◽

C. A. HOLLINGSWORTH

Keyword(s):

Organometallic Compounds ◽

Grignard Reagents

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The reactions of transition metal chelates with organometallic compounds and their paramagnetic products. V—New possibilities in the generation of anion radicals by reactions of Grignard reagents and lithium alkyls in the presence of transition metal ions

Organic Magnetic Resonance ◽

10.1002/mrc.1270090506 ◽

1977 ◽

Vol 9 (5) ◽

pp. 269-275 ◽

Cited By ~ 19

Author(s):

A. Staško ◽

L. Malík ◽

A. Tkáč ◽

V. Adamčík ◽

M. Hronec

Keyword(s):

Transition Metal ◽

Metal Ions ◽

Organometallic Compounds ◽

Transition Metal Ions ◽

Metal Chelates ◽

Grignard Reagents ◽

Transition Metal Chelates ◽

Anion Radicals

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