Spectroscopic and electrochemical properties of ruthenium complexes with photochromic triarylamine–dithienylethene–acetylide ligands

2016 ◽  
Vol 3 (11) ◽  
pp. 1432-1443 ◽  
Author(s):  
Dao-Bin Zhang ◽  
Jin-Yun Wang ◽  
Denis Jacquemin ◽  
Zhong-Ning Chen
Keyword(s):  
Electrochemical Properties ◽  
Mixed Valence ◽  
Ruthenium Complexes ◽  
Progressive Increase ◽  
Charge Delocalization ◽  
System P ◽  
Molecular Backbone

The charge delocalization along the molecular backbone shows a progressive increase following stepwise photocyclization in the inorganic–organic mixed-valence system.

Spectroscopic and magnetic studies on electrogenerated mixed-valence ruthenium complexes

1982 ◽  
Vol 233 (3) ◽  
pp. 353-358 ◽  
Author(s):  
G.A. Heath ◽  
A.J. Lindsay ◽  
T.A. Stephenson ◽  
D.K. Vattis
Keyword(s):  
Mixed Valence ◽  
Ruthenium Complexes ◽  
Magnetic Studies

scholarly journals Variable Coordination Modes of Benzaldehyde Thiosemicarbazones - Synthesis, Structure, and Electrochemical Properties of Some Ruthenium Complexes

2008 ◽  
Vol 2008 (29) ◽  
pp. 4538-4546 ◽  
Author(s):  
Swati Dutta ◽  
Falguni Basuli ◽  
Alfonso Castineiras ◽  
Shie-Ming Peng ◽  
Gene-Hsiang Lee ◽  
...  
Keyword(s):  
Electrochemical Properties ◽  
Ruthenium Complexes ◽  
Coordination Modes ◽  
Variable Coordination

Syntheses, Crystal Structures and Electrochemical Properties of Acetylacetonato-Ruthenium Complexes Containing Substituted Pyridine Ligands

2013 ◽  
Vol 68 (9) ◽  
pp. 993-999 ◽  
Author(s):  
Xiuli Wu ◽  
Rufei Ye ◽  
Ai-Quan Jia ◽  
Qun Chen ◽  
Qian-Feng Zhang
Keyword(s):  
Electrochemical Properties ◽  
Crystal Structures ◽  
Zinc Dust ◽  
Ruthenium Complexes ◽  
Reducing Agent ◽  
Molecular Structures ◽  
X Ray ◽  
X Ray Crystallography ◽  
Crystal And Molecular Structures ◽  
Pyridine Ligands

Treatment of Ru(acac)3 with 2-cyano-pyridine and 3,5-dimethyl-pyridine in the presence of zinc dust as reducing agent in refluxing THF afforded the ruthenium(II) complexes cis-[RuII(acac)2(2- CN-py)2] (1) and cis-[RuII(acac)2(3,5-Me2-py)2] (2), respectively. Interaction of Ru(acac)3 with 3- Me-pyridine and 3,5-Me2-pyridine in the presence of Br2 in refluxing THF gave the ruthenium(III) complexes [RuIII(acac)Br2(3-Me-py)2] (3) and [RuIII(acac)Br2(3,5-Me2-py)2] (4), respectively. The four complexes have been spectroscopically and electrochemically characterized, and their crystal and molecular structures have been established by X-ray crystallography

An Investigation of Superexchange in Dinuclear Mixed-Valence Ruthenium Complexes

1998 ◽  
Vol 120 (50) ◽  
pp. 13096-13103 ◽  
Author(s):  
Christopher E. B. Evans ◽  
Mark L. Naklicki ◽  
Ali R. Rezvani ◽  
Christopher A. White ◽  
Veniamin V. Kondratiev ◽  
...  
Keyword(s):  
Mixed Valence ◽  
Ruthenium Complexes
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