ChemInform Abstract: METAL CORE BINDING ENERGY AND CHARGE DELOCALIZATION IN (OS(NH3)4CLN2CL(NH3)4OS)CL3, A BINUCLEAR MIXED-VALENCE OSMIUM COMPLEX: AN ESCA STUDY

1980 ◽  
Vol 11 (11) ◽  
Author(s):  
M. S. LAZARUS ◽  
T. K. SHAM
Keyword(s):  
Binding Energy ◽  
Mixed Valence ◽  
Metal Core ◽  
Charge Delocalization

Surface binding energy shifts, mixed valence and localization of 4f electrons: Ce vs. Sm (invited)

1981 ◽  
Vol 52 (3) ◽  
pp. 2123-2128 ◽  
Author(s):  
W. Gudat ◽  
M. Campagna ◽  
R. Rosei ◽  
J. H. Weaver ◽  
W. Eberhardt ◽  
...  
Keyword(s):  
Binding Energy ◽  
Mixed Valence ◽  
Surface Binding ◽  
Surface Binding Energy

scholarly journals Charge Delocalization in Self-Assembled Mixed-Valence Aromatic Cation Radicals

Langmuir ◽  
2011 ◽  
Vol 28 (1) ◽  
pp. 71-83 ◽  
Author(s):  
Tushar S. Navale ◽  
Khushabu Thakur ◽  
Vijay S. Vyas ◽  
Shriya H. Wadumethrige ◽  
Ruchi Shukla ◽  
...  
Keyword(s):  
Mixed Valence ◽  
Charge Delocalization ◽  
Cation Radicals ◽  
Self Assembled

scholarly journals Charge Delocalization and Bulk Electronic Conductivity in the Mixed-Valence Metal–Organic Framework Fe(1,2,3-triazolate)2(BF4)x

2018 ◽  
Vol 140 (27) ◽  
pp. 8526-8534 ◽  
Author(s):  
Jesse G. Park ◽  
Michael L. Aubrey ◽  
Julia Oktawiec ◽  
Khetpakorn Chakarawet ◽  
Lucy E. Darago ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Electronic Conductivity ◽  
Mixed Valence ◽  
Charge Delocalization ◽  
Metal Organic ◽  
Organic Framework

Raman Spectroscopy Shows Interchain through Space Charge Delocalization in a Mixed Valence Oligothiophene Cation and in Its π-Dimeric Biradicaloid Dication

2008 ◽  
Vol 130 (43) ◽  
pp. 14028-14029 ◽  
Author(s):  
Juan Casado ◽  
Kazuo Takimiya ◽  
Tetsuo Otsubo ◽  
Francisco J. Ramírez ◽  
J. Joaquín Quirante ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Space Charge ◽  
Mixed Valence ◽  
Charge Delocalization

Spectroscopic and electrochemical properties of ruthenium complexes with photochromic triarylamine–dithienylethene–acetylide ligands

2016 ◽  
Vol 3 (11) ◽  
pp. 1432-1443 ◽  
Author(s):  
Dao-Bin Zhang ◽  
Jin-Yun Wang ◽  
Denis Jacquemin ◽  
Zhong-Ning Chen
Keyword(s):  
Electrochemical Properties ◽  
Mixed Valence ◽  
Ruthenium Complexes ◽  
Progressive Increase ◽  
Charge Delocalization ◽  
System P ◽  
Molecular Backbone

The charge delocalization along the molecular backbone shows a progressive increase following stepwise photocyclization in the inorganic–organic mixed-valence system.

Mössbauer effect study on the mixed valence state of iron in tourmaline

1988 ◽  
Vol 52 (365) ◽  
pp. 221-228 ◽  
Author(s):  
E. A. Ferrow ◽  
H. Annersten ◽  
R. P. Gunawardane
Keyword(s):  
Activation Energy ◽  
Temperature Dependence ◽  
Valence State ◽  
Mixed Valence ◽  
Effect Study ◽  
High Activation ◽  
Charge Delocalization ◽  
Thermally Activated ◽  
Different Temperatures ◽  
Iron Bearing

AbstractMössbauer spectra of iron-bearing tourmaline, obtained at different temperatures, show the existence of thermally-activated charge delocalization among clusters of iron atoms situated in the Y and Z octahedra of the tourmaline structure. The temperature dependence indicates an unusually high activation energy for the delocalization process which suggests that the process takes place between crystallographically non-equivalent sites. Annealing of the tourmaline in hydrogen is observed to inhibit the delocalization process, thus localizing the electron into the Z-site.

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