Reaction of a P/Al-Based Frustrated Lewis Pair with Ammonia, Borane, and Amine-Boranes: Adduct Formation and Catalytic Dehydrogenation

2013 ◽  
Vol 52 (15) ◽  
pp. 4256-4259 ◽  
Author(s):  
Christian Appelt ◽  
J. Chris Slootweg ◽  
Koop Lammertsma ◽  
Werner Uhl
Keyword(s):  
Ammonia Borane ◽  
Adduct Formation ◽  
Catalytic Dehydrogenation ◽  
Frustrated Lewis Pair ◽  
Amine Boranes

Catalytic Dehydrogenation of Ammonia Borane Mediated by a Pt(0)/Borane Frustrated Lewis Pair: Theoretical Design

ChemPhysChem ◽  
2020 ◽  
Vol 21 (23) ◽  
pp. 2573-2578
Author(s):  
Lei Zhang ◽  
Takumi Oishi ◽  
Liuzhou Gao ◽  
Shiyu Hu ◽  
Linlin Yang ◽  
...  
Keyword(s):  
Ammonia Borane ◽  
Catalytic Dehydrogenation ◽  
Theoretical Design ◽  
Frustrated Lewis Pair

Bis(perchlorocatecholato)silane and Heteroleptic Bidonors: Hidden Frustrated Lewis Pairs by Ring Strain

2021 ◽  
Author(s):  
Deborah Hartmann ◽  
Sven Braner ◽  
Lutz Greb
Keyword(s):  
Ammonia Borane ◽  
Frustrated Lewis Pairs ◽  
Ring Strain ◽  
Frustrated Lewis Pair ◽  
Lewis Pairs

Bis(perchlorocatecholato)silane and bidentate N,N- or N,P-heteroleptic donors form hexacoordinated complexes. Depending on the ring strain and hemilability in the adducts, Frustrated Lewis pair reactivity with aldehydes and catalytic ammonia borane...

DFT studies on catalytic dehydrogenation of ammonia borane by Ni(NHC)2

2014 ◽  
Vol 27 (7) ◽  
pp. 597-603 ◽  
Author(s):  
Dongxia Ai ◽  
Yi Guo ◽  
Wei Liu ◽  
Yong Wang
Keyword(s):  
Ammonia Borane ◽  
Catalytic Dehydrogenation ◽  
Dft Studies

Catalytic dehydrogenation of ammonia borane in non-aqueous medium

2009 ◽  
Vol 34 (6) ◽  
pp. 2616-2621 ◽  
Author(s):  
Roshan P. Shrestha ◽  
Himashinie V.K. Diyabalanage ◽  
Troy A. Semelsberger ◽  
Kevin C. Ott ◽  
Anthony K. Burrell
Keyword(s):  
Aqueous Medium ◽  
Ammonia Borane ◽  
Catalytic Dehydrogenation

Effective hydrogen release from ammonia borane and sodium borohydride mixture through homopolar based dehydrocoupling driven by intermolecular interaction and restrained water supply

2020 ◽  
Vol 8 (36) ◽  
pp. 19050-19056
Author(s):  
Pei Pei ◽  
Mark Cannon ◽  
Grace Quan ◽  
Erik Kjeang
Keyword(s):  
Water Vapor ◽  
Solid State ◽  
Water Supply ◽  
Intermolecular Interaction ◽  
Sodium Borohydride ◽  
Ammonia Borane ◽  
Hydrogen Release ◽  
Catalytic Dehydrogenation ◽  
Effective Hydrogen

Non-catalytic dehydrogenation of solid-state ammonia borane and sodium borohydride mixtures is achieved in this work by water vapor facilitated hydrothermolysis.

The “electric-dipole” effect of Pt–Ni for enhanced catalytic dehydrogenation of ammonia borane

2020 ◽  
Vol 844 ◽  
pp. 156253
Author(s):  
Bin Wang ◽  
Laifei Xiong ◽  
Hanjing Hao ◽  
Hairui Cai ◽  
Pengfei Gao ◽  
...  
Keyword(s):  
Electric Dipole ◽  
Ammonia Borane ◽  
Catalytic Dehydrogenation
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