The Catalytic Dehydrogenation of Ammonia-Borane Involving an Unexpected Hydrogen Transfer to Ligated Carbene and Subsequent Carbon−Hydrogen Activation

2008 ◽  
Vol 130 (6) ◽  
pp. 1798-1799 ◽  
Author(s):  
Xinzheng Yang ◽  
Michael B. Hall
Keyword(s):  
Hydrogen Transfer ◽  
Ammonia Borane ◽  
Catalytic Dehydrogenation ◽  
Hydrogen Activation

DFT studies on catalytic dehydrogenation of ammonia borane by Ni(NHC)2

2014 ◽  
Vol 27 (7) ◽  
pp. 597-603 ◽  
Author(s):  
Dongxia Ai ◽  
Yi Guo ◽  
Wei Liu ◽  
Yong Wang
Keyword(s):  
Ammonia Borane ◽  
Catalytic Dehydrogenation ◽  
Dft Studies

Catalytic dehydrogenation of ammonia borane in non-aqueous medium

2009 ◽  
Vol 34 (6) ◽  
pp. 2616-2621 ◽  
Author(s):  
Roshan P. Shrestha ◽  
Himashinie V.K. Diyabalanage ◽  
Troy A. Semelsberger ◽  
Kevin C. Ott ◽  
Anthony K. Burrell
Keyword(s):  
Aqueous Medium ◽  
Ammonia Borane ◽  
Catalytic Dehydrogenation

Effective hydrogen release from ammonia borane and sodium borohydride mixture through homopolar based dehydrocoupling driven by intermolecular interaction and restrained water supply

2020 ◽  
Vol 8 (36) ◽  
pp. 19050-19056
Author(s):  
Pei Pei ◽  
Mark Cannon ◽  
Grace Quan ◽  
Erik Kjeang
Keyword(s):  
Water Vapor ◽  
Solid State ◽  
Water Supply ◽  
Intermolecular Interaction ◽  
Sodium Borohydride ◽  
Ammonia Borane ◽  
Hydrogen Release ◽  
Catalytic Dehydrogenation ◽  
Effective Hydrogen

Non-catalytic dehydrogenation of solid-state ammonia borane and sodium borohydride mixtures is achieved in this work by water vapor facilitated hydrothermolysis.

Catalytic Dehydrogenation of Ammonia Borane Mediated by a Pt(0)/Borane Frustrated Lewis Pair: Theoretical Design

ChemPhysChem ◽  
2020 ◽  
Vol 21 (23) ◽  
pp. 2573-2578
Author(s):  
Lei Zhang ◽  
Takumi Oishi ◽  
Liuzhou Gao ◽  
Shiyu Hu ◽  
Linlin Yang ◽  
...  
Keyword(s):  
Ammonia Borane ◽  
Catalytic Dehydrogenation ◽  
Theoretical Design ◽  
Frustrated Lewis Pair

The “electric-dipole” effect of Pt–Ni for enhanced catalytic dehydrogenation of ammonia borane

2020 ◽  
Vol 844 ◽  
pp. 156253
Author(s):  
Bin Wang ◽  
Laifei Xiong ◽  
Hanjing Hao ◽  
Hairui Cai ◽  
Pengfei Gao ◽  
...  
Keyword(s):  
Electric Dipole ◽  
Ammonia Borane ◽  
Catalytic Dehydrogenation

The Role of Free N-Heterocyclic Carbene (NHC) in the Catalytic Dehydrogenation of Ammonia-Borane in the Nickel NHC System

2009 ◽  
Vol 121 (12) ◽  
pp. 2235-2239 ◽  
Author(s):  
Paul M. Zimmerman ◽  
Ankan Paul ◽  
Zhiyong Zhang ◽  
Charles B. Musgrave
Keyword(s):  
Ammonia Borane ◽  
Catalytic Dehydrogenation

scholarly journals B-Methylated Amine-Boranes: Substituent Redistribution, Catalytic Dehydrogenation, and Facile Metal-Free Hydrogen Transfer Reactions

2015 ◽  
Vol 54 (22) ◽  
pp. 10878-10889 ◽  
Author(s):  
Naomi E. Stubbs ◽  
André Schäfer ◽  
Alasdair P. M. Robertson ◽  
Erin M. Leitao ◽  
Titel Jurca ◽  
...  
Keyword(s):  
Hydrogen Transfer ◽  
Transfer Reactions ◽  
Catalytic Dehydrogenation ◽  
Metal Free ◽  
Free Hydrogen ◽  
Amine Boranes ◽  
Hydrogen Transfer Reactions

Catalytic Dehydrogenation of Ammonia Borane at Ni Monocarbene and Dicarbene Catalysts

2009 ◽  
Vol 48 (12) ◽  
pp. 5418-5433 ◽  
Author(s):  
Paul M. Zimmerman ◽  
Ankan Paul ◽  
Charles B. Musgrave
Keyword(s):  
Ammonia Borane ◽  
Catalytic Dehydrogenation

scholarly journals Nanocatalysts for Hydrogen Generation from Ammonia Borane and Hydrazine Borane

2014 ◽  
Vol 2014 ◽  
pp. 1-11 ◽  
Author(s):  
Zhang-Hui Lu ◽  
Qilu Yao ◽  
Zhujun Zhang ◽  
Yuwen Yang ◽  
Xiangshu Chen
Keyword(s):  
Hydrogen Storage ◽  
Hydrogen Content ◽  
Hydrogen Generation ◽  
Ammonia Borane ◽  
High Potential ◽  
Catalytic Dehydrogenation ◽  
Hydrogen Storage Materials ◽  
Methanolic Solution ◽  
Storage Materials ◽  
Chemical Hydrogen Storage

Ammonia borane (denoted as AB, NH3BH3) and hydrazine borane (denoted as HB, N2H4BH3), having hydrogen content as high as 19.6 wt% and 15.4 wt%, respectively, have been considered as promising hydrogen storage materials. Particularly, the AB and HB hydrolytic dehydrogenation system can ideally release 7.8 wt% and 12.2 wt% hydrogen of the starting materials, respectively, showing their high potential for chemical hydrogen storage. A variety of nanocatalysts have been prepared for catalytic dehydrogenation from aqueous or methanolic solution of AB and HB. In this review, we survey the research progresses in nanocatalysts for hydrogen generation from the hydrolysis or methanolysis of NH3BH3and N2H4BH3.

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