Corrosion Behavior of High-Mn Austenitic Fe–Mn–Al–Cr–C Steels in NaCl and NaOH Solutions

The corrosion behavior of austenitic Fe–Mn–Al–Cr–C twinning-induced plasticity (TWIP) and microband-induced plasticity (MBIP) steels with different alloying elements ranging from 22.6–30 wt.% Mn, 5.2–8.5 wt.% Al, 3.1–5.1 wt.% Cr, to 0.68–1.0 wt.% C was studied in 3.5 wt.% NaCl (pH 7) and 10 wt.% NaOH (pH 14) solutions. The results obtained using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques, alongside optical microscopy analysis, revealed pitting as the dominant corrosion mechanism in high-Mn TWIP steels. An X-ray diffraction analysis of the surface revealed that the main corrosion products were hematite (Fe2O3), braunite (Mn2O3), and hausmannite (Mn3O4), and binary oxide spinels were also identified, such as galaxite (MnAl2O4) and jacobsite (MnFe2O4). This is due to the higher dissolution rate of Fe and Mn, which present a more active redox potential. In addition, a protective Al2O3 passive film was also revealed, showing enhanced corrosion protection. The highest corrosion susceptibility in both electrolytes was exhibited by the MBIP steel (30 wt.% Mn). Pitting corrosion was observed in both chloride and alkaline solutions.

Synthesis and Electrochemical Performance of a Homogenously Dispersed LiaMn2-x-y- ZFexCoyNizO4-dCld Lithium Ion Battery Cathode Material

Lithium manganese oxide spinels are attractive materials for lithium-ion battery cathodes due to their capability for high voltage application paired with a three-dimensional conductive pathway that can allow for improved lithium insertion and deinsertion kinetics. However, this material suffers from limited cyclability as a result of the energy barriers for removing lithium from the octahedral sites and capacity fading as a result of manganese dissociation. This work incorporates a multiple doping strategy for selecting capacity distribution across various voltage regimes. The resulting electrochemical cells are able to produce useful capacity at 5.2 V, 4.7 V, 4.1 V, and 2.75 V. Additionally, materials synthesized in a laboratory setting and via large scale production via licensing with no cobalt content has resulted in capacities exceeding 200 mAh/g. These materials achieve 75% capacity retention at 3C vs. C/10 discharge down to 2.75 V.

Nanocrystalline Transition-Metal Gallium Oxide Spinels from Acetylacetonate Precursors via Solvothermal Synthesis

The synthesis of mixed-metal spinels based on substituted γ-Ga2O3 is reported using metal acetylacetonate precursors in solvothermal reactions with alcohols as solvents at 240 °C. New oxides of Cr, Mn and Fe have been produced, all of which are formed as nanocrystalline powders, as seen by high-resolution transmission electron microscopy (HR-TEM). The first chromium-gallium mixed oxide is thus formed, with composition 0.33Ga1.87Cr0.8O4 ( = vacant site). X-ray absorption near-edge spectroscopy (XANES) at the chromium K-edge shows the presence of solely octahedral Cr3+, which in turn implies a mixture of tetrahedral and octahedral Ga3+, and the material is stable on annealing to at least 850 °C. An analogous manganese material with average chemical composition close to MnGa2O4 is shown to contain octahedral Mn2+, along with some Mn3+, but a different inversion factor to materials reported by conventional solid-state synthesis in the literature, which are known to have a significant proportion of tetrahedral Mn2+. In the case of iron, higher amounts of the transition metal can be included to give an Fe:Ga ratio of 1:1. Elemental mapping using energy dispersive X-ray spectroscopy on the TEM, however, reveals inhomogeneity in the distribution of the two metals. This is consistent with variable temperature 57Fe Mössbauer spectroscopy that shows the presence of Fe2+ and Fe3+ in more than one phase in the sample. Variable temperature magnetisation and electron paramagnetic resonance (EPR) indicate the presence of superparamagnetism at room temperature in the iron-gallium oxides.