Glycerol-plasticized spirulina-poly(vinyl alcohol) films with improved mechanical performance

2017 ◽  
Vol 134 (20) ◽  
Author(s):  
Bo Shi ◽  
Liang Liang ◽  
Hui Yang ◽  
Liming Zhang ◽  
Fuan He
2005 ◽  
Vol 284-286 ◽  
pp. 469-472 ◽  
Author(s):  
Caihong You ◽  
Toshiki Miyazaki ◽  
Eiichi Ishida ◽  
Masahiro Ashizuka ◽  
Chikara Ohtsuki ◽  
...  

Organic polymers with ability of apatite formation in body environment are expected as novel bone substitutes having not only bone-bonding ability, i.e. bioactivity, but also mechanical performance analogous to natural bone. Several metal oxides have been found to be effective for the apatite deposition in body environment. In addition, release of calcium ions from the materials significantly enhances it. In this study, we attempted to synthesize bioactive organic-inorganic hybrids from Poly(vinyl alcohol) (PVA) by incorporation of various metal oxides and calcium salt. Silica and molybdenum oxides were selected as metal oxides. Ability of apatite formation on the hybrids was examined in vitro using simulated body fluid (SBF, Kokubo solution). Apatite deposition were observed to occur on the surfaces of PVA/silica and PVA/molybdenum oxide hybrids in SBF, when their compositions were appropriately controlled.


Small ◽  
2013 ◽  
Vol 9 (14) ◽  
pp. 2466-2472 ◽  
Author(s):  
Luqi Liu ◽  
Yun Gao ◽  
Qing Liu ◽  
Jun Kuang ◽  
Ding Zhou ◽  
...  

2018 ◽  
Vol 1 (4) ◽  
pp. 722-730 ◽  
Author(s):  
Shuai Yang ◽  
Yongxu Liu ◽  
Zaixing Jiang ◽  
Jiyou Gu ◽  
Dawei Zhang

2006 ◽  
Vol 309-311 ◽  
pp. 1153-1156 ◽  
Author(s):  
Caihong You ◽  
Toshiki Miyazaki ◽  
Eiichi Ishida ◽  
Masahiro Ashizuka ◽  
Chikara Ohtsuki

Organic polymers with ability of apatite formation in body environment are expected as novel bone substitutes having not only bone-bonding ability, i.e. bioactivity, but also mechanical performance analogous to natural bone. Several metal oxides have been found to be effective for the apatite deposition in body environment. In addition, release of calcium ions from the materials significantly enhances it. In this study, we attempted to synthesize bioactive organic-inorganic hybrids from poly(vinyl alcohol) (PVA) by incorporation of titanium oxide or zirconium oxide as well as calcium salt. Ability of apatite formation on the hybrids was examined in vitro using simulated body fluid (SBF, Kokubo solution). Apatite deposition was observed to occur on the surfaces of PVA/titanium oxide hybrids in SBF, when their compositions were appropriately controlled.


2013 ◽  
Vol 52 (18) ◽  
pp. 6177-6181 ◽  
Author(s):  
Dagang Liu ◽  
Changqing Zhu ◽  
Kai Peng ◽  
Yi Guo ◽  
Peter R. Chang ◽  
...  

Polymers ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 497 ◽  
Author(s):  
Johana Andrade ◽  
Chelo González-Martínez ◽  
Amparo Chiralt

Lecithin-encapsulated carvacrol has been incorporated into poly (vinyl alcohol) (PVA) for the purpose of obtaining active films for food packaging application. The influence of molecular weight (Mw) and degree of hydrolysis (DH) of the polymer on its ability to retain carvacrol has been analysed, as well as the changes in the film microstructure, thermal behaviour, and functional properties as packaging material provoked by liposome incorporation into PVA matrices. The films were obtained by casting the PVA aqueous solutions where liposomes were incorporated until reaching 0 (non-loaded liposomes), 5 or 10 g carvacrol per 100 g polymer. The non-acetylated, high Mw polymer provided films with a better mechanical performance, but less CA retention and a more heterogeneous structure. In contrast, partially acetylated, low Mw PVA gave rise to more homogenous films with a higher carvacrol content. Lecithin enhanced the thermal stability of both kinds of PVA, but reduced the crystallinity degree of non-acetylated PVA films, although it did not affect this parameter in acetylated PVA when liposomes contained carvacrol. The mechanical and barrier properties of the films were modified by liposome incorporation in line with the induced changes in crystallinity and microstructure of the films.


Polymers ◽  
2019 ◽  
Vol 12 (1) ◽  
pp. 7 ◽  
Author(s):  
Marta A. Teixeira ◽  
M. Teresa P. Amorim ◽  
Helena P. Felgueiras

Tissue engineering (TE) holds an enormous potential to develop functional scaffolds resembling the structural organization of native tissues, to improve or replace biological functions and prevent organ transplantation. Amongst the many scaffolding techniques, electrospinning has gained widespread interest because of its outstanding features that enable the production of non-woven fibrous structures with a dimensional organization similar to the extracellular matrix. Various polymers can be electrospun in the form of three-dimensional scaffolds. However, very few are successfully processed using environmentally friendly solvents; poly(vinyl alcohol) (PVA) is one of those. PVA has been investigated for TE scaffolding production due to its excellent biocompatibility, biodegradability, chemo-thermal stability, mechanical performance and, most importantly, because of its ability to be dissolved in aqueous solutions. Here, a complete overview of the applications and recent advances in PVA-based electrospun nanofibrous scaffolds fabrication is provided. The most important achievements in bone, cartilage, skin, vascular, neural and corneal biomedicine, using PVA as a base substrate, are highlighted. Additionally, general concepts concerning the electrospinning technique, the stability of PVA when processed, and crosslinking alternatives to glutaraldehyde are as well reviewed.


Polymers ◽  
2019 ◽  
Vol 11 (4) ◽  
pp. 610 ◽  
Author(s):  
Shaojian He ◽  
Jiaqi Wang ◽  
Mengxia Yu ◽  
Yang Xue ◽  
Jianbin Hu ◽  
...  

Owing to the high aspect ratio, the two-dimensional (2D) inorganic nanofillers have attracted extensive interest in the field of polymer reinforcement. In this work, graphitic carbon nitride (g-C3N4) nanosheets were obtained via thermal condensation of melamine and were then ultrasonically exfoliated in water, which was confirmed by atomic force microscopy (AFM) and TEM. Poly(vinyl alcohol) (PVA)/g-C3N4 nanocomposites were achieved by solution casting using water as the solvent. The structure and mechanical performance of PVA/g-C3N4 nanocomposites were studied. It was found that the g-C3N4 nanosheets were well dispersed in the PVA matrix. The introduction of g-C3N4 nanosheets increased the glass transition temperature and crystallinity of the nanocomposites, leading to the improved mechanical performance. Compared with the pure PVA, the PVA/g-C3N4 nanocomposite with 0.50 wt% g-C3N4 nanosheets showed ~70.7% enhancement in tensile strength, up from 51.2 MPa to 87.4 MPa.


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