Reaction of 1-Alkynes with Organometallic Compounds. VIII.1Rate of Reaction of Grignard Reagents with Hexyne-1 in the Presence of Tertiary Amines and Magnesium Bromide2

JOHN H. WOTIZ; C. A. HOLLINGSWORTH; ALBERT W. SIMON

doi:10.1021/jo01091a009

Reaction of 1-Alkynes with Organometallic Compounds. VIII.1Rate of Reaction of Grignard Reagents with Hexyne-1 in the Presence of Tertiary Amines and Magnesium Bromide2

The Journal of Organic Chemistry ◽

10.1021/jo01091a009 ◽

1959 ◽

Vol 24 (9) ◽

pp. 1202-1205 ◽

Cited By ~ 8

Author(s):

JOHN H. WOTIZ ◽

C. A. HOLLINGSWORTH ◽

ALBERT W. SIMON

Keyword(s):

Organometallic Compounds ◽

Grignard Reagents ◽

Tertiary Amines

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Three-Component Coupling Reactions of Thioformamides with Organolithium and a Grignard Reagents Leading to Formation of Tertiary Amines and a Thiolating Agent.

ChemInform ◽

10.1002/chin.200723064 ◽

2007 ◽

Vol 38 (23) ◽

Author(s):

Toshiaki Murai ◽

Fumio Asai

Keyword(s):

Grignard Reagents ◽

Coupling Reactions ◽

Tertiary Amines ◽

Three Component Coupling

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Relative reactivities of organometallic compounds. XI Grignard reagents

Recueil des Travaux Chimiques des Pays-Bas ◽

10.1002/recl.19360550708 ◽

2010 ◽

Vol 55 (7) ◽

pp. 577-585 ◽

Cited By ~ 6

Author(s):

Henry Gilman ◽

Edith L. St. John ◽

Nina B. St. John ◽

Myrl Lichtenwalter

Keyword(s):

Organometallic Compounds ◽

Grignard Reagents

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ChemInform Abstract: SYNTHESIS AND REACTIVITY OF PERFLUORINATED ORGANOMETALLIC COMPOUNDS. VIII. IMPROVED SYNTHESES OF NEW FLUORINATED ACETYLENIC COMPOUNDS RFCCRH AND OF THEIR FLUOROOLEFINIC ANALOGS RFCF:CFRH VIA PERFLUORINATED GRIGNARD REAGENTS

Chemischer Informationsdienst ◽

10.1002/chin.198319123 ◽

1983 ◽

Vol 14 (19) ◽

Author(s):

R. ALBADRI ◽

P. MOREAU ◽

A. COMMEYRAS

Keyword(s):

Organometallic Compounds ◽

Grignard Reagents ◽

Acetylenic Compounds

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Asymmetric conjugate addition of Grignard reagents in the presence of tertiary amines to α,β-unsaturated amides derived from (S)-2-(1-hydroxy-1-methylethyl)pyrrolidine or (S)-prolinol

Journal of the Chemical Society Chemical Communications ◽

10.1039/c39850000469 ◽

1985 ◽

Vol 0 (8) ◽

pp. 469-470 ◽

Cited By ~ 15

Author(s):

Kenso Soai ◽

Hideaki Machida ◽

Atsuhiro Ookawa

Keyword(s):

Conjugate Addition ◽

Grignard Reagents ◽

Tertiary Amines

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The Reaction of 1-Alkynes with Organometallic Compounds. II. The Relationship between Decomposition Potentials of Grignard Reagents and Their Relative Reactivity Towards Terminal Acetylens

Journal of the American Chemical Society ◽

10.1021/ja01621a068 ◽

1955 ◽

Vol 77 (16) ◽

pp. 4410-4410 ◽

Cited By ~ 3

Author(s):

Raymond E. Dessy ◽

C.A. Hollingsworth ◽

John H. Wotiz

Keyword(s):

Organometallic Compounds ◽

Relative Reactivity ◽

Grignard Reagents ◽

The Relationship

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ChemInform Abstract: ASYMMETRIC CONJUGATE ADDITION OF GRIGNARD REAGENTS IN THE PRESENCE OF TERTIARY AMINES TO α,β-UNSATURATED AMIDES DERIVED FROM (S)-2-(1-HYDROXY-1-METHYLETHYL)PYRROLIDINE OR (S)-PROLINOL

Chemischer Informationsdienst ◽

10.1002/chin.198531175 ◽

1985 ◽

Vol 16 (31) ◽

Author(s):

K. SOAI ◽

H. MACHIDA ◽

A. OOKAWA

Keyword(s):

Conjugate Addition ◽

Grignard Reagents ◽

Tertiary Amines

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Sequential Addition Reactions of Lithium Acetylides and Grignard Reagents to Selenoiminium Salts Leading to 2-Propynyl Tertiary Amines Bearing a Tetrasubstituted Carbon Center

Bulletin of the Chemical Society of Japan ◽

10.1246/bcsj.80.2220 ◽

2007 ◽

Vol 80 (11) ◽

pp. 2220-2225 ◽

Cited By ~ 13

Author(s):

Toshiaki Murai ◽

Sho Nogawa ◽

Yuichiro Mutoh

Keyword(s):

Grignard Reagents ◽

Addition Reactions ◽

Tertiary Amines ◽

Sequential Addition

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Reaction of Troponoids and Organometallic Compounds. VI. Reaction of Tropone with Grignard Reagents

Bulletin of the Chemical Society of Japan ◽

10.1246/bcsj.34.619 ◽

1961 ◽

Vol 34 (5) ◽

pp. 619-622 ◽

Cited By ~ 21

Author(s):

Tetsuo Nozoe ◽

Toshio Mukai ◽

Takahiro Tezuka

Keyword(s):

Organometallic Compounds ◽

Grignard Reagents

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Water opens the door to organolithiums and Grignard reagents: exploring and comparing the reactivity of highly polar organometallic compounds in unconventional reaction media towards the synthesis of tetrahydrofurans

Chemical Science ◽

10.1039/c5sc03436a ◽

2016 ◽

Vol 7 (2) ◽

pp. 1192-1199 ◽

Cited By ~ 74

Author(s):

Luciana Cicco ◽

Stefania Sblendorio ◽

Rosmara Mansueto ◽

Filippo M. Perna ◽

Antonio Salomone ◽

...

Keyword(s):

Organometallic Compounds ◽

Grignard Reagents ◽

Nucleophilic Additions ◽

Organolithium Reagents ◽

Reaction Media

Grignard and organolithium reagents undergo smooth nucleophilic additions to γ-chloroketones “on water”.

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ChemInform Abstract: Water Opens the Door to Organolithiums and Grignard Reagents: Exploring and Comparing the Reactivity of Highly Polar Organometallic Compounds in Unconventional Reaction Media Towards the Synthesis of Tetrahydrofurans.

ChemInform ◽

10.1002/chin.201623120 ◽

2016 ◽

Vol 47 (23) ◽

Author(s):

Luciana Cicco ◽

Stefania Sblendorio ◽

Rosmara Mansueto ◽

Filippo M. Perna ◽

Antonio Salomone ◽

...

Keyword(s):

Organometallic Compounds ◽

Grignard Reagents ◽

Reaction Media

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