Prediction of renal crystalline size distributions in space using a PBE analytic model. 2. Effect of dietary countermeasures

An analytic Population Balance Equation model is used to assess the efficacy of citrate, pyrophosphate, and augmented fluid intake as dietary countermeasures aimed at reducing the risk of renal stone formation for astronauts. The model uses the measured biochemical profile of the astronauts as input and predicts the steady-state size distribution of the nucleating, growing, and agglomerating renal calculi subject to biochemical changes brought about by administration of these dietary countermeasures. Numerical predictions indicate that an increase in citrate levels beyond its average normal ground-based urinary values is beneficial but only to a limited extent. Unfortunately, results also indicate that any decline in the citrate levels during space travel below its normal urinary values on Earth can easily move the astronaut into the stone-forming risk category. Pyrophosphate is found to be an effective inhibitor since numerical predictions indicate that even at quite small urinary concentrations, it has the potential of shifting the maximum crystal aggregate size to a much smaller and plausibly safer range. Finally, our numerical results predict a decline in urinary volume below 1.5 liters/day can act as a dangerous promoter of renal stone development in microgravity while urinary volume levels of 2.5–3 liters/day can serve as effective space countermeasures.

The Microwave Radiative Properties of Falling Snow Derived from Nonspherical Ice Particle Models. Part II: Initial Testing Using Radar, Radiometer and In Situ Observations

In this study, two different particle models describing the structure and electromagnetic properties of snow are developed and evaluated for potential use in satellite combined radar–radiometer precipitation estimation algorithms. In the first model, snow particles are assumed to be homogeneous ice–air spheres with single-scattering properties derived from Mie theory. In the second model, snow particles are created by simulating the self-collection of pristine ice crystals into aggregate particles of different sizes, using different numbers and habits of the collected component crystals. Single-scattering properties of the resulting nonspherical snow particles are determined using the discrete dipole approximation. The size-distribution-integrated scattering properties of the spherical and nonspherical snow particles are incorporated into a dual-wavelength radar profiling algorithm that is applied to 14- and 34-GHz observations of stratiform precipitation from the ER-2 aircraftborne High-Altitude Imaging Wind and Rain Airborne Profiler (HIWRAP) radar. The retrieved ice precipitation profiles are then input to a forward radiative transfer calculation in an attempt to simulate coincident radiance observations from the Conical Scanning Millimeter-Wave Imaging Radiometer (CoSMIR). Much greater consistency between the simulated and observed CoSMIR radiances is obtained using estimated profiles that are based upon the nonspherical crystal/aggregate snow particle model. Despite this greater consistency, there remain some discrepancies between the higher moments of the HIWRAP-retrieved precipitation size distributions and in situ distributions derived from microphysics probe observations obtained from Citation aircraft underflights of the ER-2. These discrepancies can only be eliminated if a subset of lower-density crystal/aggregate snow particles is assumed in the radar algorithm and in the interpretation of the in situ data.

Morphology and surface features of olivine in kimberlite: implications for ascent processes

Most kimberlite rocks contain large proportions of ellipsoidal-shaped xenocrystic olivine grains that are derived mainly from disaggregation of peridotite. Here, we describe the shapes, sizes and surfaces of olivine grains recovered from kimberlite lavas erupted from the Quaternary Igwisi Hills volcano, Tanzania. The Igwisi Hills kimberlitic olivine grains are compared to phenocrystic olivine, liberated from picritic lavas, and mantle olivine, liberated from a fresh peridotite xenolith. Image analysis, scanning electron microscopy imagery and laser microscopy reveal significant differences in the morphologies and surface features of the three crystal populations. The kimberlitic olivine grains form smooth, rounded to ellipsoidal shapes and have rough flaky micro-surfaces that are populated by impact pits. Mantle olivine grains are characterised by flaked surfaces and indented shapes consistent with growth as a crystal aggregate. Phenocrystic olivine exhibit faceted, smooth-surfaced crystal faces. We suggest that the unique shape and surface properties of the Igwisi Hills kimberlitic olivine grains are products of the transport processes attending kimberlite ascent from mantle source to surface. We infer that the unique shapes and surfaces of kimberlitic olivine grains result from three distinct mechanical processes attending their rapid transport through the thick cratonic mantle lithosphere: (1) penetrative flaking from micro-tensile failure induced by rapid decompression; (2) sustained abrasion and attrition driven by particle–particle collisions between grains within a turbulent, volatile-rich flow regime; and (3) higher-energy particle–particle collisions producing impact cavities superimposed on decompression structures. The combination of these processes during the rapid ascent of kimberlite magmas is responsible for the distinctive ellipsoidal shape of olivine xenocrysts found in kimberlites worldwide.

