ChemInform Abstract: Thiourea Catalyzed Aminolysis of Epoxides under Solvent-Free Conditions. Electronic Control of Regioselective Ring Opening.

ChemInform ◽  
2010 ◽  
Vol 41 (33) ◽  
pp. no-no
Author(s):  
Swapandeep Singh Chimni ◽  
Neeraj Bala ◽  
Vaibhav A. Dixit ◽  
Prasad V. Bharatam
Keyword(s):  
Ring Opening ◽  
Solvent Free ◽  
Electronic Control ◽  
Solvent Free Conditions

Thiourea catalyzed aminolysis of epoxides under solvent free conditions. Electronic control of regioselective ring opening

Tetrahedron ◽  
2010 ◽  
Vol 66 (16) ◽  
pp. 3042-3049 ◽  
Author(s):  
Swapandeep Singh Chimni ◽  
Neeraj Bala ◽  
Vaibhav A. Dixit ◽  
Prasad V. Bharatam
Keyword(s):  
Ring Opening ◽  
Solvent Free ◽  
Electronic Control ◽  
Solvent Free Conditions

Solid lithium perchlorate as a powerful catalyst for the synthesis of β-aminoalcohols under solvent-free conditions

2005 ◽  
Vol 83 (5) ◽  
pp. 505-507 ◽  
Author(s):  
Najmodin Azizi ◽  
Mohammad R Saidi
Keyword(s):  
Ring Opening ◽  
Room Temperature ◽  
Lithium Perchlorate ◽  
Solvent Free ◽  
Solvent Free Conditions ◽  
Reaction Proceeds ◽  
Ring Opening Of Epoxides ◽  
Neutral Conditions ◽  
Hindered Amines ◽  
Short Times

Lithium perchlorate catalyzed the ring opening of epoxides with amines to provide the corresponding β-aminoalcohols in excellent yields with high regioselectivity. The reaction proceeds rapidly under mild and neutral conditions and worked well with primary, secondary, aliphatic, aromatic, and hindered amines in short times at room temperature, in the absence of solvent.Key words: epoxide, lithium perchlorate, β-aminoalcohols, solvent-free.

Efficient method for ring opening of epoxides with amines by NaY zeolite under solvent-free conditions

2007 ◽  
Vol 264 (1-2) ◽  
pp. 162-169 ◽  
Author(s):  
Rukhsana Ilyas Kureshy ◽  
Surendra Singh ◽  
Noor-ul Hasan Khan ◽  
Sayed Hasan Razi Abdi ◽  
Eringathodi Suresh ◽  
...  
Keyword(s):  
Efficient Method ◽  
Ring Opening ◽  
Solvent Free ◽  
Nay Zeolite ◽  
Solvent Free Conditions ◽  
Ring Opening Of Epoxides

Synthesis of β-amino alcohols using MgO as a new catalyst under solvent-free conditions

2008 ◽  
Vol 86 (1) ◽  
pp. 65-71 ◽  
Author(s):  
Mona Hosseini-Sarvari
Keyword(s):  
Ring Opening ◽  
Amino Alcohols ◽  
Solvent Free ◽  
Aliphatic Amines ◽  
Solvent Free Conditions ◽  
Ring Opening Of Epoxides ◽  
High Yields ◽  
Aromatic And Aliphatic Amines

MgO catalyzed efficiently the ring opening of epoxides with a range of aromatic and aliphatic amines to produce β-substituted alcohols in high yields under solvent-free conditions. Exclusive trans stereoselectivity is observed for cyclic epoxide.Key words: MgO, β-amino alcohols, solvent-free, epoxide, amine.

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