Effect of fuels, aromatics and preparation methods on seal swell

New alternative jet fuels have provided many advantages in the aviation industry, especially in terms of economics and environment. However, fuel–seal compatibility is one of the major issues that restricts alternative fuel advancement into the market. Thus, to help understand and solve the problem, this study examines the swelling effect of prepared and non-prepared O-rings in different fuels and aromatic species. Stress relaxation experiments were carried out to evaluate seal compatibility under compression, which mimics engine operation conditions. Seals were compressed and immersed in a variety of fuels and their blends for about 90h while maintaining a constant temperature 30°C and constant compression force of 25% seal thickness. The two types of elastomers investigated were fluorosilicone and nitrile O-rings, which are predominantly used in the aviation industry. Meanwhile, three different fuels and aromatic species were utilised as the variables in the experiments. The fuels used were Jet-A1, SPK and SHJFCS, while the aromatic species added were propyl benzene, tetralin and p-xylene. The swelling effects were determined from the P/Po value. Results indicate that Jet-A1 has the highest swelling effect, followed by SHJFCS and SPK. It was observed that the higher the percentage of aromatics in fuel, the higher the rate of swelling. Furthermore, prepared seals had a lower swelling rate than did non-prepared seals. Meanwhile, the intensity of the swelling effect in the Jet-A1-SHJFCS blends was in the order of 60/40, 85/15 and 50/50 blend. The work done in this study will aid in the selection of suitable aromatic species in future fuels. The novelty of this research lies in the determination of the appropriate amount of aromatic content as well as the selection of type of aromatic and its mixture fuel. Moreover, the various proportions of fuel blends with aromatic are investigated. The primary aim of this study is to understand the behaviour of prepared and non-prepared seals, and their compatibility with alternative fuels.

Evaluation of the Chemical Composition of Gas and Particle Phase Products of Aromatic Oxidation

Aromatic volatile organic compounds (VOC) are key anthropogenic pollutants emitted to the atmosphere and are important for both ozone and secondary organic aerosol (SOA) formation in urban areas. Recent studies have indicated that aromatic hydrocarbons may follow previously unknown oxidation chemistry pathways, including autoxidation that can lead to the formation of highly oxidised products. In this study we evaluate the gas and particle phase ions formed during the hydroxyl radical oxidation of substituted C9-aromatic isomers (1,3,5-trimethyl benzene, 1,2,4-trimethyl benzene, propyl benzene and isopropyl benzene) and a substituted polyaromatic hydrocarbon (1-methyl naphthalene) under low and medium NOx conditions. The majority of product signal in both gas and particle phases comes from ions which are common to all precursors, though signal distributions are distinct for different VOCs. Gas and particle phase composition are distinct from one another, and comparison with the near explicit gas phase Master Chemical Mechanism (MCMv3.3.1) highlights a range of missing highly oxidised products in the pathways. In the particle phase, the bulk of product signal from all precursors comes from ring scission ions, many of which have undergone further oxidation to form HOMs. Under perturbation of OH oxidation with increased NOx, the contribution of HOM ion signals to the particle phase signal remains elevated for more substituted aromatic precursors. Up to 25 % of product signal comes from ring-retaining ions including highly oxygenated organic molecules (HOMs); this is most important for the more substituted aromatics. Unique products are a minor component in these systems, and many of the dominant ions have ion formulae concurrent with other systems, highlighting the challenges in utilising marker ions for SOA.

The Regulatory Role of Nuclear Factor Kappa B in the Heart of Hereditary Hypertriglyceridemic Rat

Activation of nuclear factor-κB (NF-κB) by increased production of reactive oxygen species (ROS) might induce transcription and expression of different antioxidant enzymes and also of nitric oxide synthase (NOS) isoforms. Thus, we aimed at studying the effect of NF-κB inhibition, caused by JSH-23 (4-methyl-N1-(3-phenyl-propyl)-benzene-1,2-diamine) injection, on ROS and NO generation in hereditary hypertriglyceridemic (HTG) rats. 12-week-old, male Wistar and HTG rats were treated with JSH-23 (bolus, 10μmol, i.v.). After one week, blood pressure (BP), superoxide dismutase (SOD) activity, SOD1, endothelial NOS (eNOS), and NF-κB (p65) protein expressions were higher in the heart of HTG rats compared to control rats. On the other hand, NOS activity was decreased. In HTG rats, JSH-23 treatment increased BP and heart conjugated dienes (CD) concentration (measured as the marker of tissue oxidative damage). Concomitantly, SOD activity together with SOD1 expression was decreased, while NOS activity and eNOS protein expression were increased significantly. In conclusion, NF-κB inhibition in HTG rats led to decreased ROS degradation by SOD followed by increased oxidative damage in the heart and BP elevation. In these conditions, increased NO generation may represent rather a counterregulatory mechanism activated by ROS. Nevertheless, this mechanism was not sufficient enough to compensate BP increase in HTG rats.

Low Dielectric Constant Thermosetting Resins For Microelectronics

Material technology for future microelectronics will require advances in all facets of materials and processing. Low dielectric constant resins that exhibit facile processing and good thermal and mechanical behavior represent one area of needed research and development. The dielectric constant must be lower than that of amorphous silicon dioxide and possess the right properties for integration with future metallurgies such as copper. Several thermoset resins that were predicted to possess the necessary characteristics have been synthesized and studied. These include a copolymer of 1,3,5-tris(2-allyloxy-hexafluoro-2-propyl) benzene with polymethylhydrosiloxane and several cyanate ester resins. Thermal gravimetric analysis indicated significant degradation between 300 and 400 degrees C depending upon the resin. Dielectric constants were measured up to 40 GHz and ranged from 2.25 to 2.75. Compatibility with copper multilevel processing was addressed. The processability of the dielectric resins was investigated to address the integration issues associated with the fabrication process.