Zero-Valent Amino-Olefin Cobalt Complexes as Catalysts for Oxygen Atom Transfer Reactions from Nitrous Oxide

2016 ◽  
Vol 128 (49) ◽  
pp. 15549-15554 ◽  
Author(s):  
Thomas L. Gianetti ◽  
Rafael E. Rodríguez-Lugo ◽  
Jeffrey R. Harmer ◽  
Monica Trincado ◽  
Matthias Vogt ◽  
...  
Keyword(s):  
Nitrous Oxide ◽  
Oxygen Atom ◽  
Cobalt Complexes ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Oxygen Atom Transfer Reactions ◽  
Atom Transfer Reactions

Zero-Valent Amino-Olefin Cobalt Complexes as Catalysts for Oxygen Atom Transfer Reactions from Nitrous Oxide

2016 ◽  
Vol 55 (49) ◽  
pp. 15323-15328 ◽  
Author(s):  
Thomas L. Gianetti ◽  
Rafael E. Rodríguez-Lugo ◽  
Jeffrey R. Harmer ◽  
Monica Trincado ◽  
Matthias Vogt ◽  
...  
Keyword(s):  
Nitrous Oxide ◽  
Oxygen Atom ◽  
Cobalt Complexes ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Oxygen Atom Transfer Reactions ◽  
Atom Transfer Reactions

Nonclassical oxygen atom transfer reactions of an eight-coordinate dioxomolybdenum(vi) complex

2021 ◽  
Author(s):  
Leila G. Ranis ◽  
Jacqueline Gianino ◽  
Justin M. Hoffman ◽  
Seth N. Brown
Keyword(s):  
Oxygen Atom ◽  
Transfer Reaction ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Oxygen Atom Transfer Reactions ◽  
Atom Transfer Reactions ◽  
Oxygen Atoms

Eight-coordinate MoO2(DOPOQ)2 can donate two oxygen atoms to substrates such as phosphines in a four-electron nonclassical oxygen atom transfer reaction.

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