The investigation of broad-absorbing tetrabenzocorrolazine dye-based black matrix of low dielectric constant

Tetrabenzocorrolazine dyes with high color strength and broad absorbance derived from a phthalocyanine moiety were designed and synthesized for a color filter on an array-mode black matrix of low dielectric constant. The prepared tetrabenzocorrolazine dyes focused the absorbance of phthalocyanine further into the visible light range so that the color was considerably closer to black, while making it easier to introduce an axial substituent in the vertical direction to the dye main body, thereby markedly improving its solubility in industrial solvents. Upon mixing with a perylene dye of 450-550 nm absorbance and a thermosetting resin composition, dye-based black matrix films with high optical density values, associated with superior light shielding capability, were fabricated. The prepared black matrix films not only ensured thermal resistance by allowing easy intermolecular cohesion but also served as an insulating membrane that did not interfere with the thin film transistor electric signals, exhibiting a value of 3-5 when dielectricity was measured as the most critical factor for the color filter on array mode display panels.

Efficacious elimination of intramolecular charge transfer in perylene imide based light-harvesting antenna molecules

A new design for the perylene dye-based light-harvesting antenna systems is presented, which enables complete suppression of parasitic intramolecular charge-transfer.

Solvent- and concentration-induced self-assembly of an amphiphilic perylene dye

PDA-CA self-assembly behavior depends on temperature, concentration, and solvent.

Push–pull type quinoidal perylene showing solvent polarity dependent diradical character and negative solvatochromism

A push–pull perylene dye shows solvent dependent diradical character and negative solvatochromism.

In situ formation of SERS hot spots by a bis-quaternized perylene dye: a simple strategy for highly sensitive detection of heparin over a wide concentration range

We have demonstrated a simple SERS assay for the sensitive detection of heparin by means of an in situ hot spot assembly method.