Absorption spectroscopy and time-dependent theoretical calculation of the intervalence band of [FeIIFeIIIBPMP(OPr)2](BPh4)2, a localized mixed-valence compound with a nonlinear metal-bridging ligand- metal core

1999 ◽  
Vol 23 (4) ◽  
pp. 425-432 ◽  
Author(s):  
Myriam Triest ◽  
Martin J. Davis ◽  
Christian Reber
Keyword(s):  
Theoretical Calculation ◽  
Absorption Spectroscopy ◽  
Mixed Valence ◽  
Time Dependent ◽  
Metal Core ◽  
Bridging Ligand ◽  
Mixed Valence Compound

Comment on “Pressure-induced structural and valence transition in AgO” by C. Hou, J. Botana, X. Zhang, X. Wang and M. Miao, Phys. Chem. Chem. Phys., 2016, 18, 15322

2016 ◽  
Vol 18 (46) ◽  
pp. 31973-31974 ◽  
Author(s):  
Mariana Derzsi ◽  
Wojciech Grochala
Keyword(s):  
Electronic Structure ◽  
Recent Article ◽  
Theoretical Study ◽  
Mixed Valence ◽  
Chem Phys ◽  
External Pressure ◽  
Valence Transition ◽  
Mixed Valence Compound ◽  
Phys Chem Chem Phys

The recent article by Hou et al. has focused on a theoretical study of mixed valence compound AgO in order to elucidate the nature of the electronic structure of this system as a function of external pressure.

Singlet carbenes as mimics for transition metals: synthesis of an air stable organic mixed valence compound [M2(C2)+˙; M = cyclic(alkyl)(amino)carbene]

2014 ◽  
Vol 1 (4) ◽  
pp. 351-354 ◽  
Author(s):  
Liqun Jin ◽  
Mohand Melaimi ◽  
Liu Liu ◽  
Guy Bertrand
Keyword(s):  
Transition Metals ◽  
Radical Cation ◽  
Mixed Valence ◽  
Ethynyl Radical ◽  
Mixed Valence Compound ◽  
Singlet Carbenes

A bis-carbene-stabilized ethynyl radical cation, a purely organic mixed valence compound, is indefinitely air stable.

scholarly journals Mechanistic Investigations of an α-Aminoarylation Photoredox Reaction

2021 ◽  
Author(s):  
Bernard Stevenson ◽  
Ethan Spielvogel ◽  
Emily Loiaconi ◽  
Victor M. Wambua ◽  
Roman Nakhamiyayev ◽  
...  
Keyword(s):  
Quantum Yield ◽  
Absorption Spectroscopy ◽  
Rate Constant ◽  
Kinetic Modeling ◽  
Rate Constants ◽  
Transient Absorption ◽  
Coupling Reaction ◽  
Time Dependent ◽  
Transient Absorption Spectroscopy ◽  
Mechanistic Investigations

We present time-dependent percent and quantum yield measurements of a photoredox-catalyzed coupling reaction between 1,4-dicyanobenzene and N-phenylpyrrolidine. We also use transient absorption spectroscopy to examine the kinetics within the reaction and use kinetic modeling to extract rate constants and predict how changes in rate constant will impact the quantum yield.

Crystal structure and properties of a new mixed-valence compound LiMn2TeO6 and the survey of the LiMM′XO6 family (X = Sb or Te)

2011 ◽  
Vol 13 (11) ◽  
pp. 1931-1937 ◽  
Author(s):  
A.A. Pospelov ◽  
V.B. Nalbandyan ◽  
E.I. Serikova ◽  
B.S. Medvedev ◽  
M.A. Evstigneeva ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Mixed Valence ◽  
Structure And Properties ◽  
Mixed Valence Compound

Effect of pressure on resistivity and Mössbauer spectra of the mixed valence compound Sn2S3

1979 ◽  
Vol 70 (11) ◽  
pp. 4837-4842 ◽  
Author(s):  
G. Amthauer ◽  
J. Fenner ◽  
S. Hafner ◽  
W. B. Holzapfel ◽  
R. Keller
Keyword(s):  
Mössbauer Spectra ◽  
Mixed Valence ◽  
Effect Of Pressure ◽  
Mossbauer Spectra ◽  
Mixed Valence Compound
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