Transformation of Silanes into Silanols using Water and Recyclable Metal Nanoparticle Catalysts

ChemCatChem ◽  
2012 ◽  
Vol 4 (4) ◽  
pp. 521-524 ◽  
Author(s):  
Mina Jeon ◽  
Junghoon Han ◽  
Jaiwook Park
Keyword(s):  
Metal Nanoparticle ◽  
Nanoparticle Catalysts

scholarly journals Transition-Metal Nanoparticle Catalysts Anchored on Carbon Supports via Short-Chain Alginate Linkers

2021 ◽  
Author(s):  
Joakim Tafjord ◽  
Erling Rytter ◽  
Anders Holmen ◽  
Rune Myrstad ◽  
Ingeborg-Helene Svenum ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Nanoparticle ◽  
Short Chain ◽  
Carbon Supports ◽  
Nanoparticle Catalysts

scholarly journals Polymer-supported CuPd nanoalloy as a synergistic catalyst for electrocatalytic reduction of carbon dioxide to methane

2015 ◽  
Vol 112 (52) ◽  
pp. 15809-15814 ◽  
Author(s):  
Sheng Zhang ◽  
Peng Kang ◽  
Mohammed Bakir ◽  
Alexander M. Lapides ◽  
Christopher J. Dares ◽  
...  
Keyword(s):  
State Of The Art ◽  
Metal Nanoparticle ◽  
Local Concentration ◽  
Electrocatalytic Reduction ◽  
Catalytic Current ◽  
Faradaic Efficiency ◽  
Nanoparticle Catalysts ◽  
Ultrafine Metal ◽  
Current Densities ◽  
Energy Strategies

Developing sustainable energy strategies based on CO2 reduction is an increasingly important issue given the world’s continued reliance on hydrocarbon fuels and the rise in CO2 concentrations in the atmosphere. An important option is electrochemical or photoelectrochemical CO2 reduction to carbon fuels. We describe here an electrodeposition strategy for preparing highly dispersed, ultrafine metal nanoparticle catalysts on an electroactive polymeric film including nanoalloys of Cu and Pd. Compared with nanoCu catalysts, which are state-of-the-art catalysts for CO2 reduction to hydrocarbons, the bimetallic CuPd nanoalloy catalyst exhibits a greater than twofold enhancement in Faradaic efficiency for CO2 reduction to methane. The origin of the enhancement is suggested to arise from a synergistic reactivity interplay between Pd–H sites and Cu–CO sites during electrochemical CO2 reduction. The polymer substrate also appears to provide a basis for the local concentration of CO2 resulting in the enhancement of catalytic current densities by threefold. The procedure for preparation of the nanoalloy catalyst is straightforward and appears to be generally applicable to the preparation of catalytic electrodes for incorporation into electrolysis devices.

Soluble porous carbon cage-encapsulated highly active metal nanoparticle catalysts

2021 ◽  
Author(s):  
Hangyu Liu ◽  
Liyu Chen ◽  
Chun-Chao Hou ◽  
Yong-Sheng Wei ◽  
Qiang Xu
Keyword(s):  
Porous Carbon ◽  
Metal Organic Framework ◽  
Metal Nanoparticle ◽  
Hydrogen Peroxide Decomposition ◽  
Carbon Cage ◽  
Nanoparticle Catalysts ◽  
Highly Active ◽  
Active Metal ◽  
Peroxide Decomposition ◽  
Metal Organic

Metal nanoparticles are encapsulated within soluble porous carbon cages by a silica-shelled metal–organic framework pyrolysis approach. The catalyst shows high catalytic activities for hydrogen peroxide decomposition and ammonia borane hydrolysis.

Monodisperse Metal Nanoparticle Catalysts: Synthesis, Characterizations, and Molecular Studies Under Reaction Conditions

2012 ◽  
Vol 55 (19-20) ◽  
pp. 1257-1275 ◽  
Author(s):  
Vladimir V. Pushkarev ◽  
Zhongwei Zhu ◽  
Kwangjin An ◽  
Antoine Hervier ◽  
Gabor A. Somorjai
Keyword(s):  
Metal Nanoparticle ◽  
Reaction Conditions ◽  
Nanoparticle Catalysts ◽  
Molecular Studies

Building up strain in colloidal metal nanoparticle catalysts

Nanoscale ◽  
2015 ◽  
Vol 7 (29) ◽  
pp. 12248-12265 ◽  
Author(s):  
Brian T. Sneed ◽  
Allison P. Young ◽  
Chia-Kuang Tsung
Keyword(s):  
Electronic Structure ◽  
Lattice Strain ◽  
Catalytic Properties ◽  
Research Topic ◽  
Metal Nanoparticle ◽  
Nanoparticle Catalysts ◽  
Surface Electronic Structure ◽  
Surface Lattice ◽  
Fundamental Research ◽  
Colloidal Metal

The focus on surface lattice strain in nanostructures as a fundamental research topic has gained momentum in recent years as scientists investigated its significant impact on the surface electronic structure and catalytic properties of nanomaterials.

Sign in / Sign up

Export Citation Format

Share Document