Site Specific Surface Interaction of Electron Donors and Acceptors on FeS2(100) Cleavage Planes

1991 ◽  
Vol 95 (5) ◽  
pp. 560-565 ◽  
Author(s):  
C. Pettenkofer ◽  
W. Jaegermann ◽  
M. Bronold
ChemInform ◽  
2010 ◽  
Vol 23 (21) ◽  
pp. no-no
Author(s):  
M. SANDER ◽  
W. JAEGERMANN ◽  
H. J. LEWERENZ

Small ◽  
2018 ◽  
Vol 14 (21) ◽  
pp. 1800131 ◽  
Author(s):  
Seyed Mohammad Mahdi Dadfar ◽  
Sylwia Sekula-Neuner ◽  
Uwe Bog ◽  
Vanessa Trouillet ◽  
Michael Hirtz

2010 ◽  
Vol 50 (4) ◽  
pp. 449-452 ◽  
Author(s):  
U. Burghaus ◽  
A. Zak ◽  
R. Rosentsveig

Author(s):  
Jian-Shing Luo ◽  
Lang-Yu Huang ◽  
Wen-Lon Gu ◽  
Jeremy D. Russell

Abstract This paper demonstrates a novel method of XTEM sample preparation for site-specific surface defect analysis using backside polishing. Analysis of three different types of site-specific surface defects was demonstrated using a novel backside XTEM sample preparation method. The details of the backside XTEM sample preparation method and some examples are reported in this paper. Comparing to Auger electron spectrometry (AES) results on similar defects, more detailed and precise information is observed using TEM analysis with this method. It is therefore a complementary technique to traditional AES analysis on surface defects for contamination with atomic level concentration. From the results, the sample preparation method can produce a clean, pristine surface that is well characterized and could be reproduced, successfully.


2018 ◽  
Vol 47 (42) ◽  
pp. 14884-14888 ◽  
Author(s):  
Yan-Ling Li ◽  
Wen-Min Zhang ◽  
Jie Wang ◽  
Yuan Tian ◽  
Zhao-Yang Wang ◽  
...  

Wide-range photoluminescence modulation of a Ag12 nanocluster was achieved by site-specific surface modification with a variety of fluorescent pyridyl ligands.


2006 ◽  
Vol 84 (2) ◽  
pp. 176-186 ◽  
Author(s):  
John P Canal ◽  
Michael C Jennings ◽  
Glenn PA Yap ◽  
Roland K Pomeroy

The cluster Os4(µ-η2-C2Ph2)(CO)14 (1) has been prepared from the reaction of Os4(CO)14 and C2Ph2 in CH2Cl2 at 25 °C. Other minor products include the known clusters Os3(µ3-η2-C2Ph2)(CO)10 and Os3(µ-η4-C4Ph4)(CO)9. The structure of 1 reveals an approximately planar C2Os4 skeleton with a dimetallacyclobutene ring (C—C = 1.32(4) Å) and a flat butterfly Os4 unit (Os—Os range = 2.859(2)–2.916(2) Å). The 13C{1H} NMR spectrum of 1 indicates the carbonyl ligands are rigid at room temperature. Stirring 1 in CH2Cl2 for 2 days (ambient temperature) afforded Os4(µ3-η2-C2Ph2)(CO)13 (2). The Os atoms in 2 also have an almost flat butterfly arrangement (Os—Os range = 2.7392(7)–2.8947(6) Å) with the alkyne ligand located over one of the Os3 triangles. The 13C NMR data for 2 are consistent with rapid rotation on the NMR timescale of the hinge Os(CO)3 units at 21 °C, but slow rotation at –50 °C. Heating 2 at 40 °C gave Os4(µ4-η2-C2Ph2)(CO)12 (3) after 2 days. Cluster 3 has the common butterfly arrangement of Os atoms with the C2Ph2 bound to all four metal atoms (Os—Os range = 2.7457(5)–2.8742(5) Å). The 13C{1H} NMR spectra of 3 at 21 and 90 °C indicate there is rapid CO exchange of the carbonyls of the two types of Os(CO)3 units, but not between the units. The spectrum at –90 °C indicates one of the rotations (presumed to be that involving the carbonyls of the wingtip Os(CO)3 units) is slowed on the NMR timescale. Compounds 1–3 form a unique series of clusters that have an alkyne ligand bound to two, three, and four metal atoms. Compound 1 is a model for a corner, compound 2 for a planar surface, and compound 3 a step site, in site-specific surface catalysts.Key words: osmium cluster, diphenylacetylene, dimetallacyclobutene, carbonyl exchange, surface catalysis.


1987 ◽  
Vol 173 (2) ◽  
pp. 606-616 ◽  
Author(s):  
David Nishioka ◽  
James S. Trimmer ◽  
Dominic Poccia ◽  
Victor D. Vacquier

Sign in / Sign up

Export Citation Format

Share Document