The Use of Silane-Aniline as Coupling Agent between Titanium (IV) Oxide Core and Polyaniline Emeraldine Salt Shell

Stable electronic configuration between the interface of an n-type oxide semiconductor core and a p-type polymer shell is necessary in order to guarantee a consistent functioning core-shell structure. This research aims to use silane-aniline to link between an n-type Titanium (IV) oxide (TiO2) core and p-type polyaniline emeraldine salt (PANI-ES) shell. Core-shell structure was created by functionalizing TiO2 powders with silane aniline molecules using simple soaking technique and then polymerizing the attached aniline molecules using an oxidative technique. Infrared spectroscopy reveals the presence of Si-O bonds signifying the presence of linkage between the inorganic core and polymeric shell. Polymerization of the attached aniline molecules may have led to coupling of aromatic rings to form long polymeric structures which caused widening and shifting of aromatic rings’ IR peak to lower wavenumber. In conclusion, silane-aniline was successfully utilized to connect the n-type TiO2 core and p-type PANI-ES shell.

Samsonov’s Model for Electronic Mechanism of Sintering and its Relevance

In the present review a generalized view of sintering mechanism on the basis of the electronic nature of the chemical species involved has been highlighted. The stable electronic configuration model proposed by G.V.Samsonov is one of the models. In spite of the fact that the model is qualitative, its far reaching impact in explaining liquid phase sintering and activated sintering of real systems can not be minimized. In a way the model holds a premium in its predictive nature , which is so crucial not only in sintering processing, but also in alloy design based on metallic or ceramic systems or composites constituted out of these.