ChemInform Abstract: Synthesis of the Alkoxo(hydrido) Clusters (Ru3(μ-H)(CO)10(μ-OR)) (R: Me, Et, nPr, or nBu) Catalyzed by Dinuclear Carbonyl Iron Complexes.

ChemInform ◽  
1987 ◽  
Vol 18 (22) ◽  
Author(s):  
S. AIME ◽  
M. BOTTA ◽  
R. GOBETTO ◽  
D. OSELLA ◽  
F. PADOVAN
Keyword(s):  
Carbonyl Iron ◽  
Iron Complexes

Synthesis of stable carbonyl-iron complexes of fumaraldehyde.

1991 ◽  
Vol 32 (49) ◽  
pp. 7259-7260 ◽  
Author(s):  
Hassan Cherkaoui ◽  
Jacques Martelli ◽  
René Grée
Keyword(s):  
Carbonyl Iron ◽  
Iron Complexes

The first carbonyl iron complexes with dihydroacepentalene ligands

Tetrahedron ◽  
1986 ◽  
Vol 42 (6) ◽  
pp. 1721-1729 ◽  
Author(s):  
Holger Butenschön ◽  
Armin de Meijere
Keyword(s):  
Carbonyl Iron ◽  
Iron Complexes

Reaktionen an komplexgebundenen Liganden, XXII Synthese und Reaktionen von Cyclopentadienyl-diphosphan-carbonyl-Eisen- und Chrom-Komplexen / Reactions at Complex Bonded Ligands, XXII Synthesis and Reactions of Cyclopentadienyl Diphosphane Carbonyl Iron and Chromium Complexes

1977 ◽  
Vol 32 (9) ◽  
pp. 1010-1014 ◽  
Author(s):  
Dieter Sellmann ◽  
Ernst Kleinschmidt
Keyword(s):  
Uv Irradiation ◽  
Carbonyl Iron ◽  
Iron Complexes ◽  
Chelate Complex ◽  
Chromium Complexes ◽  
Chromium Complex ◽  
Bridging Ligand ◽  
Chelating Ligand ◽  
Binuclear Iron

The synthesis of binuclear iron and chromium complexes with bridging dppe ligands is reported, e.g. [μ-dppe{C5H5Fe(CO)Br}2] or [μ-dppe{C5H5Cr(CO)(NO)}2], (dppe = (C6H5)2PC2H4P(C6H5)2). With hydrazine, these compounds yield no doubly bridged complexes with dppe and N2H4 bridges, neither in dark- nor in photo-reactions. In case of the iron complexes either reduction of the starting complex or transformation of the dppe bridging ligand into a chelating ligand are observed instead. The reactions depend upon the polarity of the solvent and yield [μ-dppe{C5H5Fe(CO)}2] in benzene, however, [C5H5Fe(CO)(dppe)]Br in tetrahydrofuran. The chromium complex undergoes decomposition on UV irradiation, splitting off CO and yielding the chelate complex [C5H5Cr(NO)(dppe)] as well as polymeric [C5H5Cr(NO)]x.

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