Microchannel Emulsification Using Stainless-Steel Chips: Oil Droplet Generation Characteristics

2012 ◽  
Vol 35 (10) ◽  
pp. 1865-1871 ◽  
Author(s):  
I. Kobayashi ◽  
Y. Wada ◽  
Y. Hori ◽  
M. A. Neves ◽  
K. Uemura ◽  
...  
Lab on a Chip ◽  
2009 ◽  
Vol 9 (13) ◽  
pp. 1957 ◽  
Author(s):  
Su-Kyoung Chae ◽  
Chang-Ha Lee ◽  
Soo Hyun Lee ◽  
Tae-Song Kim ◽  
Ji Yoon Kang

2018 ◽  
Vol 37 (1) ◽  
pp. 68-73 ◽  
Author(s):  
Ran Li ◽  
Isao Kobayashi ◽  
Yanru Zhang ◽  
Marcos A. Neves ◽  
Kunihiko Uemura ◽  
...  

Author(s):  
Isao Kobayashi ◽  
Katerina Butron Fujiu ◽  
Marcos A. Neves ◽  
Mitsutoshi Nakajima

Microfluidic techniques for producing emulsions have been proposed over the last decade. Major advantages of microfluidic techniques include the production of monodisperse emulsions with a coefficient of variation (CV) of typically <5%, superior controllability of droplet size and monodispersity, and in situ microscopic monitoring. Microchannel (MC) emulsification, proposed by our research group, is a unique and robust technique to produce monodisperse emulsions with controlled droplet sizes of >1 μm. In MC emulsification, droplet generation via MC arrays does not require any external shear/elongational stress; i.e., the dispersed phase that passed through MCs is transformed spontaneously into uniform droplets due to hydrodynamic instability of the oil-water interface. Here we present some of the recent findings obtained from MC emulsification studies and the controlled production of monodisperse submicron emulsions by novel nanochannel (NC) emulsification. The first topic on MC emulsification is the influence of operating temperature (10 to 70 °C) on production of oil-in-water (O/W) emulsions using a surface-oxidized silicon MC array plate with an MC depth of 8 μm. The droplet generation results were correlated well with the contact angle of the dispersed phase to the MC walls that was measured using a novel method using parallel long MCs. Another topic on MC emulsification is the development of stainless-steel MC emulsification devices. Stainless-steel MC array plates with an MC depth of 100 or 150 μm were mechanically fabricated using an end mill. The use of the stainless-steel MC array plates enabled stably producing monodisperse O/W emulsions with an average droplet diameter of up to 550 μm. We also recently developed silicon NC array plates with the smallest NC depth of 50 nm. NC emulsification experiments demonstrated successful production of monodisperse submicron O/W emulsions with the smallest average droplet diameter of 480 nm. The diameter of the droplets generated by NC emulsification was measured by a novel technique that exploits nanospace.


Author(s):  
L.E. Murr ◽  
J.S. Dunning ◽  
S. Shankar

Aluminum additions to conventional 18Cr-8Ni austenitic stainless steel compositions impart excellent resistance to high sulfur environments. However, problems are typically encountered with aluminum additions above about 1% due to embrittlement caused by aluminum in solid solution and the precipitation of NiAl. Consequently, little use has been made of aluminum alloy additions to stainless steels for use in sulfur or H2S environments in the chemical industry, energy conversion or generation, and mineral processing, for example.A research program at the Albany Research Center has concentrated on the development of a wrought alloy composition with as low a chromium content as possible, with the idea of developing a low-chromium substitute for 310 stainless steel (25Cr-20Ni) which is often used in high-sulfur environments. On the basis of workability and microstructural studies involving optical metallography on 100g button ingots soaked at 700°C and air-cooled, a low-alloy composition Fe-12Cr-5Ni-4Al (in wt %) was selected for scale up and property evaluation.


Author(s):  
J. A. Korbonski ◽  
L. E. Murr

Comparison of recovery rates in materials deformed by a unidimensional and two dimensional strains at strain rates in excess of 104 sec.−1 was performed on AISI 304 Stainless Steel. A number of unidirectionally strained foil samples were deformed by shock waves at graduated pressure levels as described by Murr and Grace. The two dimensionally strained foil samples were obtained from radially expanded cylinders by a constant shock pressure pulse and graduated strain as described by Foitz, et al.


Author(s):  
R. Gonzalez ◽  
L. Bru

The analysis of stacking fault tetrahedra (SFT) in fatigued metals (1,2) is somewhat complicated, due partly to their relatively low density, but principally to the presence of a very high density of dislocations which hides them. In order to overcome this second difficulty, we have used in this work an austenitic stainless steel that deforms in a planar mode and, as expected, examination of the substructure revealed planar arrays of dislocation dipoles rather than the cellular structures which appear both in single and polycrystals of cyclically deformed copper and silver. This more uniform distribution of dislocations allows a better identification of the SFT.The samples were fatigue deformed at the constant total strain amplitude Δε = 0.025 for 5 cycles at three temperatures: 85, 293 and 773 K. One of the samples was tensile strained with a total deformation of 3.5%.


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