Reaction of Silyl(carbonyl)iron Complexes with LiAlH4Giving Methylsilanes: Reduction of a Carbonyl Ligand and Coupling with a Silyl Group

1997 ◽  
Vol 26 (8) ◽  
pp. 805-806 ◽  
Author(s):  
Hiromi Tobita ◽  
Rie Shiozawa ◽  
Hiroshi Ogino
Keyword(s):  
Carbonyl Iron ◽  
Iron Complexes ◽  
Carbonyl Ligand ◽  
Silyl Group

Synthesis of stable carbonyl-iron complexes of fumaraldehyde.

1991 ◽  
Vol 32 (49) ◽  
pp. 7259-7260 ◽  
Author(s):  
Hassan Cherkaoui ◽  
Jacques Martelli ◽  
René Grée
Keyword(s):  
Carbonyl Iron ◽  
Iron Complexes

Juxtaposition of the strong back-bonding carbonyl ligand and weak back-bonding acetonitrile ligand in binuclear iron complexes

2013 ◽  
Vol 38 (6) ◽  
pp. 617-625 ◽  
Author(s):  
Guoliang Li ◽  
Lihua Liu ◽  
Jing Wang ◽  
Qian-shu Li ◽  
Yaoming Xie ◽  
...  
Keyword(s):  
Iron Complexes ◽  
Carbonyl Ligand ◽  
Back Bonding ◽  
Binuclear Iron

scholarly journals Synthesis and Structural Studies of (h3-allyl)carbonylnitrosyl Triphenylphosphine Iron Complexes

2019 ◽  
Vol 70 (11) ◽  
pp. 3893-3898
Author(s):  
Misbah Tabassam ◽  
Muhammad Imran ◽  
Amna Farooq ◽  
Syeda Robina Gillani ◽  
Zaid Mehmood ◽  
...  
Keyword(s):  
Single Crystal ◽  
1H Nmr ◽  
13C Nmr ◽  
Iron Complexes ◽  
Single Crystal Xrd ◽  
Structural Studies ◽  
Atmospheric Conditions ◽  
Carbonyl Ligand ◽  
Distorted Octahedral ◽  
Triphenylphosphine Ligand

In this paper we report the preparation of two (h3-allyl)carbonylnitrosyltriphenylphosphine iron complexes i.e.(p-allyl)carbonylnitrosyltriphenylphosphine iron (1) and (2-methyl-p-allyl) carbonylnit rosyltriphenylphosphine iron (2). These complexes (1) and (2) were prepared by reacting (p-allyl)dicarbonylnitrosyl iron and (2-methyl-p-allyl)dicarbonylnitrosyl iron with triphenylphosphine under inert atmospheric conditions. Both the resulting complexes were sufficiently and well characterized by IR, 1H NMR, 13C NMR, ESI/MS, HRMS and single crystal XRD. Triphenylphosphine ligand was found to be strong sigma donor and replaced carbonyl ligand readily. XRD revealed that the geometry of iron in both complexes is distorted octahedral.

scholarly journals Synthesis and Structural Studies of (h3-allyl)carbonylnitrosyl Triphenylphosphine Iron Complexes

2019 ◽  
Vol 70 (11) ◽  
pp. 3893-3898
Author(s):  
Misbah Tabassam ◽  
Muhammad Imran ◽  
Amna Farooq ◽  
Syeda Robina Gillani ◽  
Zaid Mehmood ◽  
...  
Keyword(s):  
Single Crystal ◽  
1H Nmr ◽  
13C Nmr ◽  
Iron Complexes ◽  
Single Crystal Xrd ◽  
Structural Studies ◽  
Atmospheric Conditions ◽  
Carbonyl Ligand ◽  
Distorted Octahedral ◽  
Triphenylphosphine Ligand

In this paper we report the preparation of two (h3-allyl)carbonylnitrosyltriphenylphosphine iron complexes i.e.(p-allyl)carbonylnitrosyltriphenylphosphine iron (1) and (2-methyl-p-allyl) carbonylnit rosyltriphenylphosphine iron (2). These complexes (1) and (2) were prepared by reacting (p-allyl)dicarbonylnitrosyl iron and (2-methyl-p-allyl)dicarbonylnitrosyl iron with triphenylphosphine under inert atmospheric conditions. Both the resulting complexes were sufficiently and well characterized by IR, 1H NMR, 13C NMR, ESI/MS, HRMS and single crystal XRD. Triphenylphosphine ligand was found to be strong sigma donor and replaced carbonyl ligand readily. XRD revealed that the geometry of iron in both complexes is distorted octahedral.

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