Simulation of the Mechanical Behavior of Nanodispersed Elastomer Particle-Modified Polyamide 6

In this work the nanodispersed elastomer copolymer particle-modified polyamide 6 (PA 6) is investigated. Micromechanical modelling is proposed to predict the mechanical behaviour of this material up to failure. A three-dimensional self-consistent embedded unit cell model is chosen which has been well applied for simulating the elastoplasticdeformation of this PA 6-composite [1,. This model will be here modified with the consideration of debonding between the elastomer particles and the PA 6-matrix. The predictions are in very good agreement with the experimental results. In terms of crash behavior, e.g. in the automotive industry the material behaviour under dynamic loading is also of particular interest. Impact strength is one of the most important parameters for describing this material behaviour. A full three-dimensional dynamic simulation of V-notched Charpy impact test is performed in ABAQUS/Explicit. The calculated impact strength coincides plausibly well with the experimental determination.

Hierarchically Ordered Multi-Component Block Copolymer/Particle Nanocomposite Materials

ABSTRACTThis contribution reviews the structure formation processes that are observed in binary diblock copolymer/particle and ternary diblock copolymer/particle1/particle2 mixtures. The particle core size, the polymer domain spacing as well as the particle surface chemistry are shown to determine three distinct morphological types in particle/block copolymer composites, which is the preferential layer homogeneous distribution, the interfacial segregation and center alignment of the nanocrystals within one polymer domain. The different microstructural environments of the sequestered component that are implied by the respective particle distribution result in distinctively different optical properties of the composite and have important consequences for the prospects of metal nanocrystal/block copolymer composites as a platform for photonic crystal engineering. A detailed comparison between morphological studies and theoretical predictions will be presented that aims to better understand and control morphologies of structured cluster matter and its relation to the respective optical and mechanical properties of new microstructured composite materials.