Predicting the Snow-to-Liquid Ratio of Surface Precipitation Using a Bulk Microphysics Scheme

Bulk microphysics parameterizations play an increasingly important role for quantitative precipitation forecasting (QPF) in operational numerical weather prediction (NWP). For wintertime, numerical prediction of snowfall amounts is done by applying an estimated snow-to-liquid ratio to the liquid-equivalent QPF from the NWP model. A method has been developed to use prognostic fields from a detailed bulk scheme to predict the instantaneous snow-to-liquid ratio of precipitating snow. By exploiting aspects of the parameterization of the large crystal/aggregate (snow) category, which allow for a prediction of the mean particle size and a corresponding realistic bulk density, combined with pristine ice and graupel fields, the total volume flux of ice-phase precipitation (excluding hail) is computed, independently from the computation of the total solid mass flux. Ultimately, the accumulated unmelted solid precipitation quantity is thus predicted without having to estimate the average snow-to-liquid ratio for a given event, as is typically done for wintertime QPF. The new technique has been implemented into the two-moment version of the Milbrandt–Yau microphysics scheme, which was used in a high-resolution (2.5 and 1 km) NWP modeling system over the Vancouver–Whistler region of Canada in support of forecasting for the Vancouver 2010 Olympic and Paralympic Games. Experimental fields were produced including the instantaneous snow-to-liquid ratio and the snowfall accumulation predicted directly from the scheme using the new approach. Subjective evaluation indicates that the model can discriminate between low-density and high-density snow for instantaneous precipitation. Comparison of the predicted snow-to-liquid ratio to observed climatologies indicates that the scheme produces a realistic probability distribution.

The crystal chemistry of ‘wheatsheaf’ tourmaline from Mogok, Myanmar

Tourmalines of unusual (mushroom) habit are common in granitic pegmatites of Momeik, northeast of Mogok, Myanmar. Here, we examine a sample of elbaite of significantly different habit, consisting of a series of diverging crystals, resembling a sheaf of wheat and ranging in colour from light purplish-red at the base to dark purplish-red at the tip with a thin green cap at the termination. The crystal structures of eight crystals are refined to R1-indices of ∼2.5% using graphite-monochromated Mo-Kα X-radiation; the same crystals were analysed by electron microprobe. 11B and 27Al magic angle spinning nuclear magnetic resonance (MAS NMR) spectra were collected on four regions of the wheatsheaf crystal, and show ∼0.3 a.p.f.u. [4]B and <0.1 a.p.f.u. [4]Al in the structure. 57Fe Mössbauerspectr oscopy was done on the dark green rim at the termination of the crystal, showing all Fe in this region (∼0.6 a.p.f.u.) to be Fe2+. Detailed electron-microprobe traverses show that the principal compositional variation involves the substitutions [4]B + YAl → Si + YFe*, where transition metals are present, and [4]B2 + YAl → Si2 + YLi, where transition metals are not present, although several other minor substitutions also affect crystal composition. Successive microscopic bifurcation of crystallites causes divergence of growth directions along the c axis, imparting the overall ‘wheatsheaf’ shape to the crystal aggregate. We suggest that such bifurcation is common in pegmatitic elbaite crystals, resulting in their common divergent habit.

Growth process and crystallographic properties of ammonia-induced vaterite

Metastable vaterite crystals were produced by increasing the pH of Ca2+- and CO32--containing solutions through diffusing ammonia gas. The SEM and TEM studies indicate that this ammonia-induced vaterite is polycrystalline with a 6-fold symmetry of the crystal aggregate. The morphology and crystallographic properties of this assemblage change druing crystallization. One hour after nucleation starts, vaterite grains display a spherical structure composed of nano-particles (5-10 nm) with random crystallographic orientations. After that, horizontal layers begin to develop at the edge of the sphere and gradually tilt toward the center as they grow vertically, which results in a three-dimensional morphology with a dent in the center. The vaterite grains mature fully 16 hours after nucleation. TEM analysis indicates the grown vaterite grain (50-60 μm) consists of numerous hexagonal pieces of single crystals (1-2 μm) of similar crystallographic orientations. High-resolution TEM demonstrates that these single crystals grow along (001) with {110} hexagonal boundaries.

Evolution of Micro-Textures within Individual Grains in Rolled Polycrystal Aluminum

Local orientation distributions of two neighbouring grains initially orientated near (01l)[100] and (210)[001], in a pure Al poly-crystal aggregate rolled by a reduction of 65% at room temperature have been investigated using electron backscatter diffraction (EBSD) technique. It was found that the rotation angles of zones adjacent to both sides of initial boundary (BP) are less than that of zones remote from the boundary (IP), which reveals that rotation incompatibility and heterogeneity of local orientations within individual grains during rolling. A type of improved Taylor type crystal plasticity models, in which an added prescribed shear (APS) depending on distances from grain boundary proposed, was established to illustrate development of micro-textures in each grain. The results simulated by the APS-Taylor models well agree with the micro-textures examined by EBSD.