scholarly journals Reactivity of Polar Organometallic Compounds in Unconventional Reaction Media: Challenges and Opportunities

2015 ◽  
Vol 2015 (31) ◽  
pp. 6779-6799 ◽  
Author(s):  
Joaquin García-Álvarez ◽  
Eva Hevia ◽  
Vito Capriati
Keyword(s):  
Organometallic Compounds ◽  
Challenges And Opportunities ◽  
Reaction Media

scholarly journals Water opens the door to organolithiums and Grignard reagents: exploring and comparing the reactivity of highly polar organometallic compounds in unconventional reaction media towards the synthesis of tetrahydrofurans

2016 ◽  
Vol 7 (2) ◽  
pp. 1192-1199 ◽  
Author(s):  
Luciana Cicco ◽  
Stefania Sblendorio ◽  
Rosmara Mansueto ◽  
Filippo M. Perna ◽  
Antonio Salomone ◽  
...  
Keyword(s):  
Organometallic Compounds ◽  
Grignard Reagents ◽  
Nucleophilic Additions ◽  
Organolithium Reagents ◽  
Reaction Media

Grignard and organolithium reagents undergo smooth nucleophilic additions to γ-chloroketones “on water”.

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