ChemInform Abstract: Green Oxidation of Alcohols Using Biomimetic Cu Complexes and Cu Enzymes as Catalysts

ChemInform ◽  
2009 ◽  
Vol 40 (9) ◽  
Author(s):  
Isabel W. C. E. Arends ◽  
Patrick Gamez ◽  
Roger A. Sheldon
Keyword(s):  
Green Oxidation ◽  
Oxidation Of Alcohols ◽  
Cu Complexes

scholarly journals A Study of Catalytic Oxidation of a Library of C2 to C4 Alcohols in the Presence of Nanogold

Nanomaterials ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 442
Author(s):  
Maciej Kapkowski ◽  
Anna Niemczyk-Wojdyla ◽  
Piotr Bartczak ◽  
Monika Pyrkosz Bulska ◽  
Kamila Gajcy ◽  
...  
Keyword(s):  
Organic Chemistry ◽  
Green Chemistry ◽  
Alcohol Oxidation ◽  
Catalytic Performance ◽  
Toxic Chemicals ◽  
Wide Scope ◽  
Catalytic Potential ◽  
Green Oxidation ◽  
Oxidation Of Alcohols ◽  
Different Levels

The classical stoichiometric oxidation of alcohols is an important tool in contemporary organic chemistry. However, it still requires huge modifications in order to comply with the principles of green chemistry. The use of toxic chemicals, hazardous organic solvents, and the large amounts of toxic wastes that result from the reactions are a few examples of the problems that must be solved. Nanogold alone or conjugated with palladium were supported on different carriers (SiO2, C) and investigated in order to evaluate their catalytic potential for environmentally friendly alcohol oxidation under solvent-free and base-free conditions in the presence H2O2 as a clean oxidant. We tested different levels of Au loading (0.1–1.2% wt.) and different active catalytic site forms (monometallic Au or bimetallic Au–Pd sites). This provided new insights on how the structure of the Au-dispersions affected their catalytic performance. Importantly, the examination of the catalytic performance of the resulting catalysts was oriented toward a broad scope of alcohols, including those that are the most resistant to oxidation—the primary aliphatic alcohols. Surprisingly, the studies proved that Au/SiO2 at a level of Au loading as low as 0.1% wt. appeared to be efficient and prospective catalytic system for the green oxidation of alcohol. Most importantly, the results revealed that 0.1% Au/SiO2 might be the catalyst of choice with a wide scope of utility in the green oxidation of various structurally different alcohols as well as the non-activated aliphatic ones.

Green oxidation of alcohols with hydrogen peroxide catalyzed by a tetra-cobalt polyoxometalate in water

2015 ◽  
Vol 12 (7) ◽  
pp. 1207-1212 ◽  
Author(s):  
Mostafa Riahi Farsani ◽  
Elham Assady ◽  
Fariba Jalilian ◽  
Bahram Yadollahi ◽  
Hadi Amiri Rudbari
Keyword(s):  
Hydrogen Peroxide ◽  
Green Oxidation ◽  
Oxidation Of Alcohols

Green oxidation of alcohols in water by a polyoxometalate nano capsule as catalyst

2015 ◽  
Vol 55 ◽  
pp. 135-138 ◽  
Author(s):  
Elham Nikbakht ◽  
Bahram Yadollahi ◽  
Mostafa Riahi Farsani
Keyword(s):  
Green Oxidation ◽  
Oxidation Of Alcohols

Efficient and selective green oxidation of alcohols by MOF-derived magnetic nanoparticles as a recoverable catalyst

RSC Advances ◽  
2016 ◽  
Vol 6 (32) ◽  
pp. 26921-26928 ◽  
Author(s):  
Xianfang Yao ◽  
Cuihua Bai ◽  
Junying Chen ◽  
Yingwei Li
Keyword(s):  
Magnetic Nanoparticles ◽  
Heterogeneous Catalyst ◽  
Highly Efficient ◽  
Neat Water ◽  
Green Oxidation ◽  
Recoverable Catalyst ◽  
Oxidation Of Alcohols

A magnetic Fe3O4@C heterogeneous catalyst derived from MOFs is highly efficient and selective in oxidation of alcohols with neat water and base-free conditions.

First electrospun immobilized molybdenum complex on bio iron oxide nanofiber for green oxidation of alcohols

Polymer ◽  
2018 ◽  
Vol 149 ◽  
pp. 229-237 ◽  
Author(s):  
Sedighe Abbaspour Noghi ◽  
Atena Naeimi ◽  
Hooshang Hamidian
Keyword(s):  
Iron Oxide ◽  
Molybdenum Complex ◽  
Green Oxidation ◽  
Oxidation Of Alcohols
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