Efficient and selective green oxidation of alcohols by MOF-derived magnetic nanoparticles as a recoverable catalyst

RSC Advances ◽  
2016 ◽  
Vol 6 (32) ◽  
pp. 26921-26928 ◽  
Author(s):  
Xianfang Yao ◽  
Cuihua Bai ◽  
Junying Chen ◽  
Yingwei Li

A magnetic Fe3O4@C heterogeneous catalyst derived from MOFs is highly efficient and selective in oxidation of alcohols with neat water and base-free conditions.

2016 ◽  
Vol 18 (4) ◽  
pp. 1061-1069 ◽  
Author(s):  
Cuihua Bai ◽  
Aiqin Li ◽  
Xianfang Yao ◽  
Hongli Liu ◽  
Yingwei Li

A magnetic Co-based heterogeneous catalyst derived from MOFs is highly efficient in selective oxidation of alcohols in neat water under an atmospheric pressure of air and base-free conditions.


RSC Advances ◽  
2016 ◽  
Vol 6 (101) ◽  
pp. 99096-99104 ◽  
Author(s):  
H. Ramezanalizadeh ◽  
F. Manteghi

In this work, a novel metal–organic framework based composite with BiFeO3 noted as MOF/BiFeO3 has been synthesized and successfully employed as a highly efficient heterogeneous and recoverable catalyst for oxidation of alcohols under mild conditions.


2014 ◽  
Vol 7 (3) ◽  
pp. 257-264 ◽  
Author(s):  
Fariba Sadri ◽  
Ali Ramazani ◽  
Abdolhossain Massoudi ◽  
Mehdi Khoobi ◽  
Roghayeh Tarasi ◽  
...  

2021 ◽  
Vol 99 (1) ◽  
pp. 72-78
Author(s):  
Shiva Zafari ◽  
Ramin Ghorbani-Vaghei ◽  
Sedigheh Alavinia

In this study, a novel heterogeneous catalyst (H3PW12O40/Fe3O4@SiO2-Pr-Pi) was prepared via immobilization of H3PW12O40 on the surface of piperidine modified magnetic nanoparticles (Fe3O4@SiO2-Pr-Pi). The synthesis of dihydro-2-oxypyrrole derivatives was carried out by the reaction of substituted aniline, formaldehyde, and dimethyl acetylenedicarboxylate, promoted by H3PW12O40/Fe3O4@SiO2-Pr-Pi in EtOH. The formation of resultant catalyst was confirmed by FTIR spectroscopy, FE-SEM, EDX, VSM, and TGA techniques. The magnetically separable and environmentally friendly nanostructured catalyst remained quite stable during reaction conditions and was reused for at least five recycle runs.


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