Epoxy loaded poly(urea‐formaldehyde) microcapsules via in situ polymerization designated for self‐healing coatings

2020 ◽  
Vol 137 (43) ◽  
pp. 49323 ◽  
Author(s):  
Sofia Tzavidi ◽  
Christos Zotiadis ◽  
Athanasios Porfyris ◽  
Dimitrios M. Korres ◽  
Stamatina Vouyiouka
Keyword(s):  
In Situ Polymerization ◽  
Urea Formaldehyde ◽  
Self Healing

scholarly journals Self-Healing EPDM Rubbers with Highly Stable and Mechanically-Enhanced Urea-Formaldehyde (UF) Microcapsules Prepared by Multi-Step In Situ Polymerization

Polymers ◽  
2020 ◽  
Vol 12 (9) ◽  
pp. 1918 ◽  
Author(s):  
Hyeong-Jun Jeoung ◽  
Kun Won Kim ◽  
Yong Jun Chang ◽  
Yong Chae Jung ◽  
Hyunchul Ku ◽  
...  
Keyword(s):  
Mechanical Stability ◽  
In Situ Polymerization ◽  
Urea Formaldehyde ◽  
Testing Machine ◽  
Optical Microscope ◽  
The Self ◽  
Self Healing ◽  
Grubbs Catalyst ◽  
Healing Efficiency

The mechanically-enhanced urea-formaldehyde (UF) microcapsules are developed through a multi-step in situ polymerization method. Optical microscope (OM) and field emission scanning electron microscope (FE-SEM) prove that the microcapsules, 147.4 μm in diameter with a shell thickness of 600 nm, are well-formed. From 1H-nuclear magnetic resonance (1H-NMR) analysis, we found that dicyclopentadiene (DCPD), a self-healing agent encapsulated by the microcapsules, occupies ca. 40.3 %(v/v) of the internal volume of a single capsule. These microcapsules are mixed with EPDM (ethylene-propylene-diene-monomer) and Grubbs’ catalyst via a solution mixing method, and universal testing machine (UTM) tests show that the composites with mechanically-enhanced microcapsules has ca. 47% higher toughness than the composites with conventionally prepared UF microcapsules, which is attributed to the improved mechanical stability of the microcapsule. When the EPDM/microcapsule rubber composites are notched, Fourier-transform infrared (FT-IR) spectroscopy shows that DCPD leaks from the broken microcapsule to the damaged site and flows to fill the notched valley, and self-heals as it is cured by Grubbs’ catalyst. The self-healing efficiency depends on the capsule concentration in the EPDM matrix. However, the self-healed EPDM/microcapsule rubber composite with over 15 wt% microcapsule shows an almost full recovery of the mechanical strength and 100% healing efficiency.

scholarly journals Green synthesis of nanocapsules for self-healing anticorrosion coating using ultrasound-assisted approach

2018 ◽  
Vol 7 (2) ◽  
pp. 147-159 ◽  
Author(s):  
Uday D. Bagale ◽  
Shirish H. Sonawane ◽  
Bharat A. Bhanvase ◽  
Ravindra D. Kulkarni ◽  
Parag R. Gogate
Keyword(s):  
Corrosion Inhibition ◽  
Electrochemical Impedance ◽  
In Situ Polymerization ◽  
Urea Formaldehyde ◽  
Immersion Test ◽  
Epoxy Coating ◽  
Self Healing ◽  
Actual Performance ◽  
Ultrasound Assisted

Abstract The present work deals with the production of nanocapsules containing a natural corrosion inhibition component. Azadirachta indica was encapsulated in urea-formaldehyde polymeric shell using ultrasound-assisted and conventional approaches of in situ polymerization. Subsequently nanocapsules were incorporated into clear epoxy polyamide to develop the green self-healing corrosion inhibition coating. The actual performance of the coating was evaluated based on the studies involving the repair of the crack of high solid surface coating. Corrosion inhibition of the healed area has been evaluated using the electrochemical impedance spectroscopy and immersion test based on the use of standard epoxy coating. The obtained results confirmed better corrosion protection in terms of the electrochemical impendence spectroscopy data and Tafel plot. It was found that current density decreases from 0.0011 A/cm2 (for standard epoxy coating) to 5.22 E−7 A/cm2 as 4 wt% nanocapsules incorporated in coating.

Mechanical Properties of Self-Healing System in Cementitious Material with Microcapsule

2018 ◽  
Vol 913 ◽  
pp. 1090-1096 ◽  
Author(s):  
Peng Liang ◽  
Qian Jin Mao ◽  
Zi Ming Wang ◽  
Su Ping Cui
Keyword(s):  
Particle Size ◽  
Compressive Strength ◽  
In Situ Polymerization ◽  
Urea Formaldehyde ◽  
Strength Loss ◽  
Cementitious Materials ◽  
Self Healing ◽  
Healing System ◽  
The Matrix

In this paper, several urea–formaldehyde/epoxy microcapsules with different particle sizes were synthesized by in-situ polymerization. The chemical structure and compressive rupture load of microcapsule were characterized. The effect of microcapsule dosage, particle size and preload pressure on compressive strength of cementitious materials was studied. The result shows: when the particle size of microcapsule is 2 mm~2.5 mm, the rupture load of microcapsule is highest, more than 3N; When the microcapsule dosage is less than 2.5%, the strength loss of the matrix is relatively small; With the increase of the particle size of the capsule, the strength of the matrix decrease greatly; When the dosage of microcapsule is 2.5%, the particle size is 1.5 mm and the preload pressure is 30%~45%fmax, the compressive strength of the self-healing specimen is 8% higher than that of the non-preloaded specimens, which shows a certain self-healing performance.

