Effective hydrogen release from ammonia borane and sodium borohydride mixture through homopolar based dehydrocoupling driven by intermolecular interaction and restrained water supply

2020 ◽  
Vol 8 (36) ◽  
pp. 19050-19056
Author(s):  
Pei Pei ◽  
Mark Cannon ◽  
Grace Quan ◽  
Erik Kjeang
Keyword(s):  
Water Vapor ◽  
Solid State ◽  
Water Supply ◽  
Intermolecular Interaction ◽  
Sodium Borohydride ◽  
Ammonia Borane ◽  
Hydrogen Release ◽  
Catalytic Dehydrogenation ◽  
Effective Hydrogen

Non-catalytic dehydrogenation of solid-state ammonia borane and sodium borohydride mixtures is achieved in this work by water vapor facilitated hydrothermolysis.

Promoted hydrogen release from ammonia borane with mannitolvia a solid-state reaction route

2012 ◽  
Vol 41 (3) ◽  
pp. 871-875 ◽  
Author(s):  
Yuede Pan ◽  
Yan Wang ◽  
Yanliang Liang ◽  
Zhanliang Tao ◽  
Jun Chen
Keyword(s):  
Solid State ◽  
Solid State Reaction ◽  
Ammonia Borane ◽  
Hydrogen Release ◽  
Reaction Route ◽  
Solid State Reaction Route

DFT studies on catalytic dehydrogenation of ammonia borane by Ni(NHC)2

2014 ◽  
Vol 27 (7) ◽  
pp. 597-603 ◽  
Author(s):  
Dongxia Ai ◽  
Yi Guo ◽  
Wei Liu ◽  
Yong Wang
Keyword(s):  
Ammonia Borane ◽  
Catalytic Dehydrogenation ◽  
Dft Studies

Planar 2-(2-hydroxyphenyl)benzothiazole-based dyes functionalized via triple bonds as exceedingly efficient solid-state fluorophores

CrystEngComm ◽  
2017 ◽  
Vol 19 (35) ◽  
pp. 5178-5183 ◽  
Author(s):  
Yahui Niu ◽  
Longfei Xu ◽  
Qin Wang ◽  
Haoran Wu ◽  
Yanrong Zhang
Keyword(s):  
Solid State ◽  
Intermolecular Interaction ◽  
Triple Bonds

Two planar 2-(2-hydroxyphenyl)benzothiazole-based dyes without sterically bulky groups as exceedingly efficient solid-state fluorophores due to the absence of strong π–π intermolecular interaction.

scholarly journals Utilizing the Combined Power of Theory and Experiment to Understand Molecular Structure – Solid-State and Gas-Phase Investigation of Morpholine Borane

2020 ◽  
Vol 73 (8) ◽  
pp. 794
Author(s):  
Aliyu M. Ja'o ◽  
Derek A. Wann ◽  
Conor D. Rankine ◽  
Matthew I. J. Polson ◽  
Sarah L. Masters
Keyword(s):  
Molecular Structure ◽  
Solid State ◽  
Gas Phase ◽  
Hydrogen Generation ◽  
Energy Requirement ◽  
Hydrogen Release ◽  
X Ray Diffraction ◽  
Structural Variations ◽  
Dehydrogenation Reaction ◽  
Quantum Chemical Methods

The molecular structure of morpholine borane complex has been studied in the solid state and gas phase using single-crystal X-ray diffraction, gas electron diffraction, and computational methods. Despite both the solid-state and gas-phase structures adopting the same conformation, a definite decrease in the B–N bond length of the solid-state structure was observed. Other structural variations in the different phases are presented and discussed. To explore the hydrogen storage potential of morpholine borane, the potential energy surface for the uncatalyzed and BH3-catalyzed pathways, as well as the thermochemistry for the hydrogen release reaction, were investigated using accurate quantum chemical methods. It was observed that both the catalyzed and uncatalyzed dehydrogenation pathways are favourable, with a barrier lower than the B–N bond dissociation energy, thus indicating a strong propensity for the complex to release a hydrogen molecule rather than dissociate along the B–N bond axis. A minimal energy requirement for the dehydrogenation reaction has been shown. The reaction is close to thermoneutral as demonstrated by the calculated dehydrogenation reaction energies, thus implying that this complex could demonstrate potential for future on-board hydrogen generation.

Deliquescence in the Hydrolysis of Sodium Borohydride by Water Vapor

2010 ◽  
Vol 49 (20) ◽  
pp. 9596-9599 ◽  
Author(s):  
Amy M. Beaird ◽  
Thomas A. Davis ◽  
Michael A. Matthews
Keyword(s):  
Water Vapor ◽  
Sodium Borohydride ◽  
Hydrolysis Of

scholarly journals Nano-inclusion in one step: spontaneous ice-templating of porous hierarchical nanocomposites for selective hydrogen release

2019 ◽  
Vol 3 (2) ◽  
pp. 396-400 ◽  
Author(s):  
Simon Champet ◽  
Jan van den Berg ◽  
Robert Szczesny ◽  
Agata Godula-Jopek ◽  
Duncan H. Gregory
Keyword(s):  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Ammonia Borane ◽  
Onset Temperature ◽  
Hydrogen Release ◽  
Aqueous Suspensions ◽  
Reduced Graphene ◽  
One Step ◽  
Ice Templating

3-D nanocomposites of (reduced) graphene oxide and ammonia borane can be fabricated in a one-step ice templating process from aqueous suspensions. The nanocomposites release hydrogen at a reduced onset temperature, suppressing the release of diborane, borazine and ammonia.

Sign in / Sign up

Export Citation Format

Share Document