Regioselective Ring-opening Reaction of 1,2-Epoxides with Arylselenol under Solvent-free Conditions and Application to the Synthesis of 1,3-Oxazolidin-2-ones

2006 ◽  
Vol 24 (5) ◽  
pp. 669-673 ◽  
Author(s):  
Ming-Hua Yang ◽  
Chao-Ying Yuan ◽  
Yi Pan ◽  
Cheng-Jian Zhu
Keyword(s):  
Ring Opening ◽  
Solvent Free ◽  
Ring Opening Reaction ◽  
Solvent Free Conditions

Solid lithium perchlorate as a powerful catalyst for the synthesis of β-aminoalcohols under solvent-free conditions

2005 ◽  
Vol 83 (5) ◽  
pp. 505-507 ◽  
Author(s):  
Najmodin Azizi ◽  
Mohammad R Saidi
Keyword(s):  
Ring Opening ◽  
Room Temperature ◽  
Lithium Perchlorate ◽  
Solvent Free ◽  
Solvent Free Conditions ◽  
Reaction Proceeds ◽  
Ring Opening Of Epoxides ◽  
Neutral Conditions ◽  
Hindered Amines ◽  
Short Times

Lithium perchlorate catalyzed the ring opening of epoxides with amines to provide the corresponding β-aminoalcohols in excellent yields with high regioselectivity. The reaction proceeds rapidly under mild and neutral conditions and worked well with primary, secondary, aliphatic, aromatic, and hindered amines in short times at room temperature, in the absence of solvent.Key words: epoxide, lithium perchlorate, β-aminoalcohols, solvent-free.

Efficient method for ring opening of epoxides with amines by NaY zeolite under solvent-free conditions

2007 ◽  
Vol 264 (1-2) ◽  
pp. 162-169 ◽  
Author(s):  
Rukhsana Ilyas Kureshy ◽  
Surendra Singh ◽  
Noor-ul Hasan Khan ◽  
Sayed Hasan Razi Abdi ◽  
Eringathodi Suresh ◽  
...  
Keyword(s):  
Efficient Method ◽  
Ring Opening ◽  
Solvent Free ◽  
Nay Zeolite ◽  
Solvent Free Conditions ◽  
Ring Opening Of Epoxides

ChemInform Abstract: Thiourea Catalyzed Aminolysis of Epoxides under Solvent-Free Conditions. Electronic Control of Regioselective Ring Opening.

ChemInform ◽  
2010 ◽  
Vol 41 (33) ◽  
pp. no-no
Author(s):  
Swapandeep Singh Chimni ◽  
Neeraj Bala ◽  
Vaibhav A. Dixit ◽  
Prasad V. Bharatam
Keyword(s):  
Ring Opening ◽  
Solvent Free ◽  
Electronic Control ◽  
Solvent Free Conditions

Highly regioselective ring-opening of epoxides with amines: a metal- and solvent-free protocol for the synthesis of β-amino alcohols

2020 ◽  
Vol 56 (15) ◽  
pp. 2256-2259
Author(s):  
Dong Li ◽  
Jing Wang ◽  
Shibo Yu ◽  
Silei Ye ◽  
Wenjie Zou ◽  
...  
Keyword(s):  
Acetic Acid ◽  
Ring Opening ◽  
Amino Alcohols ◽  
Solvent Free ◽  
Ring Opening Reaction ◽  
Ring Opening Of Epoxides

We herein report a metal- and solvent-free acetic acid-mediated ring-opening reaction of epoxides with amines.

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