Self-healing coatings based on poly(urea-formaldehyde) microcapsules: In situ polymerization, capsule properties and application

2021 ◽  
Vol 161 ◽  
pp. 106475
Author(s):  
Christos Zotiadis ◽  
Ioannis Patrikalos ◽  
Vasileia Loukaidou ◽  
Dimitrios M. Korres ◽  
Antonis Karantonis ◽  
...  
Keyword(s):  
In Situ Polymerization ◽  
Urea Formaldehyde ◽  
Self Healing

Preparation and Characterization of Microcapsules for Self-Healing Material

2012 ◽  
Vol 430-432 ◽  
pp. 960-963 ◽  
Author(s):  
Wan Peng Ma ◽  
Wei Zhang ◽  
Yang Zhao ◽  
Le Ping Liao ◽  
Si Jie Wang
Keyword(s):  
In Situ Polymerization ◽  
Urea Formaldehyde ◽  
Self Healing ◽  
Water Emulsion ◽  
Good Thermal Stability ◽  
Oil In Water ◽  
Inner Surface ◽  
Oil In Water Emulsion

Urea-formaldehyde microcapsules containing epoxy resin is a promising material for self-healing design. The microcapsules were prepared by in-situ polymerization in an oil-in-water emulsion. The microcapsule formation process was monitored using optical microscopy. Surface morphology was observed using field emission scanning electron microscopy. The thermal property of microcapsules was characterized using thermogravimetric analysis. The results indicate that microcapsule wall has a rough outer surface and a smooth inner surface. The microcapsule size is controlled by different agitation rates. Microcapsules have a good thermal stability below 157°C.

Preparation and Characterization of Hexadecane Microcapsule Phase Change Materials by In Situ Polymerization

2013 ◽  
Vol 815 ◽  
pp. 367-370 ◽  
Author(s):  
Xiao Qiu Song ◽  
Yue Xia Li ◽  
Jing Wen Wang
Keyword(s):  
Particle Size ◽  
Phase Change ◽  
Phase Change Materials ◽  
In Situ Polymerization ◽  
Urea Formaldehyde ◽  
Agitation Speed ◽  
Urea Formaldehyde Resin ◽  
Formaldehyde Resin ◽  
Mass Ratio

Hexadecane microcapsule phase change materials were prepared by the in-situ polymerization method using hexadecane as core materials, urea-formaldehyde resin and urea-formaldehyde resin modified with melamine as shell materials respectively. Effect of melamine on the properties of microcapsules was studied by FTIR, biomicroscopy (UBM), TGA and HPLC. The influences of system concentration, agitation speed and mass ratio of wall to core were also investigated. The results indicated that hexadecane was successfully coated by the two types of shell materials. The addition of melamine into the urea-formaldehyde resin microcapsule reduced microcapsule particle size and microencapsulation efficiency. The influences of factors such as system concentration, agitation speed and mass ratio of wall to core to different wall materials microcapsules presented different variety trends of the microcapsule particle size.

scholarly journals Microencapsulation of Liquid Cyanoacrylate via In Situ Polymerization for Self-healing Bone Cement Application – ERRATUM

2012 ◽  
Vol 1417 ◽  
pp. 1-13
Author(s):  
Vineela D. Gandham ◽  
Alice B.W. Brochu ◽  
William M. Reichert
Keyword(s):  
Bone Cement ◽  
In Situ Polymerization ◽  
Self Healing ◽  
Healing Bone

Poly(urea-formaldehyde) microcapsules containing commercial paraffin: in situ polymerization study

2018 ◽  
Vol 296 (9) ◽  
pp. 1449-1457 ◽  
Author(s):  
L. Sánchez-Silva ◽  
V. Lopez ◽  
N. Cuenca ◽  
J. L. Valverde
Keyword(s):  
In Situ Polymerization ◽  
Urea Formaldehyde

Microencapsulation of Epoxy Resins for Self-Healing Material

2010 ◽  
Vol 148-149 ◽  
pp. 1031-1035
Author(s):  
Yang Zhao ◽  
Wei Zhang ◽  
Le Ping Liao ◽  
Wu Jun Li ◽  
Yi Xin
Keyword(s):  
Epoxy Resins ◽  
In Situ Polymerization ◽  
Heating Temperature ◽  
Hot Water ◽  
Core Material ◽  
Agitation Rate ◽  
Self Healing ◽  
Water Emulsion ◽  
Oil In Water Emulsion

With the development of the embedded microcapsule concept for self-healing material, the preparation of microcapsule has been paid more attentions. A new series of microcapsules were prepared by in situ polymerization technology in an oil-in-water emulsion with polyoxymethylene urea (PMU) as shell material and a mixture of epoxy resins as core material. The PMU microcapsules were characterized by Fourier transform infrared spectroscopy (FTIR), scanning electronic microscopy (SEM), particle size analyzer and thermo gravimetric analyzer (TGA) to investigate their chemical structure, surface morphology, size distribution and thermal stability, respectively. The results indicate that PMU microcapsules containing epoxy resins can be synthesized successfully. The optimized reaction parameters were obtained as follow: agitation rate 600 rpm, 60°C water bath, pH=3.5, core material 20ml and hot water dilution by in-situ polymerization. The size is around 116 μm. The rough outer surface of microcapsule is composed of agglomerated PMU nanoparticles. The microcapsules basically exhibit good storage stability at room temperature, and they are chemically stable before the heating temperature is up to approximately 200°C.

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