Photo-Aligned Nematic Liquid Crystals Enable the Modulation of Thermoplasmonic Heating

We experimentally demonstrate that the plasmonic heat delivered by a single layer of homogeneously distributed gold nanoparticles (AuNPs), immobilized on a glass substrate, can be optically tuned by taking advantage of the properties of an organic layer based on azobenzene and nematic liquid crystal (NLC) molecules. The effect, which exploits the dependence of the NLC refractive index value on the molecular director orientation, is realized using the polarization-dependent, light-induced molecular reorientation of a thin film of photo-aligning material that the NLC is in contact with. The reversibility of the optically induced molecular director reorientation of the NLC enables an active modulation of the plasmonic photo-induced heat.

Orientational instability of the director in a nematic cell caused by electro-induced anchoring modification

We theoretically investigate the threshold for the director reorientation from the homeotropic state to the hybrid homeotropic-planar state and vice versa in a cell filled with a flexoelectric nematic liquid crystal (NLC) subjected to an electric field. The liquid crystal is doped by a CTAB-like substance, a part of molecules of which dissociates into positive and negative ions. The anchoring on one of the cell surfaces is assumed to be strong and homeotropic, while the other surface can adsorb positive ions which play the role of an orienting surfactant for NLC molecules on this surface. At certain voltages, the orientational transitions in the bulk of the NLC are possible due to the changing conditions for the director on the adsorbing surface. We calculate respective threshold voltages as functions of anchoring parameters. The existence of the critical values of these parameters, beyond which the orientational transitions do not take place, is established.

Modelling the Surface Plasmon Spectra of an ITO Nanoribbon Grating Adjacent to a Liquid Crystal Layer

The reflection and transmission coefficients of an indium tin oxide (ITO) nanoribbon grating placed between a nematic liquid crystal (LC) layer and an isotropic dielectric medium are calculated in the infrared region. Reflection and transmission spectra in the range of 1–5 μm related to the surface plasmon excitation in the ITO nanoribbons are obtained. Dependence of the peak spectral position on the grating spacing, the ribbon aspect ratio, and the 2D electron concentration in the nanoribbons is studied. It is shown that director reorientation in the LC layer influences the plasmon spectra of the grating, enabling a control of both the reflection and transmission of the system. The data obtained with our model are compared to the results obtained using COMSOL software, giving the similar results.

Dielectric and Electro-Optic Effects in a Nematic Liquid Crystal Doped with h-BN Flakes

A small quantity of hexagonal boron nitride (h-BN) flakes is doped into a nematic liquid crystal (LC). The epitaxial interaction between the LC molecules and the h-BN flakes rising from the π−π electron stacking between the LC’s benzene rings and the h-BN’s honeycomb structure stabilizes pseudo-nematic domains surrounding the h-BN flakes. Electric field-dependent dielectric studies reveal that the LC-jacketed h-BN flakes follow the nematic director reorientation upon increasing the applied electric field. These anisotropic pseudo-nematic domains exist in the isotropic phase of the LC+h-BN system as well, and interact with the external electric field, giving rise to a nonzero dielectric anisotropy in the isotropic phase. Further investigations reveal that the presence of the h-BN flakes at a low concentration in the nematic LC enhances the elastic constants, reduces the rotation viscosity, and lowers the pre-tilt angle of the LC. However, the Fréedericksz threshold voltage stays mostly unaffected in the presence of the h-BN flakes. Additional studies show that the presence of the h-BN flakes enhances the effective polar anchoring strength in the cell. The enhanced polar anchoring strength and the reduced rotational viscosity result in faster electro-optic switching in the h-BN-doped LC cell.

Peculiarities in the Director Reorientation and the NMR Spectra Evolution in a Nematic Liquid Crystals under the Effect of Crossed Electric and Magnetic Fields

The illustrative description of the field-induced peculiarities of the director reorientation in the microsized nematic volumes under the effect of crossed magnetic B and electric E fields have been proposed. The most interesting feature of such configuration is that the nematic phase becomes unstable after applying the strong E . The theoretical analysis of the reorientational dynamics of the director field provides an evidence for the appearance of the spatially periodic patterns in response to applied large E directed at an angle α to B . The feature of this approach is that the periodic distortions arise spontaneously from a homogeneously aligned nematic sample that ultimately induces a faster response than in the uniform mode. The nonuniform rotational modes involve additional internal elastic distortions of the conservative nematic system and, as a result, these deformations decrease of the viscous contribution U vis to the total energy U of the nematic phase. In turn, that decreasing of U vis leads to decrease of the effective rotational viscosity coefficient γ eff ( α ) . That is, a lower value of γ eff ( α ) , which is less than one in the bulk nematic phase, gives the less relaxation time τ on ( α ) ∼ γ eff ( α ) , when α is bigger than the threshold value α th . The results obtained by Deuterium NMR spectroscopy confirm theoretically obtained dependencies of τ on ( α ) on α .

Interaction of supramolecular aggregates and the enhanced optical torque on the director in a dye doped nematic liquid crystal

Based on the experimental evidence of aggregation of dye molecules, the effect of strong enhancement of the light-induced director reorientation in a dye-doped nematic liquid crystal is explained by the interaction of supramolecular aggregates.