Similar curvature-to-width ratios for channels and channel belts: Implications for paleo-hydraulics of fluvial ridges on Mars

The surface of Mars contains abundant sinuous ridges that appear similar to river channels in planform, but they stand as topographic highs. Ridges have similar curvature-to-width ratios as terrestrial meandering rivers, which has been used to support the hypothesis that ridges are inverted channels that directly reflect channel geometry. Anomalously wide ridges, in turn, have been interpreted as evidence for larger rivers on Mars compared to Earth. However, an alternate hypothesis is that ridges are exhumed channel-belt deposits—a larger zone of relatively coarse-grained deposits formed from channel lateral migration and aggradation. Here, we measured landform wavelength, radius of curvature, and width to compare terrestrial channels, terrestrial channel belts, and martian ridges. We found that all three landforms follow similar scaling relations, in which ratios of radius of curvature to width range from 1.7 to 7.3, and wavelength-to-width ratios range from 5.8 to 13. We interpret this similarity to be a geometric consequence of a sinuous curved line of finite width. Combined with observations of ridge-stacking patterns, our results suggest that wide ridges on Mars could indicate fluvial channel belts that formed over significant time rather than anomalously large rivers.

Tetra-μ3-iodido-tetrakis[(tri-n-butylphosphane-κP)copper(I)]

The title complex, [Cu4I4(C12H27P)4], crystallizes with six molecules in the unit cell and with three independent one-third molecule fragments, completed by application of the relevant symmetry operators, in the asymmetric unit. The tetranuclear copper core shows a tetrahedral geometry (site symmetry 3..). The I atoms also form a tetrahedron, with I...I distances of 4.471 (1) Å. Both tetrahedra show an orientation similar to that of a pair of self-dual platonic bodies. The edges of the I-tetrahedral structure are capped to the face centers of the Cu-tetrahedron andvice versa. The Cuface...I distances are 2.18 Å (averaged) and the Iface...Cu distances are 0.78 Å (averaged). As a geometric consequence of these properties there are eight distorted trigonal–bipyramidal polyhedra evident, wherein each trigonal face builds up the equatorial site and the opposite Cu...I positions form the axial site. As expected, then-butyl moieties are highly flexible, resulting in large elongations of their anisotropic displacement parameters. Some C atoms of then-butyl groups were needed to fix alternative discrete disordered positions.