Substrate-Controlled Diastereoselective Synthesis of Sugar-Based Chlorinated Perhydrofuro[2,3-b]pyransviaCopper(I)-Catalyzed Radical Cyclization

2017 ◽  
Vol 359 (3) ◽  
pp. 432-442 ◽  
Author(s):  
Ram N. Ram ◽  
Neeraj Kumar ◽  
Dharmendra Kumar Gupta
2014 ◽  
Vol 50 (63) ◽  
pp. 8764-8767 ◽  
Author(s):  
Xiao Liu ◽  
Lingjuan Zhang ◽  
Xianxiu Xu ◽  
Shan Wang ◽  
Ling Pan ◽  
...  

A copper-catalyzed aerobic tandem Michael addition–intramolecular radical cyclization–benzyl C(sp3)–H bond oxidation reaction of dicinnamoyl ketene dithioacetals and ethyl cyanoacetate was developed for the diastereoselective synthesis of seven-membered carbocycles.


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