scholarly journals Green Oxidation of Alcohols to Carbonyl Compounds by Heterogeneous Photocatalysis

ChemSusChem ◽  
2010 ◽  
Vol 3 (10) ◽  
pp. 1135-1138 ◽  
Author(s):  
Vincenzo Augugliaro ◽  
Leonardo Palmisano
Keyword(s):  
Carbonyl Compounds ◽  
Heterogeneous Photocatalysis ◽  
Green Oxidation ◽  
Oxidation Of Alcohols

N-tert-Butylbenzenesulfenamide-catalyzed oxidation of alcohols to the corresponding carbonyl compounds with N-chlorosuccinimide

Tetrahedron ◽  
2003 ◽  
Vol 59 (35) ◽  
pp. 6739-6750 ◽  
Author(s):  
Jun-ichi Matsuo ◽  
Daisuke Iida ◽  
Hiroyuki Yamanaka ◽  
Teruaki Mukaiyama
Keyword(s):  
Carbonyl Compounds ◽  
Oxidation Of Alcohols ◽  
Catalyzed Oxidation

Chemoselective C−H Oxidation of Alcohols to Carbonyl Compounds with Iodosobenzene Catalyzed by (Salen)chromium Complex

2000 ◽  
Vol 65 (7) ◽  
pp. 1915-1918 ◽  
Author(s):  
Waldemar Adam ◽  
Feyissa Gadissa Gelalcha ◽  
Chantu R. Saha-Möller ◽  
Veit R. Stegmann
Keyword(s):  
Carbonyl Compounds ◽  
Chromium Complex ◽  
Oxidation Of Alcohols

Aerobic oxidation of alcohols to carbonyl compounds mediated by poly(ethylene glycol)-supported TEMPO radicals

Tetrahedron ◽  
2005 ◽  
Vol 61 (51) ◽  
pp. 12058-12064 ◽  
Author(s):  
Maurizio Benaglia ◽  
Alessandra Puglisi ◽  
Orsolya Holczknecht ◽  
Silvio Quici ◽  
Gianluca Pozzi
Keyword(s):  
Ethylene Glycol ◽  
Carbonyl Compounds ◽  
Aerobic Oxidation ◽  
Poly Ethylene Glycol ◽  
Oxidation Of Alcohols ◽  
Poly Ethylene

Photocatalysis with Quantum Dots and Visible Light: Selective and Efficient Oxidation of Alcohols to Carbonyl Compounds through a Radical Relay Process in Water

2017 ◽  
Vol 129 (11) ◽  
pp. 3066-3070 ◽  
Author(s):  
Lei-Min Zhao ◽  
Qing-Yuan Meng ◽  
Xiang-Bing Fan ◽  
Chen Ye ◽  
Xu-Bing Li ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Visible Light ◽  
Carbonyl Compounds ◽  
Oxidation Of Alcohols

scholarly journals A Study of Catalytic Oxidation of a Library of C2 to C4 Alcohols in the Presence of Nanogold

Nanomaterials ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 442
Author(s):  
Maciej Kapkowski ◽  
Anna Niemczyk-Wojdyla ◽  
Piotr Bartczak ◽  
Monika Pyrkosz Bulska ◽  
Kamila Gajcy ◽  
...  
Keyword(s):  
Organic Chemistry ◽  
Green Chemistry ◽  
Alcohol Oxidation ◽  
Catalytic Performance ◽  
Toxic Chemicals ◽  
Wide Scope ◽  
Catalytic Potential ◽  
Green Oxidation ◽  
Oxidation Of Alcohols ◽  
Different Levels

The classical stoichiometric oxidation of alcohols is an important tool in contemporary organic chemistry. However, it still requires huge modifications in order to comply with the principles of green chemistry. The use of toxic chemicals, hazardous organic solvents, and the large amounts of toxic wastes that result from the reactions are a few examples of the problems that must be solved. Nanogold alone or conjugated with palladium were supported on different carriers (SiO2, C) and investigated in order to evaluate their catalytic potential for environmentally friendly alcohol oxidation under solvent-free and base-free conditions in the presence H2O2 as a clean oxidant. We tested different levels of Au loading (0.1–1.2% wt.) and different active catalytic site forms (monometallic Au or bimetallic Au–Pd sites). This provided new insights on how the structure of the Au-dispersions affected their catalytic performance. Importantly, the examination of the catalytic performance of the resulting catalysts was oriented toward a broad scope of alcohols, including those that are the most resistant to oxidation—the primary aliphatic alcohols. Surprisingly, the studies proved that Au/SiO2 at a level of Au loading as low as 0.1% wt. appeared to be efficient and prospective catalytic system for the green oxidation of alcohol. Most importantly, the results revealed that 0.1% Au/SiO2 might be the catalyst of choice with a wide scope of utility in the green oxidation of various structurally different alcohols as well as the non-activated aliphatic ones.

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